吉林大学学报(地球科学版) ›› 2018, Vol. 48 ›› Issue (3): 736-753.doi: 10.13278/j.cnki.jjuese.20170058

• 地质与资源 • 上一篇    下一篇

云南个旧锡多金属矿床锡石矿物化学特征及其成因意义

谈树成1, 郭翔宇1,2, 何小虎1, 谢志鹏2, 张亚辉1, 李惠民3, 郝爽3   

  1. 1. 云南大学资源环境与地球科学学院, 昆明 650500;
    2. 昆明理工大学国土资源工程学院, 昆明 650093;
    3. 中国地质调查局天津地质调查中心, 天津 300170
  • 收稿日期:2017-09-25 出版日期:2018-05-26 发布日期:2018-05-26
  • 作者简介:谈树成(1970-),男,教授,博士,主要从事矿床学、矿床地球化学方面的研究,E-mail:shchtan@ynu.edu.cn
  • 基金资助:
    国家自然科学基金项目（41262004，41702084）；云南省科技厅应用基础研究计划青年项目（2017FD063）

Mineral Chemical Characteristics and Genesis of Cassiterite in Gejiu Tin-Polymetallic Deposit, Yunnan Province

Tan Shucheng1, Guo Xiangyu1,2, He Xiaohu1, Xie Zhipeng2, Zhang Yahui1, Li Huimin3, Hao Shuang3   

  1. 1. School of Resource Environment and Earth Science, Yunnan University, Kunming 650500, China;
    2. Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, China;
    3. Tianjin Center of China Geological Survey, Tianjin 300170, China
  • Received:2017-09-25 Online:2018-05-26 Published:2018-05-26
  • Supported by:
    Supported by National Natural Science Foundation of China(41262004, 41702084) and Applied Basic Research Program for Youth Project of Science and Technology Department, Yunnan Province (2017FD063)

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摘要： 云南个旧锡多金属矿床处于滇东南锡矿带的西端，是全球最大的锡多金属矿床之一。锡石作为个旧锡矿床中最主要的矿石矿物，其矿物化学特征对矿床成因具有重要的指示意义。本文运用扫描电镜、电子探针等手段对个旧锡多金属矿床中6种不同类型矿石中的锡石进行了详细的内部结构和矿物化学特征研究，并对其可能的成因进行了探讨。扫描电镜研究结果发现，除层间氧化矿型锡石较破碎外，其余类型锡石内部均发育有明显的环带结构。电子探针分析结果显示：各类型矿石中锡石的SnO2质量分数变化范围为97.700%~101.728%；Ta2O5、FeO、ZrO2、HfO2平均质量分数较高，指示锡石形成于高温热液环境；（Fe+Mn）/（Nb+Ta）显示个旧锡矿区各类型矿石中的锡石具有热液锡石的特征，且各类型锡石中Nb2O5和MnO的质量分数极低，说明成矿热液可能来自于高度分异的花岗质岩浆，而Nb、Ta质量分数说明成矿作用发生于酸性-弱酸性环境中；In2O3质量分数显示了成矿温度及压力从块状硫化物型矿石、矽卡岩型矿石、电气石细脉带型矿石、含锡白云岩型矿石到层间氧化矿型矿石有逐渐降低的趋势；云英岩型矿石中锡石的In2O3质量分数较高还需进一步论证。锡石形成过程中岩浆热液物理化学条件的变化导致其内部环带结构的形成，电子探针数据显示锡石的环带结构中化学成分呈"锯齿状"变化，显示成矿作用发生于动荡的环境中，说明锡石沉淀具有多期多阶段的特征。

关键词: 矿物化学, 电子探针, 锡石, 个旧锡多金属矿床

Abstract: The Gejiu tin polymetallic deposit is located in the west of the southeastern Yunnan tin ore belt, and is one of the largest tin polymetallic deposits in the world. As the main ore minerals in the Gejiu tin-polymetallic deposit,the mineral chemical characteristics of cassiterite have a great implication to the ore genesis. In this research, we studied the internal structure and the mineral chemical characteristics of cassiterites out of six types of ores in the Gejiu tin-polymetallic using the scanning electron microscopy and electron probe microscope analyzer. The results of scanning electron microscopy show that except the interlayer oxidation broken ore type cassiterites,the zonal structure is clearly developed within cassiterites. The results of electron probe microscope analyzer (EPMA) show that the variation range of the mass fraction of SnO2 is 97.700%-101.728%, and the mass fractions of Ta2O5, FeO, ZrO2 and HfO2 are high, which indicates that these cassiterites may be precipitated in a high temperature environment. The value of (Fe+Mn)/(Nb+Ta) shows that the different types of cassiterites have the characteristics of hydrothermal cassiterites. Very low mass fractions of Nb2O5 and MnO in different types of cassiterites suggest that the ore-forming fluid may be derived from the high-fractionated granitic magma. The mass fractions of Na, Ta indicate that the mineralization occurred in an acid to weak acid environment. The gradually decreased In2O3 in different ores (including sulfide, skarn, tourmaline veinlet belt, tin-bearing dolomite, and interlayer oxidation types of ores) indicates that the ore forming temperature and pressure have decreased gradually. However, the average mass fractions of In2O3 in greisen type need further study. The change of the physicochemical conditions of magma hydrothermal fluid during the formation of cassiterite resulted in the formation of its internal zonal structure. The electron probe data shows that the chemical composition in the zonal structure of cassiterite is "serrated", indicating that the mineralization occurred in turbulence, so the cassiterite deposits have multi-stage characteristics.

Key words: mineral chemistry, electron probe microscope analyzer, cassiterite, Gejiu tin-polymetallic deposit

中图分类号: 

  • P618.4
[1] 庄永秋,王任重,杨树培,等.云南个旧锡铜多金属矿床[M].北京:地震出版社,1996. Zhuang Yongqiu, Wang Renzhong, Yang Shupei, et al. Gejiu Tin-Copper Polymetallic Ore Deposit in Yunnan[M].Beijing:Seismological Presshgfgy, 1996.
[2] 毛景文,程彦博,郭春丽,等.云南个旧锡矿田:矿床模型及若干问题讨论[J].地质学报,2008,82(11):1455-1467. Mao Jingwen, Cheng Yanbo, Guo Chunli, et al. Gejiu Tin Polymatallic Orefield:Deposit Model and Discussion for Several Points Concerned[J].Acta Geologica Sinica, 2008,82(11):1455-1467.
[3] Li C Y, Zhang R Q, Ding X, et al. Dating Cassiterite Using Laser Ablation ICP-MS[J]. Ore Geology Reviews,2016,72:313-322.
[4] 朱立军,张杰.桂北地区锡矿床锡石主要、微量及稀土元素特征及其地质意义[J].贵州工学院学报,1993,22(4):22-26. Zhu Lijun, Zhang Jie. Compositional Characteristics and Geological Significance of Major, Trace and Rare-Earth Elements in Cassiterite in North Guangxi Region[J].Journal of Guizhou Institute of Technology,1993,22(4):22-26.
[5] 朱立军,张杰.桂北地区锡多金属矿床中锡石的成因矿物学研究[J].矿物学报,1994,14(1):32-39. Zhu Lijun, Zhang Jie. A Genetic Mineralogical Study of Cassiterites from Tin Polymetallic Deposits in Northern Guangxi[J].Acta Mineralogica Sinica,1994,14(1):32-39.
[6] Plimer I R, Lu J, Kleeman J D. Trace and Rare Earth Elements in Cassiterite-Sources of Components for the Tin Deposits of the Mole Granite, Australia[J]. Mineralium Deposita, 1991, 26:267-274.
[7] Jiang S Y, Yu J M, Lu J J. Trace and Rare-Earth Element Geochemistry in Tourmaline and Cassiterite from the Yunlong Tin Deposit, Yunnan, China:Implication for Magmatitic-Hydrothermal Fluid Evolution and Ore Genesis[J]. Chemical Geology,2004,209:193-213.
[8] Pavlova G G, Palessky S V, Borisenko A S, et al. Indium in Cassiterite and Ores of Tin Deposits[J]. Ore Geology Reviews,2015,66:99-113.
[9] 程彦博.个旧超大型锡多金属矿区成岩成矿时空演化及一些关键性问题探讨[D].北京:中国地质大学,2012. Cheng Yanbo.Spatial-Temperal Evolution of the Magmatism and Mineralization in the Gejiu Supergiant Sn Polymetallic District and Insights into Several Key Problems[D].Bejing:China University of Geosciences,2012.
[10] 秦德先,黎应书.个旧锡铜多金属矿床地质研究[M].北京:科学出版社,2008. Qin Dexian, Li Yingshu. Geologic Study of Gejiu Tin-Copper Polymetallic Deposit[M]. Beijng:Science Press,2008.
[11] 李肖龙,毛景文,程彦博. 云南个旧白沙冲和北炮台花岗岩岩石学、地球化学研究及成因探讨[J].地质论评,2011,57(6):837-850. Li Xiaolong, Mao Jingwen, Cheng Yanbo. Petrology, Geochemistry and Petrogenesis of Baishachong and Beipaotai Granitic Stocks in Gejiu, Yunnan Province, Southwest China[J]. Geological Review,2011,57(6):837-850.
[12] Cheng, Y B, Mao, J W. Age and Geochemistry of Granites in Gejiu Area, Yunnan Province, SW China:Constraints on Their Petrogenesis and Tectonic Setting[J]. Lithos,2010,120:258-276.
[13] Cheng Y B, Spandler C, Mao J W, et al. Granite, Gabbro and Mafic Microgranular Enclaves in the Gejiu Area, Yunnan Province, China:A Case of Two-Stage Mixing of Crust-and Mantle-Derived Magmas[J]. Contributions to Mineralogy and Petrology, 2012,164:659-676.
[14] Cheng Y B, Mao J W. Geochronology of the Gabbromafic Microgranular Enclavesgranite Associations in the Gejiu District, Yunnan Province and Their Geodynamic Significance[J]. Acta Geological Sinica (English Edition), 2012, 86(3):748-761.
[15] Cheng Y B, Mao J W, Yang Z X. Geology and Vein Tin Mineralization in the Dadoushan Deposit, Gejiu District, SW China[J]. Mineralium Deposits, 2012,47:701-712.
[17] Cheng Y B, Mao J W, Spandler, C. Petrogenesis and Geodynamic Implications of the Gejiu Igneous Complex in the Western Cathaysia Block, South China[J]. Lithos, 2013,175/176:213-229.
[18] Cheng Y B, Mao J W, Chang Z S, et al. The Origin of the World Class Tin-Polymetallic Deposits in the Gejiu District, SW China:Constraints from Metal Zoning Characteristics and 40Ar-39Ar Geochronology[J]. Ore Geology Reviews, 2013,53:50-62.
[19] Cheng Y B, Mao J W, Zhu X K, et al. Iron Isotope Fractionation During Supergene Weathering Process and Its Application to Constrain Ore Genesis in Gaosong Deposit, Gejiu District, SW China[J]. Gondwana Research, 2015,27:1283-1291.
[20] 黄文龙,许继峰,陈建林,等.云南个旧杂岩体年代学与地球化学:岩石成因和幔源岩浆对锡成矿贡献[J].岩石学报,2016,32(8):2330-2346. Huang Wenlong, Xu Jifeng, Chen Jianlin, et al. Geochronology and Geochemistry of the Gejiu Complex in the Yunnan Province, SW China:Petrogenesis and Contributions of Mantal-Derived Melts to Tin Mineralization[J].Acta Petrologica Sinica, 2016,32(8):2330-2346.
[21] 谈树成. 个旧锡-多金属矿床成矿系列研究[D].昆明:昆明理工大学,2004. Tan Shucheng. Deposit Metallogenic Series of Gejiu Tin Polymetallic Deposit[D].Kunming:Kunming University of Science and Technology, 2004.
[22] 谈树成,秦德先,陈爱兵,等.个旧锡矿区域地壳演化与成矿探讨[J].矿物学报,2004,24(2):157-163. Tan Shucheng, Qin Dexian, Chen Aibing, et al. Regional Crust Evolution and Metallogenesis of Gejiu Tin Deposit:A Discussion[J]. Acta Mineralogica Sinica,2004,24(2):157-165.
[23] 谈树成,秦德先,赵筱青,等. 个旧锡矿印支中晚期海底基性火山-沉积Sn-Cu-Zn(Au)矿床成矿雏议[J].地质与勘探,2006,42(1):43-50. Tan Shucheng, Qin Dexian, Zhao Xiaoqing, et al. Submarine Basic Volcano-Sedimentary Sn-Cu-Zn(Au)Deposit Metallognic Series of the Middle-Later Indo-Chinese Epoch in Gejiu Tin Deposit[J].Geology and Prospecting,2006,42(1):43-50.
[24] 陈骏,王汝成,周建平,等.锡的地球化学[M].南京:南京大学出版社,1999. Chen Jun, Wang Rucheng, Zhou Jianping, et al. The Geochemistry of Tin[M].Nanjing:Nanjing University Press,1999.
[25] 张必敏.湖南千里山-骑田岭芙蓉锡矿田锡石的成因矿物学及流体包裹体研究[D].北京:中国地质大学,2006. Zhang Bimin. Study on Genetic Mineralogy and Fluid Inclusions of Cassiterite in Hunan Qianlishan-Qitianling Furong Tin Ore Field[D].Beijing:Chinese University of Geosciences, 2006.
[26] 聂治,尹观.云南昌宁锡矿床锡石的标型特征研究[J].广东微量元素科学,2007,14(10):50-55. Nie Zhi, Yin Guan. Typomorphic Feature of Cassiterite from Changning Tin Deposit in Yunnan Province[J].Trace Element Science in Guangdong,2007,14(10):50-55
[27] 黄品赟,汪相,陈洁,等.赣南淘锡坑锡矿床中锡石晶体形态学和地球化学研究[J].地质论评,2012,58(5):987-1000. Huang Pinyun, Wang Xiang, Chen Jie, et al. Morphological and Geochemical Study of the Cassiterite in Taoxikeng Tin Deposit, Southern Jiangxi, China[J].Geological Review,2012,58(5):987-1000.
[28] 陈锦荣.郴县红旗岭锡矿床锡石成因矿物学研究[J].湖南地质,1992,11(4):299-304. Chen Jinrong. Study on Genetic Mineralogy of Cassiterite in Hongqiling Tin Deposit, Chenzhou[J].Hunan Geology,1992,11(4):299-304.
[29] 杨岳清,王文瑛,陈成湖,等.福建南平花岗伟晶岩中锡石的矿物学研究[J].福建地质, 2006,25(2):75-81. Yang Yueqing, Wang Wenying,Chen Chenghu,et al. Study on the Cassiterite from the Granitic Pegmatites in Nanping, Fujian Province[J].Fujian Geology,2006,25(2):75-81.
[30] 于际民,蒋少涌.葡萄牙Neves Corvo块状硫化物矿床锡石的微量元素地球化学[J].地球化学,2001,30(2):140-145. Yu Jimin, Jiang Shaoyong. Trace Element Geochemistry of Cassiterite from the Neves Corvo Massive Sulfide Deposit, Portugal[J].Geochemica,2001,30(2):140-145.
[31] 王玉往,王京彬,王莉娟.内蒙古大井锡多金属矿床锡石矿物特征[J].地质与勘探,2006,42(4):51-56. Wang Yuwang,Wang Jingbin,Wang Lijuan. Characteristics of Tin Minerals from Dajing Tin-Polymetallic Deposit, Inner Mongolia,China[J].Geology and Prospecting,2006,42(4):51-56.
[32] 王濮,潘兆橹,翁玲宝,等.系统矿物学[M].北京:地质出版社,1982:541-544. Wang Pu,Pan Zhaolu,Weng Lingbao, et al. Systematic Mineralogy[M].Beijing:Geological Publishing House, 1982:541-544.
[33] 吕蒙.个旧锡矿锡石成因矿物学及流体包裹体研究[D].昆明:昆明理工大学,2015. Lü Meng. Study of Genetic Mineralogy and Fluid Inclusions of Cassiterite in Gejiu Tin Deposit[D].Kunming:Kunming University of Science and Technology,2015.
[34] 吕蒙,谈树成,郝爽,等.个旧锡矿锡石的矿物学研究[J].西北地质,2016,49(1):101-108. Lü Meng,Tan Shucheng,Hao Shuang,et al. Mineralogical Study of Cassiterite Grains from Gejiu Tin Deposit[J].Northwestern Geology,2016,49(1):101-108.
[35] Tindle A G, Breaks F W, Webb P C. Wodginite-Group Minerals from the Separation Rapids Rare-Element Granitic Pegmatite Group, Northwestern Ontario[J].Can Mineral,1998,36:637-658.
[36] Murciego A, Sanchez A G, Dusausoy Y, et al. Geochemistry and EPR of Cassiterites from Iberian Hercynian Massif[J].Mineral. Mag,1997,61:357-365.
[37] 赵斌,李维显,蔡元吉. 黑钨矿、锡石、铌铁矿、细晶石、铌钽铁矿生产条件及黑钨矿和锡石中Ta、Nb含量变化的实验研究[J].地球化学,1977(2):123-135,157-158. Zhao Bin, Li Weixian, Cai Yuanji. Conditions of Formation of Wolframite, Cassiterites, Columbit, Microlite and Tapiolite and Experimental Study on the Variation of Nb and Ta in Wolframite and Cassiterite[J]. Geochimica,1997(2):123-135,157-158.
[38] 王汝成,徐士进. 苏州花岗岩中钽铁矿的发现及其地质意义[J].地质论评,1996,42(4):373-379. Wang Rucheng, Xu Shijin. Discovery of Tantalite in the Suzhou Granite and Its Geological Significance[J].Geological Review,1996,42(4):373-379.
[39] 王文瑛,杨岳清,陈成湖,等. 福建南平花岗伟晶岩中的铌钽矿物学研究[J].福建地质,1999, 20(3):113-134. Wang Wenying, Yang Yueqing, Chen Chenghu, et al. Study on the Nb and Ta-Mineral from the Granitic Pegmatites in Nanping, Fujian Province[J].Fujian Geology,1999,20(3):113-134.
[40] 王汝成. 法国中央高原Beauvoir花岗岩中铌钽矿中环带构造类型、化学成分和形成条件[J].矿物学报,1991,11(3):225-233. Wang Rucheng. Zoning in Columbite Crystals from the Beauvoir Granite, Massif Central, France:Types, Composition and Constraints on Their Formation[J]. Acta Mineraolgica Journal, 1991,11(3):225-233.
[41] Huang Xiaolong, Wang Rucheng, Chen Xiaoming, et al. Vertical Variations in the Mineralogy of the Yichun Topaz-Lepidolite Granite, Jiangxi Province, Southern China[J]. Can Mineral,2002, 40:1047-1068.
[42] 李鸿莉,毕献武,胡瑞忠,等.芙蓉锡矿田骑田岭花岗岩黑云母矿物化学组成及其对锡成矿的指示意义[J].岩石学报,2007,23(10):2605-2614. Li Hongli, Bi Xianwu, Hu Ruizhong, et al. Mineral Chemistry of Biotite in the Qitianling Granite Associate with the Furong Tin Deposit:Tracing Tin Mineralization Signatures[J]. Acta Petrologica Sinica,2007,23(10):2605-2614.
[43] 王雄武,王晓地,刘家齐,等.湖南骑田岭花岗岩与锡成矿的关系[J].地质科技情报,2004,23(2):1-12. Wang Xiongwu, Wang Xiaodi, Liu Jiaqi, et al. Relationship of Qitianling Granite to Sn Mineralization in Hunan Province[D].Geological Science and Technology Information,2004,23(2):1-12.
[44] 王汝成,朱金初,张文兰,等.南岭地区钨锡花岗岩的成矿矿物学:概念与实例[J]. 高校地质学报,2008,14(4):485-495. Wang Rucheng, Zhu Jinchu, Zhang Wenlan, et al. Ore-Forming Mineralogy of W-Sn Granite in the Nanling Range:Concept and Case Study[J].Geological Journal of China Universities,2008,14(4):485-495.
[45] Guo J, Zhang R Q, Li C Y, et al. Genesis of the Gaosong Sn-Cu Deposit, Gejiu District, SW China:Constraints from in Situ LA-ICP-MS Cassiterite U-Pb Dating and Trace Element Fingerprinting[J]. Ore Geology Reviews, 2018, 92:627-642.
[46] 张娟,毛景文,程彦博,等.云南个旧卡房锡-铜矿床成矿作用过程探讨:成矿流体约束[J].岩石学报,2012,28(1):166-182. Zhang Juan, Mao Jingwen, Cheng Yanbo, et al. Mineralization Process of the Kafang Tin-Copper Deposit in the Gejiu District,Yunnan Province:Constraints from Fluid Inclusions[J].Acta Petrologica Sinica, 2012, 28(1):166-182.
[47] 杨宗喜,毛景文,陈懋弘,等.云南个旧卡房铜矿床地质地球化学特征及其成因探讨[J].岩石学报,2010,26(3):830-844. Yang Zongxi, Mao Jingwen, Chen Maohong, et al. Geology, Geochemistry and Genesis of Kafang Copper Deposit in Gejiu, Yunnan Province[J].Acta Petrologica Sinica,2010,26(3):830-844.
[48] Jia R X, Fang W X, Hu R Z. Mineral Geochemical Compositions of Tourmalines and Their Significance in the Gejiu Tin Polymetallic Deposits, Yunnan, China[J]. Acta Geologica Sinica (English Edition),2010,84(1):155-166.
[49] Liao S L, Chen S Y, Deng X H, et al. Fluid Inclusion Characteristics and Geologic Significance of the Xi'ao Copper-Tin Polymetallic Deposit in Gejiu, Yunnan Province[J].Journal of Asian Earth Sciences,2014,79:455-467.
[50] Duslki P. Spurenanalyse Als Hilfsmittel Bei Geoche-mischen Untersuchung Der Genese Bolivianischer Zinnerzlagerstatten[M].Berlin:Verlag von Dietrich Reimer,1980:79.
[51] Taylor G R. Geology of Tin Deposit[M].New York:Elsevier,1979:554.
[52] Hиkyлин H H.锡石中微量元素是锡矿床评价的标志[J].冶金矿产地质,1983(1):56-60. Hиkyлин H H. Trace Elements of Cassiterite in Tin Deposit is a Sign of Evaluation[J].Metallurgy and Mineral Geology,1983(1):56-60.
[53] 干国梁,陈志雄.广西都庞岭地区锡矿床锡石主要、微量及稀土元素的组成特点及赋存状态[J].矿物学报,1992,12(1):58-68. Gan Guoliang, Chen Zhixiong. Compositional Characteristics and Existing Forms of Major, Trace and Rare-Earth Elements in Cassiterite in the Dupangling Tin Ore Field, Guangxi[J].Acta Mineraolgica Journal,1992,12(1):58-68.
[54] 朱笑青,张乾,何玉良,等.富铟与贫铟矿床成矿流体中铟与锡铅锌的关系研究[J]. 地球化学,2006,35(1):6-12. Zhu Xiaoqing, Zhang Qian, He Yuliang,et al. Relationships Between Indium and Tin, Zinc and Lead in Ore-Forming Fluid from the Indium-Rich and-Poor Deposit in China[J]. Geochimica,2006,35(1):6-12.
[55] 陈学明,邓军,林棕,等.云南白牛厂超大型银多金属矿床中富铟锡石及其与银的伴生关系[J].地球学报,1999,20(增刊):379-384. Chen Xueming, Deng Jun, Lin Zong, et al. The Cassiterite Enrich in and Ag Associated Relationship in the Bainiuchang Superlarge Silver Polymetallic Deposit[J].Acta Geoscientia Sinica,1990,20(Sup.):379-384.
[56] Banerjee S K, Johnson C K, Krs M. Mossbauer Study to Find the Origin of Weak Ferromagnetism in Cassiterite[J].Nature,1970,225:173-175.
[57] Schneider H J, Dulski P, Luck J, et al. Correlation of Trace Element Distribution in Cassiterite and Geotectonic Position of Their Deposit in Bolivia[J].Mineral. Deposit, 1978, 13:119-122.
[58] Clark A M, Fejer E E, Donaldson J D, et al. The 119Sn Mossbauer Spectra,Cell Dimensions and Minor Elements Content of Some Cassiterites[J].Mineral Mag, 1976, 40:895-898.
[59] Izoret L, Marnier G, Dusausoy Y. Caracterisation Cristallochimique de la Cassiterite des Gisements D'etain et de Tundstene de Galice,Espagne[J].Can Mineral,1985,23:221-231.
[60] Giuliali G. La Cassiterite Zonee du Gisement de Sokhret Allal(Granite des Zaer;Maroc Central):Composition Chimique et Phases Fluids Associees[J].Mineral Deposit,1987,22:253-261.
[61] Neiva A M R. Geochemistry of Cassiterite and Its Inclusions and Exsolution Products from Tin and Tungsten Deposits in Portugal[J].Can Mineral,1996,34:745-768.
[62] Wang Rucheng, Fontan F, Monchoux P. Interrela-tions et Evolution Comparee de la Cassiterite et des Niobo-Tantalates dans les Different Facies du Granite de Beauvoir (Massif d,Echassieres)[J]. Geol France,1987(2/3):237-245.
[63] 朱立军.广西九毛锡矿超基性岩中锡石的成因矿物学研究[J].矿物岩石,1989,9(4):14-21. Zhu Lijun. Studies of Genetic Mineralogy on Cassiterites from Ultrabasic Rocks in Jiumao Tin Deposit,Guangxi[J].Minerals and Rocks,1989, 9(4):14-21.
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