吉林大学学报(地球科学版) ›› 2018, Vol. 48 ›› Issue (1): 87-104.doi: 10.13278/j.cnki.jjuese.20160224

• 地质与资源 • 上一篇    下一篇

甘肃合作早子沟金矿床流体包裹体及硫铅同位素特征

陈瑞莉1, 陈正乐1,2, 伍俊杰1, 梁志录3, 韩凤彬2, 王永2, 肖昌浩2, 韦良喜4, 沈滔1   

  1. 1. 东华理工大学地球科学学院, 南昌 330013;
    2. 中国地质科学院地质力学研究所, 北京 100081;
    3. 甘肃省地矿局第三地质矿产勘查院, 兰州 730050;
    4. 中国地质大学(北京)研究生院, 北京 100037
  • 收稿日期:2017-02-23 出版日期:2018-01-26 发布日期:2018-01-26
  • 作者简介:陈瑞莉(1991-),女,硕士研究生,主要从事矿床学方面研究,E-mail:mary_wu901230@sina.com
  • 基金资助:
    国家自然科学基金重点项目(U1403292);中国地质调查局地质调查项目(1212011220936,12120114032401)

Fluid Inclusions and S-Pb Isotopes in Zaozigou Gold Deposit, Hezuo in Gansu Province

Chen Ruili1, Chen Zhengle1,2, Wu Junjie1, Liang Zhilu3, Han Fengbin2, Wang Yong2, Xiao Changhao2, Wei Liangxi4, Shen Tao1   

  1. 1. School of Earth Sciences, East China University of Technology, Nanchang 330013, China;
    2. Institute of Geomechanics, Chinese Academy of Geological Sciences, Beijing 100081, China;
    3. Third Institute Geological and Mineral Exploration of Gansu Province Bureau of Geology and Mineral Resources, Lanzhou 730050, China;
    4. Graduate School of China University of Geosciences, Beijing 100037, China
  • Received:2017-02-23 Online:2018-01-26 Published:2018-01-26
  • Supported by:
    Supported by Key Program of National Natural Science Foundation of China (U1403292) and Project of China Geological Survey (1212011220936,12120114032401)

摘要: 早子沟金矿床是西秦岭西段近年来发现的大型金矿床之一。矿床产于中三叠世古浪堤组中,矿体产出与中酸性岩脉关系密切;矿体受断裂控制,呈脉状、条带状,少数似层状产出。含金石英脉可分为两个成矿期次,分别为含金粗粒石英脉期和多金属硫化物-金石英期;金属硫化物主要为辉锑矿、黄铁矿、毒砂等。辉锑矿石英脉型金矿石中流体包裹体主要为富液相的气液两相流体包裹体,均一温度为129.8 ~324.3 ℃,平均为203.2 ℃,盐度(w(NaCl))为1.22%~10.73%,平均为6.04%,成矿流体的密度平均为0.90 g/cm3,矿床的成矿平均深度约为2.00 km;阴阳离子分析结果表明,流体包裹体液相成分主要为Na+-SO42--Cl-,单个流体包裹体激光拉曼显示流体包裹体中的气相成分主要为H2O、CO2和SO2,个别样品显示有CO和CH4,成矿流体为NaCl-H2O-CO2体系。流体包裹体研究揭示了早子沟金矿床辉锑矿-金成矿阶段的成矿流体为浅成中低温低盐度低密度流体,主要为岩浆水与地下水的混合热液,不同性质流体的混合作用和它们的沸腾作用是使金沉淀的重要因素。矿石中辉锑矿硫同位素组成很稳定,δ34SV-CDT值为-10.30‰~-8.10‰,平均为-9.33‰,表明硫主要为岩浆热液来源,并混有地层硫。矿石铅同位素组成显示206Pb/204Pb为18.166~19.027,207Pb/204Pb为15.608~15.741,208Pb/204Pb为38.249~39.275,矿石铅同位素组成为壳幔混合成因铅。根据早子沟金矿床特征,结合成矿流体性质及来源、成矿物质来源研究成果,推测甘肃早子沟金矿床应为岩浆期后低温热液金矿床。

关键词: 流体包裹体, S-Pb同位素, 早子沟金矿床

Abstract: The Zaozigou gold deposit is located at the west part of the Western Qinling Mountain range. It is one of the recently discovered large-scale gold deposits. The ore bodies are hosted in the Triassic Gulangti sedimentary rocks, and have a close relationship with the medium-acid dykes. The ore bodies and Indo-Sinian granitic veins are tightly controlled by faults; where the metal sulfides are stibnite, pyrite and arsenopyrite et al. Microscope observations showed that there are two-phase isolated primary inclusions in the gold-bearing quartz veins. Homogenization temperature falls in 129.8-324.3℃ with 203.2℃ as the average. The salinity w(NaCl) is 1.22%-10.73% with 6.04% as the average, indicating that the average density of ore-forming solution was 0.90 g/cm3, and the average depth was 2.00 km. The analyses of the fluid inclusion composition showed that the composition of gaseous phase is a NaCl-H2O-CO2 system, and the main fluid phase composition is a Na+-SO42--Cl- system. The Laser Raman spectroscopy revealed that the main composition in single inclusion are H2O,CO2 and SO2, only a few with CH4 and CO, suggesting that the ore-forming fluid in the Zaozigou deposit is a fluid of magmatic water mixed with ground water formed under low temperature, low salinity, and low density. The studies indicate that the mineralization has intimate relationship with two different proper fluid boiling and fluid mixing. The composition of the sulfur isotope is relatively stable, and the value of δ34SV-CDT changes from -10.30‰ to -8.10‰ with the average value of -9.33‰, suggesting that the sulfur was mainly derived from the deep seated magma and a little from sedimentary strata. The lead isotopic ratios of ore samples are 206Pb/204Pb 18.166-19.027, 207Pb/204Pb 15.608-15.741, 208Pb/204Pb 38.249-39.275, indicating the crust and mantle mixing lead. The characteristics of the deposit, the nature and resource of ore-forming fluids and material suggest that the Zaozigou gold deposit is a kind of epithermal deposit related with magmatism.

Key words: fluid inclusions, S-Pb isotope, Zaozigou gold deposit

中图分类号: 

  • P611.11
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