云南个旧锡多金属矿床锡石矿物化学特征及其成因意义

doi:10.13278/j.cnki.jjuese.20170058

Abstract

Abstract: The Gejiu tin polymetallic deposit is located in the west of the southeastern Yunnan tin ore belt, and is one of the largest tin polymetallic deposits in the world. As the main ore minerals in the Gejiu tin-polymetallic deposit,the mineral chemical characteristics of cassiterite have a great implication to the ore genesis. In this research, we studied the internal structure and the mineral chemical characteristics of cassiterites out of six types of ores in the Gejiu tin-polymetallic using the scanning electron microscopy and electron probe microscope analyzer. The results of scanning electron microscopy show that except the interlayer oxidation broken ore type cassiterites,the zonal structure is clearly developed within cassiterites. The results of electron probe microscope analyzer (EPMA) show that the variation range of the mass fraction of SnO₂ is 97.700%-101.728%, and the mass fractions of Ta₂O₅, FeO, ZrO₂ and HfO₂ are high, which indicates that these cassiterites may be precipitated in a high temperature environment. The value of (Fe+Mn)/(Nb+Ta) shows that the different types of cassiterites have the characteristics of hydrothermal cassiterites. Very low mass fractions of Nb₂O₅ and MnO in different types of cassiterites suggest that the ore-forming fluid may be derived from the high-fractionated granitic magma. The mass fractions of Na, Ta indicate that the mineralization occurred in an acid to weak acid environment. The gradually decreased In₂O₃ in different ores (including sulfide, skarn, tourmaline veinlet belt, tin-bearing dolomite, and interlayer oxidation types of ores) indicates that the ore forming temperature and pressure have decreased gradually. However, the average mass fractions of In₂O₃ in greisen type need further study. The change of the physicochemical conditions of magma hydrothermal fluid during the formation of cassiterite resulted in the formation of its internal zonal structure. The electron probe data shows that the chemical composition in the zonal structure of cassiterite is "serrated", indicating that the mineralization occurred in turbulence, so the cassiterite deposits have multi-stage characteristics.

Key words: mineral chemistry, electron probe microscope analyzer, cassiterite, Gejiu tin-polymetallic deposit

CLC Number:

P618.4

Tan Shucheng, Guo Xiangyu, He Xiaohu, Xie Zhipeng, Zhang Yahui, Li Huimin, Hao Shuang. Mineral Chemical Characteristics and Genesis of Cassiterite in Gejiu Tin-Polymetallic Deposit, Yunnan Province[J].Journal of Jilin University(Earth Science Edition), 2018, 48(3): 736-753.

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Mineral Chemical Characteristics and Genesis of Cassiterite in Gejiu Tin-Polymetallic Deposit, Yunnan Province

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