吉林大学学报(地球科学版) ›› 2020, Vol. 50 ›› Issue (4): 1112-1126.doi: 10.13278/j.cnki.jjuese.20190015

• 地质工程与环境工程 • 上一篇    

酸性矿山排水影响的水库沉积物微量元素地球化学特征

曹星星1,2,3, 吴攀2,3, 周少奇1,2,4,5, 谢峰1, 荣嵘2   

  1. 1. 贵州科学院贵州省分析测试研究院, 贵阳 550014;
    2. 贵州大学资源与环境工程学院, 贵阳 550025;
    3. 喀斯特地质资源与环境教育部重点实验室(贵州大学), 贵阳 550025;
    4. 华南理工大学环境与能源学院, 广州 510006;
    5. 华南理工大学亚热带建筑科学国家重点实验室, 广州 510641
  • 收稿日期:2019-01-23 发布日期:2020-07-29
  • 通讯作者: 吴攀(1973-),男,侗族,教授,博士,主要从事矿山环境地球化学方面的研究,E-mail:pwu@gzu.edu.cn E-mail:pwu@gzu.edu.cn
  • 作者简介:曹星星(1989-),男,讲师,博士,主要从事环境地球化学方面的研究,E-mail:xxcao@gzu.edu.cn
  • 基金资助:
    国家自然科学基金委员会-贵州省政府联合基金项目（U1612442）；中国博士后科学基金项目（2017M623071）；国土资源部喀斯特环境与地质灾害重点实验室开放课题（KST2017K06）

Trace Elements Geochemical Characteristics of Reservoir Sediments Affected by Acid Mine Drainage

Cao Xingxing1,2,3, Wu Pan2,3, Zhou Shaoqi1,2,4,5, Xie Feng1, Rong Rong2   

  1. 1. Guizhou Academy of Testing and Analysis, Guizhou Academy of Sciences, Guiyang 550014, China;
    2. College of Resource and Environmental Engineering, Guizhou University, Guiyang 550025, China;
    3. Key Laboratory of Karst Georesources and Environment(Guizhou University), Ministry of Education, Guiyang 550025, China;
    4. College of Environment and Energy, South China University of Technology, Guangzhou 510006, China;
    5. State Key Laboratory of Subtropical Building Sciences, South China University of Technology, Guangzhou 510641, China
  • Received:2019-01-23 Published:2020-07-29
  • Supported by:
    Supported by Joint of National Natural Science Foundation of China and Guizhou Province(U1612442), China Postdoctoral Science Foundation (2017M623071) and Key Laboratory of Karst Environments and Geohazards, Ministry of Land and Resources (KST2017K06)

PDF (PC)

15323

摘要： 为了解酸性矿山排水（AMD）影响下水库沉积物中微量元素的质量分数水平及其分布特征，对常年受酸性废水影响的贵州兴仁猫石头水库沉积物中26种微量元素的质量分数、相关性及控制因素进行了分析。结果表明：猫石头水库沉积物柱中Sr、Ba、Zr、V、Cr和As质量分数平均值超过了100 μg/g，其中As质量分数最高，平均值超过800 μg/g；Be、Ta、Co、Ag、Cd、Sn和Se质量分数的平均值都在5 μg/g以下；其他元素质量分数平均值则在10~60 μg/g之间。相较未受AMD影响的水系沉积物，研究区水库沉积物具有明显的As和Sb富集特征。水库沉积物中Li、Be、Rb、Sr、Cs、Ba、Sc、Y、Zr、Hf、Nb、Ta、Th之间存在显著正相关关系，而As与这些元素之间存在显著负相关关系。元素相关分析、因子分析及微量元素图解表明，Li、Be、Rb、Sr、Cs、Ba、Sc、Y、Zr、Hf、Nb、Ta、Th、Cr、Sb等元素受控于流域岩石化学风化和土壤物理侵蚀，这也是控制研究区元素分布最重要的因素，而Cu、Cd等重金属元素则与AMD对地层中元素的溶蚀析出和有机质等细颗粒物的吸附有关。另外，研究区重金属元素中，Cd、Cu、Pb、Cr、Zn的生态风险轻微，而As和Sb则具有很强的潜在生态风险。

关键词: 微量元素, 水库沉积物, 酸性矿山排水, 贵州

Abstract: In order to understand the content and distribution characteristics of trace elements in reservoir sediments under the influence of acid mine drainage(AMD),the concentration and distribution of twenty-six trace elements were analyzed in the sediment cores from Maoshitou Reservoir and its inflow tributaries in Guizhou Province, Southwest China. The results show that the mean contents of Sr, Ba, Zr, V, Cr and As in the sediment cores are higher than 100 μg/g, and the content of As is the highest, the average content exceeds 800 μg/g; while the mean values of Be, Ta, Co, Ag are lower than 5 μg/g, the values of other elements lie in the range of 10 and 60 μg/g. Compared with the stream sediments without affected by AMD, the reservoir sediments in the study area are obviously rich in As and Sb. There are obvious positive correlations between Li, Be, Rb, Sr, Cs, Ba, Sc, Y, Zr, Hf, Nb, Ta,and Th in reservoir sediments, and their distribution is basically similar, while there is a significant negative correlation between As and these elements. Element correlation analysis, factor analysis,and trace element diagrams show that Li, Be, Rb, Sr, Cs, Ba, Sc, Y, Zr, Hf, Nb, Ta, Th, Cr,and Sb etc. are controlled by chemical weathering and physical erosion of watershed rock, which is the most important factor controlling the distribution of elements in the study area; while heavy metals (such as Cu and Cd etc.) are related to the dissolution of elements in the formation of AMD and the adsorption of fine particles such as organic matter. In addition, the ecological risks of Cd, Cu, Pb, Cr, and Zn are low, while the ecological risks of As and Sb are high.

Key words: trace elements, reservoir sediments, acid mine drainage, Guizhou Province

中图分类号: 

  • P595
[1] Norman M D, Deckker P. Trace Metals in Lacustrine and Marine Sediments:A Case Sudy from the Gulf of Carpentaria, Northern Australia[J]. Chemical Geology, 1990, 82:299-318.
[2] 朱赖民, 杜俊民, 张远辉,等. 南黄海中部E2柱样沉积物来源的稀土元素及微量元素示踪[J]. 环境科学学报, 2006, 26(3):495-500. Zhu Laimin, Du Junmin, Zhang Yuanhui, et al.Tracing the Sediment Source at E2 Hole in the South Yellow Sea with Rare Earth Element and Trace Element[J]. Acta Scientiae Circumstantiae, 2006, 26(3):495-500.
[3] Jia X, Wang H, Wan H. Sources and Trace Element Geochemical Characteristics of the Coarse Sediment in the Ningxia-Inner Mongolia Reaches of the Yellow River[J]. Geosciences Journal, 2014, 18(2):181-192.
[4] 伊彩文,陈炳辉,李文,等.粤北大宝山酸性矿山废水的稀土元素地球化学特征[J].地球与环境,2016,44(1):73-81. Yi Caiwen, Chen Binghui, Li Wen, et al.Geochemical Characteristics of Rare Earth Elements in Dabaoshan Acid Mine Drainages, Guangdong Province, China[J]. Earth and Environment, 2016,44(1):73-81.
[5] Knöller K, Fauville A, Mayer B, et al. Sulfur Cycling in an Acid Mining Lake and Its Vicinity in Lusatia, Germany[J]. Chemical Geology, 2004, 204(3/4):0-323.
[6] Sarmiento A M, Olias M, Nieto J M, et al. Natural Attenuation Processes in Two Water Reservoirs Receiving Acid Mine Drainage[J]. Science of the Total Environment, 2009, 407(6):2051-2062.
[7] 胡国成, 许振成, 赵学敏, 等. 高州水库表层沉积物重金属污染特征及生态风险评价[J]. 环境科学研究, 2011, 24(8):949-957. Hu Guocheng, Xu Zhencheng, Zhao Xuemin, et al.Pollution Characteristics and Ecological Risk Assessment of Heavy Metals in Surface Sediments from Gaozhou Reservoir, Guangdong Province[J]. Research of Environmental Sciences, 2011, 24(8):949-957.
[8] 王建丰, 雷天柱, 张生银, 等. 刘家峡水库表层沉积物微量元素地球化学特征[J]. 沉积与特提斯地质, 2018, 38(3):51-59. Wang Jiangfeng, Lei Tianzhu, Zhang Shengyin,et al.Trace Element Geochemistry of the Surface Sediments in the Liujiaxia Reservoir, Gansu[J]. Sedimentary Geology and Tethyand Geology, 2018, 38(3):51-59.
[9] 吴攀. 贵州高砷煤矿区环境中砷的地球化学[M]. 贵阳:贵州科技出版社, 2013. Wu Pan. Geochemistry of Arsenic in the Environment of High Arsenic Coal Mines in Guizhou Province[M]. Guiyang:Guizhou Science and Technology Publishing House, 2013.
[10] 谢欢欢, 吴攀, 唐常源,等. 酸性矿山排水污染的水库水体酸化特征[J]. 环境科学研究, 2011, 24(2):199-204. Xie Huanhuan, Wu Pan, Tang Changyuan, et al. Acidification Characteristics of Reservoir Water Polluted by Acid Mine Drainage[J]. Research of Environmental Sciences, 2011, 24(2):199-204.
[11] Sun J, Tang C, Wu P, et al. Migration of Cu, Zn, Cd and As in Epikarst Water Affected by Acid Mine Drainage at a Coalfield Basin, Xingren, Southwest China[J]. Environmental Earth Sciences, 2013, 69(8):2623-2632.
[12] Li X, Wu P. Geochemical Characteristics of Dissolved Rare Earth Elements in Acid Mine Drainage from Abandoned High-As Coal Mining Area, South Western China[J]. Environmental Science and Pollution Research, 2017.
[13] Zhang C P, Wu P, Tang C Y, et al. Geochemical Behavior of Arsenic in Reducing Sulfidic Sediments of Reservoir Contaminated by Acid Mine Drainage[J]. Environmental Earth Sciences, 2014, 71(10):4341-4351.
[14] 廖铸敏,马路遥,陶平.黔西南龙潭组微量元素地球化学特征与金矿成矿物质来源研究[J].贵州地质,2014,31(1):10-20. Liao Zhumin, Ma Luyao, Tao Ping. Geochemical Characteristics of Trace Elements and Source of Metallogenic Material of Gold Deposit in Longtan Formation in Southwest Guizhou[J]. Guizhou Geology, 2014,31(1):10-20.
[15] 史长义,梁萌,冯斌.中国水系沉积物39种元素系列背景值[J].地球科学,2016,41(2):234-251. Shi Changyi, Liang Meng, Feng Bin. Average Background Values of 39 Chemical Elements in Stream Sediments of China[J]. Earth Science, 2016,41(2):234-251.
[16] 何邵麟.贵州表生沉积物地球化学背景特征[J].贵州地质,1998, 15(2):149-156. He Shaolin. Geochemical Background of Supergene Sediments in Guizhou[J]. Guizhou Geology, 1998, 15(2):149-156.
[17] 赵兴媛. 黔中小流域水体悬浮物与沉积物元素地球化学及风化侵蚀指示[D]. 北京:首都师范大学, 2012. Zhao Xingyuan. Element Geochemical Characteristics of Suspended Matters and Sediments in a Small Watershed of the Central Guizhou Province and Their Weathering Implication[D]. Beijing:Capital Normal University, 2012.
[18] 杨守业,杨从先.元素地球化学特征的多元统计方法研究:长江与黄河沉积物元素地球化学研究[J].矿物岩石,1999(1):63-67. Yang Shouye, Yang Congxian. Multiple Statistic Study of Element Geochemical Characteristics:Element Geochemical Study on the Changjiang and Huanghe Sediments[J]. Journal of Mineralogy and Petrology, 1999(1):63-67.
[19] 朱赖民,高志友,尹观,等.南海表层沉积物的稀土和微量元素的丰度及其空间变化[J].岩石学报,2007,23(11):2963-2980. Zhu Laimin, Gao Zhiyou, Yin Guan, et al. Content and Spatial Change of Rare Earth Element and Trace Element of Surficial Sediment in the South China Sea[J]. Acta Petrologica Sinica, 2007,23(11):2963-2980.
[20] 赵兴媛,季宏兵,朱先芳,等.黔中小流域水体悬浮物与沉积物微量元素地球化学特征及物源指示[J].地球化学,2012,41(3):250-265. Zhao Xingyuan, Ji Hongbing, Zhu Xianfang, et al. Geochemical Characteristics of Trace Elements in Suspended Matters and Sediments in a Small Watershed of the Central Guizhou Province and Their Provenance Implications[J]. Geochimica, 2012,41(3):250-265.
[21] 丁振华,郑宝山,庄敏.贵州燃煤型砷中毒地区煤的微量元素的赋存状态[J].矿物学报,2005,25(4):357-362. Ding Zhenhua, Zheng Baoshan, Zhuang Min. The Mode of Occurrence of Trace Elements in Coals from Arsenosis-Affected Areas, Guizhou Province[J]. Acta Mineralogica Sinica, 2005,25(4):357-362.
[22] 谢欢欢.酸性矿山废水酸化水库中As的迁移转化及其归趋[D].贵阳:贵州大学,2011. Xie Huanhuan. Migration and Transformation of As in Acidified Reservoir of Acid Mine Wastewater and Its Fate[D]. Guiyang:Guizhou University, 2011.
[23] Powell J D. Origin and Influence of Coal Mine Drainage on Streams of the United States[J]. Environmental Geology & Water Sciences, 1988, 11(2):141-152.
[24] Lin J G, Chen S Y. The Relationship Between Adsorption of Heavy Metal and Organic Matter in River Sediments[J]. Environment International, 1998, 24(3):345-352.
[25] 甘华阳,梁开,郑志昌.珠江口表层沉积物中微量元素地球化学[J].海洋地质与第四纪地质,2010,30(4):131-139. Gan Huayang, Liang Kai, Zheng Zhichang.Trace Elements Geochemical Characteristics of the Surface Sediments of Pear River Estuary[J]. Marine Geology & Quaternary Geology,2010,30(4):131-139.
[26] Bauluz B, Mayayo M J, Fernandez-Nieto C, et al.Geochemistry of Precambrian and Paleozoic Siliciclastic Rocks from the Iberian Range (NE Spain):Implications Forsource-area Weathering, Sorting, Provenance, and Tectonic Setting[J]. Chemical Geology,2000, 168:135-150.
[27] Muhs D R, Budahn J R. Geochemical Evidence for African Dust and Volcanic Ash Inputs to Terra Rossa Soils on Carbonate Reef Terraces, Northern Jamaica, West Indies[J]. Quaternary International, 2009, 196(1):13-35.
[28] 刘英俊, 曹励明, 李兆麟, 等. 元素地球化学[M]. 北京:科学出版社, 1984. Liu Yingjun,Cao Liming, Li Zhaolin, et al. Geochemistry of Element[M]. Beijing:Science Press, 1984.
[29] MVller G. Index of Geoaccumulation in Sediments of the Rhine River[J]. Geo Journal,1969,2(3):108-118.
[30] Hakanson L. An Ecological Risk Index for Aquatic Pollution Control:A Sedimentological Approach[J]. Water Research,1980,14(8):975-1001.
[31] 王娅,赵铮,木志坚,等.三峡库区典型农田小流域土壤汞的空间分布特征[J].环境科学,2015,36(1):130-135. Wang Ya, Zhao Zheng, Mu Zhijian, et al.Spatial Distribution of Mercury in Soils of a Typical Small Agricultural Watershed in the Three Gorges Reservoir Region[J]. Environmental Science, 2015,36(1):130-135.
[32] 陆继龙,刘奇志,王春珍,等.二道松花江沉积物重金属特征及其潜在生态风险[J].吉林大学学报(地球科学版),2018,48(2):566-573. Lu Jilong, Liu Qizhi, Wang Chunzhen, et al. Characteristics and Potential Ecological Risk of Heavy Metals of Sediments in Erdaosonghua River[J]. Journal of Jilin University (Earth Science Edition),2018,48(2):566-573.
[33] 王丽,杨爱江,邓秋静,等.贵州独山锑矿区土壤:头花蓼系统中重金属的分布特征[J].生态学杂志,2017,36(12):3545-3552. Wang Li, Yang Aijiang, Deng Qiujing, et al.Distribution Characteristics of Heavy Metals in Soil:Polygonum Capitatum System at Dushan Antimony Deposit, Guizhou Province[J]. Chinese Journal of Ecology, 2017,36(12):3545-3552.
[34] 林绍霞,张清海,郭媛,等.贵州草海沉积物重金属污染特征及潜在生态风险分析[J].农业环境科学学报,2012,31(11):2236-2241. Lin Shaoxia, Zhang Qinghai, Guo Yuan, et al.Pollution Characteristics and Potential Ecological Risk Assessment of Heavy Metals in Sediments of Caohai in Guizhou Province, China[J]. Journal of Agro-Environment Science, 2012,31(11):2236-2241.
[35] 吴洋,杨军,周小勇,等.广西都安县耕地土壤重金属污染风险评价[J].环境科学,2015,36(8):2964-2971. Wu Yang, Yang Jun, Zhou Xiaoyong, et al.Risk Assessment of Heavy Metal Contamination in Farmland Soil in Du'an Autonomous County of Guangxi Zhuang Autonomous Region, China[J]. Environmental Science, 2015,36(8):2964-2971.
[1] 龙天祥, 何小虎, 刘飞, 李宗勇, 王玉朝, 赵俊, 李云飞, 王长兵, 曹原. 长安金矿区碱性岩锆石U-Pb年代学、微量元素、Hf同位素特征及其地质意义[J]. 吉林大学学报(地球科学版), 2019, 49(6): 1607-1627.
[2] 叶霖, 刘玉平, 张乾, 鲍谈, 何芳, 王小娟, 王大鹏, 蓝江波. 云南都龙超大型锡锌多金属矿床中闪锌矿微量及稀土元素地球化学特征[J]. 吉林大学学报(地球科学版), 2017, 47(3): 734-750.
[3] 戴朝成，郑荣才，任军平，朱如凯. 四川前陆盆地上三叠统须家河组物源区分析及其地质意义[J]. 吉林大学学报(地球科学版), 2014, 44(4): 1085-1096.
[4] 陶平，陈启飞，王亮，胡从亮. 黔东南天锦黎地区矿田级金矿定位预测--兼论勘查及研究程度较低地区的矿产预测方法[J]. 吉林大学学报(地球科学版), 2013, 43(4): 1235-1245.
[5] 曹锐, 木合塔尔·扎日, 陈斌, 李德威, 曹福根, 刘德民. 东天山板块缝合带石炭纪火山岩地球化学和Sr-Nd同位素特征及其大地构造意义[J]. J4, 2012, 42(2): 400-409.
[6] 叶霖, 杨玉龙, 高伟, 刘铁庚. 陕南铜厂铜矿床成矿物质来源探讨[J]. J4, 2012, 42(1): 92-103.
[7] 严再飞, 黄智龙, 陈觅, 周家喜, 赵正, 丁伟. 峨眉山溢流玄武岩省高钛玄武岩的两种不同地幔源特征[J]. J4, 2010, 40(6): 1311-1322.
[8] 刘丽红, 束龙仓, 鲁程鹏. 基于管道流模型的岩溶含水系统降雨泉流量响应规律--以贵州后寨典型小流域为例[J]. J4, 2010, 40(5): 1083-1089.
[9] 朱章显,杨振强. 巴布亚新几内亚新生代埃达克岩及成矿意义[J]. J4, 2008, 38(4): 618-0623.
[10] 刘亚剑，范继璋，李钟山，雷万杉. 吉林省小石人金矿区微量元素地球化学特征[J]. J4, 2008, 38(2): 202-0210.
[11] 辛 馨，杨俊鹏，赵奎涛，胡 克. 双台河口土壤中Mn、Zn和Rb的变化规律及其原因分析[J]. J4, 2007, 37(5): 983-0987.
[12] 朴寿成，张博文，于泽新，师 磊. 辽宁小塔子沟金矿床地球化学特征及找矿方向[J]. J4, 2007, 37(3): 432-0436.
[13] 高桂梅,苏 克,王文颖,甘树才,刘招君. 吉林省桦甸油页岩中稀土元素和微量元素的研究[J]. J4, 2006, 36(6): 974-0979.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
版权所有 © 《吉林大学学报(地球科学版)》编辑部
地址：长春市西民主大街938号(130026)　电话：+86-431-88502374；13756165364　E-mail: xuebao1956@jlu.edu.cn
本系统由北京玛格泰克科技发展有限公司设计开发