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甘氨酸燃烧法制备纳米晶CoFe2O4铁氧体及烧结温度对其磁性能的影响

于 涛, 王冬梅, 王向群, 周建伟   

  1. 吉林大学 物理学院, 长春 130021
  • 收稿日期:2008-05-30 修回日期:1900-01-01 出版日期:2009-05-26 发布日期:2009-06-23
  • 通讯作者: 王向群

Influence of Thermal Annealing on Magnetic Properties of Nanostructured CoFe2O4 Ferrite Prepared by Combustion Method

YU Tao, WANG Dong mei, WANG Xiang qun, ZHOU Jian wei   

  1. College of Physics, Jilin University, Changchun 130021, China
  • Received:2008-05-30 Revised:1900-01-01 Online:2009-05-26 Published:2009-06-23
  • Contact: WANG Xiang qun

摘要: 利用甘氨酸作为燃料和配合剂, 采用自蔓延燃烧法制备纳米晶钴铁氧体, 并通过X射线衍射、 扫描电子显微镜和振动样品磁强计表征样品的结构和磁性能. 结果表明, 平均晶粒尺寸对样品的磁性能影响较大, 晶粒尺寸随烧结温度的变化而变化, 并得到了矫顽力Hc和比饱和磁化强度σs随烧结温度的变化曲线. 

关键词: 燃烧法, 纳米颗粒, 矫顽力, 比饱和磁化强度

Abstract: High coercivity magnetic nanoparticles (CoFe2O4) were synthesized by the combustion method with glycine as fuel followed by proper thermal annealing treatment to induce the crystallization. Structural and magnetic properties of the products were investigated via X\|ray diffractometry, a scanning electron microscopy, and a vibrating sample magnetometer, respectively. The magnetic properties of the products were greatly affected by the average crystalline size of the nanoparticles. By controlling the thermal annealing treatment, the coercivity (Hc) and saturation magnetization (σs) of the nanoparticles can be well tuned as a function of temperature. The range of the annealing temperature is from 500 ℃ to 900 ℃.

Key words: combustion method, nanoparticle, coercivity, saturation magnetization

中图分类号: 

  • O482.54