Infrared-radiative ceramic materials for grain drying were prepared based on the characteristic infrared absorbance of grains. The sintering raw materials are mainly composed of Al2O3, SiO2, while Fe2O3 , CuO and Y2O3 are used as doping materials. The infrared radiances of the ceramics(mullite,mullite doped), which was measured by infrared radiator in the wave band range from 2.5 to 15 μm, are varied from 0.845 to 0.933. An optimized composition, which is obtained by using an orthogonal experimental design method, is as follows:mullite(Al2O3∶SiO2=3∶2), Fe2O3 2.5%, CuO 5%, and Y2O3 2.5%.