感应熔覆制备Mo2C颗粒增强CoCrFeNiMn高熵合金复合涂层的显微组织与摩擦学性能

doi:10.13229/j.cnki.jdxbgxb.20251045

摘要/Abstract

摘要：

使用感应熔覆技术首次成功制备了Mo₂C/CoCrFeNiMn高熵合金复合涂层。研究了Mo₂C颗粒对复合涂层的相组成、微观组织、显微硬度、常温和高温磨损性能的影响。结果表明：复合涂层中除了FCC相外，还存在Mo₂C相及析出碳化物相；Mo₂C颗粒的加入起到了晶粒细化、第二相强化和固溶强化的效果，同时还促进了小角度晶界和几何必要位错的形成，提高了涂层的显微硬度；常温下磨损表面形成的机械混合层和600 ℃高温下磨损表面形成的氧化釉质层起到了物理屏障的作用，增强了涂层的耐磨性。

关键词: 高熵合金, 感应熔覆, 涂层, Mo₂C, 耐磨性

Abstract:

In this study， Mo₂C/CoCrFeNiMn high-entropy alloy composite coating was successfully prepared for the first time by induction cladding technology. The effects of Mo₂C particles on the phase composition， microstructure， microhardness， room temperature and high temperature wear properties of the composite coating were studied. The results show that in addition to the FCC phase， there are Mo₂C phase and precipitated carbide phase in the composite coating. The addition of Mo₂C particles has the effect of grain refinement， second phase strengthening and solid solution strengthening. At the same time， it also promotes the formation of small angle grain boundaries and geometric necessary dislocations， and improves the microhardness of the coating. The mechanical mixed layer （MML） formed on the worn surface at room temperature and the oxidized enamel layer formed on the worn surface at 600 ℃ play a physical barrier role， which enhances the wear resistance of the coating.

Key words: high entropy alloy, induction cladding, coating, Mo₂C, wear resistance

中图分类号:

TG174.4

刘继波,陈子夏,李永亮,孟超,廉贞松. 感应熔覆制备Mo₂C颗粒增强CoCrFeNiMn高熵合金复合涂层的显微组织与摩擦学性能[J]. 吉林大学学报(工学版), 2026, 56(7): 1825-1833.

Ji-bo LIU,Zi-xia CHEN,Yong-liang LI,Chao MENG,Zhen-song LIAN. Microstructure and tribological properties of Mo₂C particle reinforced CoCrFeNiMn high entropy alloy composite coating prepared by induction cladding[J]. Journal of Jilin University(Engineering and Technology Edition), 2026, 56(7): 1825-1833.

图/表 9

图1

图2

表1

图3

图4

图5

图6

图7

表2

参考文献 33

[1]	Islam M A, Jiang J J, Xie Y. Assessment of low-stress and rolling contact abrasion of WC-based overlays for the restoration of undercarriage components[J]. Wear, 2021, 477: No.203820.
[2]	Peng Y B, Zhang W, Li T C, et al. Effect of WC content on microstructures and mechanical properties of FeCoCrNi high-entropy alloy/WC composite coatings by plasma cladding[J]. Surf Coat Technol, 2020, 385: No.125326.
[3]	Wang X H, Zhang M, Du B S, et al. Microstructure and wear properties of laser clad TiB₂+ TiC/Fe composite coating[J]. Surface Review and Letters, 2012, 19(5): No.1250052.
[4]	Wu H, Zhang S, Zhang H Y, et al. Exploration of wear and slurry erosion mechanisms of laser clad CoCrFeNi+x(NbC) high entropy alloys composite coatings[J]. Tribology International, 2024, 193: No.109405.
[5]	时海芳, 李德财, 白杨, 等. Ti含量对氩弧熔覆CoCrFeNiCuTi _x 高熵合金涂层组织及性能的影响[J].材料热处理学报, 2024, 45(3): 82-89.
	Shi Hai-fang, Li De-cai, Bai Yang, et al. Effect of Ti content on microstructure and properties of CoCrFeNiCuTi _x high entropy alloy coatings by argon arc cladding[J]. Transactions of Materials and Heat Treatment, 2024, 45(3): 82-89.
[6]	Xi S, Chen H, Zhou J, et al. Microstructure evolution and wear resistance of a novel ceramic particle-reinforced high-entropy alloy prepared by laser powder bed fusion[J]. Ceramics International, 2024, 50(4): 5962-5973.
[7]	Liang H, He R, Liu L, et al. Investigating the elastic, mechanical, and thermal properties of polycrystalline Mo₂C under high pressure and high temperature[J]. Ceramics International, 2023, 49(5): 7341-7349.
[8]	Mao X, Meng Q, Yuan M, et al. Wear performance of the Fe-Ni-WC-based impregnated diamond bit with Mo₂C-coated diamonds: effect of the interface layer[J]. Wear, 2023, 522: No. 204683.
[9]	Zhang X, Lei Q, Zhang M, et al. Mo₂C particle-reinforced CuCrZr composite with enhanced wear and softening resistance[J]. Materials Characterization, 2023, 203: No.113077.
[10]	Wei M, Yu H L, Song Z Y, et al. Microstructural evolution, mechanical properties and wear behavior of in-situ TiC-reinforced Ti matrix composite coating by induction cladding[J]. Surf Coat Technol, 2021, 412: No.127048.
[11]	Chen X L, Qin X P, Zhu Z H, et al. Microstructural evolution and wear properties of the continual local induction cladding NiCrBSi coatings[J]. J Mater Process Technol, 2018, 262: 257-268.
[12]	Graf K, Tetzlaff U, Souza G B, et al. Effect of dilution on the microstructure and properties of CoCrMoSi alloy coatings processed on high-carbon substrate[J]. Materials Research, 2018, 22: No.e20180502.
[13]	Li K, Liang J, Zhou J. Microstructure and elevated temperature tribological performance of the CoCrFeNiMo high entropy alloy coatings[J]. Surf Coat Technol, 2022, 449: No.128978.
[14]	Wang Z, Wang G, Song Z, et al. Microstructure evolution, wear and corrosion behavior of WC reinforced CoCrFeNiMn high-entropy alloy composite coatings by induction cladding[J]. Surf Coat Technol, 2024, 486: No.130938.
[15]	Zhao S B, Yang L J, Huang Y M, et al. A novel method to fabricate Ni/WC composite coatings by laser wire deposition: processing characteristics, microstructural evolution and mechanical properties under different wire transfer modes[J]. Additive Manufacturing, 2021, 38: No.101738.
[16]	Peng Y B, Zhang W, Li T C, et al. Microstructures and wear-resistance of WC-reinforced high entropy alloy composite coatings by plasma cladding: effect of WC morphology[J]. Surface Engineering, 2021, 37(5): 678-687.
[17]	Su Z, Li J, Shi Y, et al. Effect of Y₂O₃ addition on the organization and tribological properties of Ni60A/Cr₃C₂ composite coatings obtained by laser-cladding[J]. Ceramics International, 2024, 50(10): 17261-17273.
[18]	Liang H, Hou J, Li X, et al. Micro-structures and dry sliding wear properties of novel AlCrFeNiMo_0.5-x(WC) high entropy alloy-ceramic composite coatings[J]. Intermetallics, 2024, 170: No.108328.
[19]	Lan X, Zhang H, Li Z B, et al. Preparation of fine-grained Mo-W solid solution alloys with excellent performances[J]. Materials Characterization, 2022, 191: No.112140.
[20]	Sun J, Ning S, Zhao J, et al. High entropy cemented carbide coupling high entropy ceramic and high entropy alloy[J]. Applied Materials Today, 2025, 42: No.102563.
[21]	Sun D, Cai Y, Zhu L, et al. High-temperature oxidation and wear properties of TiC-reinforced CrMnFeCoNi high entropy alloy composite coatings produced by laser cladding[J]. Surf Coat Technol, 2022, 438: No.128407.
[22]	Geng Y, Chen W, Cheng J, et al. Selective solid solution tailoring mechanical and tribological synergy in heterogeneous single-phase high-entropy alloys at elevated temperatures[J]. Tribology International, 2022, 173: No.107617.
[23]	Liu H, Liu J, Chen P J, Microstructure and high temperature wear behaviour of in-situ TiC reinforced AlCoCrFeNi-based high-entropy alloy composite coatings fabricated by laser cladding[J]. Optics and Laser Technology, 2019, 118:140-150.
[24]	Zhang L J, Jiang Z K, Zhang M D, et al. Effect of solid carburization on the surface microstructure and mechanical properties of the equiatomic CoCrFeNi high-entropy alloy[J]. Journal of Alloys and Compounds, 2018, 769: 27-36.
[25]	Menezes P L, Nosonovsky M, Kailas S V. Friction and Wear, Tribology for Scientists and Engineers: From Basics to Advanced Concepts[M]. Berlin: Springer, 2013.
[26]	Pillari L K, Lessoway K, Bichler L. Reciprocating dry sliding friction and wear behavior of B319 aluminum alloy-graphene composites[J]. Tribology International, 2024, 192: No.109334.
[27]	Li Y, Liu H, Liu X, et al. Microstructure, thermostability and tribological behavior of composite CoCrFeNiTi_x high-entropy alloy coatings fabricated by laser cladding[J]. Optik, 2023, 283: No.170899.
[28]	Li Xin-Cheng, Pang Ming. Research on the effect of the variation of laser power on the contour control and performance control of laser cladding Ni60CuMo/IN718 coating on RuT300[J]. Materials Today Communications, 2024, 38: No.107856.
[29]	Alidokht S A, Wu L, Bessette S, et al. Microstructure and tribology of cold spray additively manufactured multimodal Ni-WC metal matrix composites[J]. Wear, 2024, 538: No.205218.
[30]	刘晓波, 杨淼, 周德坤, 等. (Mg_2Si+Si)/Al复合材料的组织和耐磨性[J]. 吉林大学学报: 工学版, 2024, 54(4): 938-946.
	Liu Xiao-bo, Yang Miao, Zhou De-kun, et al. Microstructure and wear resistance of (Mg2Si+Si)/Al composites[J]. Journal of Jilin University(Engineering and Technology Edition),2024, 54(4): 938-946.
[31]	Xin B, Zhang A, Han J, et al. The tribological properties of carbon doped Al_0.2Co_1.5CrFeNi_1.5Ti_0.5 high entropy alloys[J]. Wear, 2021, 484: No.204045.
[32]	Sun H, Jia J, Zhang B, et al. Tribological characteristic of atmospheric plasma sprayed NiAl coatings with addition of nanostructured MoO₃/Bi₂O₃ binary oxides as high temperature lubricant[J]. Journal of Materials Research and Technology, 2022, 17: 1662-1671.
[33]	Geng Y, Chen W, Cheng J, et al. Selective solid solution tailoring mechanical and tribological synergy in heterogeneous single-phase high-entropy alloys at elevated temperatures[J]. Tribology International, 2022, 173: No.107617.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed

Position	Cr	Mn	Fe	Co	Ni	Mo	C
A1	18.14	17.94	24.90	19.72	19.30	-	-
A2	18.28	18.02	25.34	19.13	19.23	-	-
B1	16.52	17.44	24.69	18.66	18.32	4.37	-
B2	6.57	3.18	11.79	6.14	4.56	24.69	43.07
B3	13.21	10.39	12.58	5.37	5.23	6.52	46.7
C1	11.24	14.65	36.83	15.82	16.90	4.56	-
C2	4.42	2.27	17.01	3.96	3.40	25.43	43.51
C3	11.51	7.36	16.56	3.22	2.97	11.56	46.82

Position	Cr	Mn	Fe	Co	Ni	Mo	W	O
P1	14.17	15.13	10.36	11.42	10.79	-	0.18	37.95
P2	11.26	11.78	10.79	10.73	10.22	4.67	0.46	40.09
P3	9.16	9.92	12.83	9.41	8.72	5.79	0.58	43.59
P4	7.78	8.23	6.89	6.75	6.88	-	1.74	61.73
P5	5.49	6.47	5.07	6.59	6.17	6.48	1.80	61.93
P6	4.23	4.52	7.66	4.91	4.75	9.29	1.86	62.78

感应熔覆制备Mo₂C颗粒增强CoCrFeNiMn高熵合金复合涂层的显微组织与摩擦学性能

Microstructure and tribological properties of Mo₂C particle reinforced CoCrFeNiMn high entropy alloy composite coating prepared by induction cladding

RICH HTML

PDF (PC)

摘要/Abstract

引用本文

使用本文

图/表 9

参考文献 33

相关文章 15

Metrics

本文评价

推荐阅读 0

[1]	王向阳,刘宇,杜家坤,陈泓,解方喜,芦大佑. 隔热涂层活塞对汽油机性能的影响[J]. 吉林大学学报(工学版), 2025, 55(9): 2828-2836.
[2]	刘晓波,杨淼,周德坤. （Mg₂Si+Si）/Al复合材料的组织和耐磨性[J]. 吉林大学学报(工学版), 2024, 54(4): 938-946.
[3]	姜继海,赵存然,张冠隆,车明阳. 航空煤油柱塞泵摩擦副涂层材料摩擦性能[J]. 吉林大学学报(工学版), 2021, 51(1): 147-153.
[4]	庄蔚敏,王鹏跃,解东旋,陈延红. 基于连续损伤力学的铝车身涂层抗划伤能力[J]. 吉林大学学报(工学版), 2019, 49(3): 829-835.
[5]	熙鹏,丛茜,王庆波,郭华曦. 仿生条纹形磨辊磨损试验及耐磨机理分析[J]. 吉林大学学报(工学版), 2018, 48(6): 1787-1792.
[6]	郑孝义, 孙大千, 李欣, 都桂刚, 辛伟达, 任振安. NbAl₃强化Al-Nb熔覆层的组织与性能[J]. 吉林大学学报(工学版), 2018, 48(5): 1531-1536.
[7]	金敬福, 李杨, 陈廷坤, 丛茜, 齐迎春. 涂层弹性模量对结冰附着强度的影响[J]. 吉林大学学报(工学版), 2017, 47(5): 1548-1553.
[8]	孙伟, 李健, 贾师. 硬涂层复合结构非线性刚度及阻尼辨识[J]. 吉林大学学报(工学版), 2016, 46(4): 1156-1162.
[9]	张金波，佟金，马云海. 仿生肋条结构表面深松铲刃的磨料磨损特性[J]. 吉林大学学报(工学版), 2015, 45(1): 174-180.
[10]	庄蔚敏, 陈延红. 基于连续损伤力学的表面涂层损伤模拟[J]. , 2012, 42(04): 857-862.
[11]	戴晟, 左敦稳, 黎向锋, 程虎, 方志刚, 王珉, 缪宏. 2738模具钢表面激光熔覆Ni基WC复合涂层的摩擦磨损性能[J]. , 2012, 42(04): 924-929.
[12]	王国磊, 陈恳, 陈雁, 朱丽, 王力强, 颜华. 变参数下的空气喷枪涂层厚度分布建模[J]. 吉林大学学报(工学版), 2012, 42(01): 188-192.
[13]	刘晓波^1,2,赵宇光¹,杨雯¹,张家陶¹. (Mg₂Si+SiC_p)/Mg复合材料的耐磨性[J]. 吉林大学学报(工学版), 2011, 41(6): 1618-1624.
[14]	李光玉,苏颖超,付宇,连建设,赵宇光. 离心铸造条件对Mg₂Si/Al梯度复合材料组织与性能的影响[J]. 吉林大学学报(工学版), 2011, 41(05): 1295-1299.
[15]	刘晓波, 赵宇光, 刘雁. Mg2Si/Al梯度复合材料的耐磨性[J]. 吉林大学学报(工学版), 2011, 41(02): 371-0376.