吉林大学学报(地球科学版) ›› 2019, Vol. 49 ›› Issue (1): 261-277.doi: 10.13278/j.cnki.jjuese.20180133

• 海洋地质与资源 • 上一篇    

南海边缘海多金属结核与大洋多金属结核对比

殷征欣1, 王海峰2, 韩金生3, 吕修亚1, 沈泽中1, 陈静1, 贺惠忠1, 谢安远1, 关瑶2,3,4, 董超1,5   

  1. 1. 国家海洋局南海调查技术中心, 广州 510275;
    2. 自然资源部海底矿产资源重点实验室, 广州 510075;
    3. 中国科学院矿物学与成矿学重点实验室, 广州 510640;
    4. 自然资源部第四海洋研究所, 广西 北海 536000;
    5. 国家海洋局南海维权技术与应用重点实验室, 广州 510275
  • 收稿日期:2018-05-25 发布日期:2019-01-18
  • 通讯作者: 关瑶(1987-),助理研究员,主要从事海洋矿产资源及矿床地球化学方面的研究,E-mail:guanyao@mail2.sysu.edu.cn E-mail:guanyao@mail2.sysu.edu.cn
  • 作者简介:殷征欣(1987-),男,工程师,博士,主要从事海洋地质方面的研究,E-mail:yinzhengxin@smst.gz.cn
  • 基金资助:
    自然资源部海底矿产资源重点实验室开放基金（KLMMR-2017-B-02）；海洋公益性行业科研专项（201505002）；国家海洋局南海分局海洋科学技术局长基金（1619）；国家海洋地质专项（DD20160147，DD20189643）；国家自然科学基金项目（41706055）；中国科学院矿物学与成矿学重点实验室合作基金（KLMM20170203）

Comparison Between the Marginal-Sea Polymetallic Nodules in South China Sea and Ocean Polymetallic Nodules

Yin Zhengxin1, Wang Haifeng2, Han Jinsheng3, Lü Xiuya1, Shen Zezhong1, Chen Jing1, He Huizhong1, Xie Anyuan1, Guan Yao2,3,4, Dong Chao1,5   

  1. 1. South China Sea Marine Survey and Technology Center, State Oceanic Administration, Guangzhou 510275, China;
    2. Key Laboratory of Marine Mineral Resources, Ministry of Natural Resources, Guangzhou 510075, China;
    3. Key Laboratory of Mineralogy and Metallogeny, Chinese Academy of Sciences, Guangzhou 510640, China;
    4. Fourth Institute of Oceanography, Ministry of Natural Resources, Beihai 536000, Guangxi, China;
    5. Key Laboratory of Technology and Application for Safeguarding of Marine Rights and Interests, State Oceanic Administration, Guangzhou 510275, China
  • Received:2018-05-25 Published:2019-01-18
  • Supported by:
    Supported by Open Project Fund of Key Laboratory of Marine Mineral Resources, Ministry of Natural Resources (KLMMR-2017-B-02), Marine Public Welfare Industry Research Projects (201505002), Marine Science and Technology of South China Sea Branch,SOA Director Fond (1619), National Marine Geology Special Project of China (DD20160147, DD20189643), National Natural Science Foundation of China(41706055) and Cooperation Project Fund of Key Laboratory of Mineralogy and Metallogeny, Chinese Academy of Sciences (KLMM20170203)

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摘要： 本文通过系统对比分析前人研究成果，研究了南海边缘海多金属结核的成矿特征，结果表明：南海边缘海结核的矿物组成与大洋结核相似，均主要由锰相矿物和铁相矿物组成，其中锰相矿物主要为水羟锰矿和钡镁锰矿，铁相矿物主要以无定型铁氧化/氢氧化物形式存在，另外南海边缘海结核中含有大量硅酸盐矿物，表明在南海结核成矿过程中受到大量的陆源碎屑矿物混杂；相对于大洋主要经济成矿区的多金属结核，南海边缘海多金属结核中主要的经济元素如Mn、Cu、Co、Ni和Zn质量分数较低，而亲陆源性元素如Fe、Ti、P、Nb、Pb、Rb、Sc、Ta、Sr、Th和REY（REE和Y）等质量分数较高；南海边缘海多金属结核的元素地球化学特征和REE配分模式显示其为水成成因，并呈现更低的Mn/Fe值；同时南海边缘海结核也具有较快的平均生长速率及较高的δCe正异常，表明其生长在更为氧化的海水环境。虽然较快的沉积物沉积速率和动荡的海水环境影响了南海边缘海结核的成矿，但大量陆源物质进入海洋也为南海边缘海结核提供了丰富的成矿物质来源，便于南海边缘海结核的快速生长成矿。南海边缘海结核富集有Fe、Ti、Pb、Rb、Th和REY等金属元素，同样可以作为极具潜力的海洋矿产资源。南海边缘海多金属结核具有其独特的地球化学特征，与大洋多金属结核存在着明显差异。

关键词: 多金属结核, 成矿特征, 矿物组成, 元素地球化学, 南海边缘海, 大洋

Abstract: With the discovery of more and more polymetallic nodule mineralization zones in the South China Sea (SCS) in recent years, the researches of marine polymetallic nodules in this area have become deeper. The SCS marginal-sea polymetallic nodules have their own unique characteristics, which are very different from those in the oceanic environment. Based on the comparative analysis of the previous research results, the authors studied the metallogenetic characteristics of the SCS polymetallic nodules, and provided theoretical guidance for the evaluation of the SCS submarine polymetallic mineral resources. The results show that the mineral composition of the SCS marginal nodules is basically similar to that of oceanic nodules, mainly composed of Mn-and Fe-phase minerals, but the SCS nodules contain a large amount of silicate minerals, indicating that they are greatly affected by terrestrial detrital minerals. Compared to the oceanic nodules in the main economic mineralization zones, the content of the main economic elements such as Mn, Cu, Co, Ni and Zn in the SCS nodules are relatively low, while the contents of terrestrial-derived elements such as Fe, Ti, P, Nb, Pb, Rb, Sc, Ta, Sr, Th and REY (REE and Y) are relatively high. The elemental geochemical characteristics and REE shale-normalized patterns of the SCS polymetallic nodules show that they are of hydrogenetic origin with lower Mn/Fe ratios, high average growth rate, and relatively higher positive δCe anomalies, indicating that the SCS nodules grew in more oxidizing seawater environment. Although the high sediment accumulation rate and turbulent seawater environment affect the mineralization of the SCS nodules, the entry of a large number of terrestrial material provides a rich source of metallogenetic material for the rapid growth of nodules. The SCS marginal polymetallic nodules are rich in a variety of economic metal elements, and can be used as potential marine mineral resources.

Key words: polymetallic nodules, metallogenic characteristics, mineral compositions, element geochemistry, Marginal-Sea in South China Sea, Oceans

中图分类号: 

  • P618.3
[1] Hein J R,Koschinsky A.Deep-Ocean Ferromanganese Crusts and Nodules[M]//2nd ed.Holland H D,Turekian K K.Treatise on Geochemistry.Amsterdam:Elsevier,2014:273-291.
[2] Koschinsky A,Halbach P.Sequential Leaching of Ferromanganese Precipitates:Genetic Implications[J].Geochimica et Cosmochimica Acta,1995,59:5113-5132.
[3] Hein J R,Mizell K,Koschinsky A,et al.Deep-Ocean Mineral Deposits as a Source of Critical Metals for High-and Green-Technology Applications:Compari-son with Land-Based Resources[J].Ore Geology Reviews,2013,51:1-14.
[4] Rona P A.The Changing Vision of Marine Minerals[J].Ore Geology Reviews,2008,33:618-666.
[5] Bau M,Schmidt K,Koschinsky A,et al.Discriminating Between Different Genetic Types of Marine Ferro-Manganese Crusts and Nodules Based on Rare Earth Elements and Yttrium[J].Chemical Geology,2014,381:1-9.
[6] Von Stackelberg U.Manganese Nodules of the Peru Basin[M]//Cronan D S.Handbook of Marine Mineral Deposits.Boca Raton:CRC Press,2000:197-238.
[7] De Carlo E H.Paleoceanographic Implications of Rare Earth Element Variability Within a Fe-Mn Crust from the Central Pacific Ocean[J].Marine Geology,1991,98:449-467.
[8] Hein J R,Spinardi F,Oka Moto N,et al.Critical Metals in Manganese Nodules from the Cook Islands EEZ,Abundances and Distributions[J].Ore Geology Reviews,2015,68:97-116.
[9] Hein J R.Manganese Nodules[M]//Harff J,Meschede M,Petersen S,et al.Encyclopedia of Marine Geosciences.Dordrecht:Springer,2016:408-412.
[10] Conrad T,Hein J R,Paytan A,et al.Formation of Fe-Mn Crusts Within a Continental Margin Environment[J].Ore Geology Reviews,2016,87:25-40.
[11] Hlawatsch S,Garbe-Schonberg C D,Lechtenberg F,et al.Trace Metal Fluxes to Ferromanganese Nodules from the Western Baltic Sea as a Record for Long-Term Environmental Changes[J].Chemical Geology,2002,182(2):697-709.
[12] Anufriev G S,Boltenkov B S.Ferromanganese Nodules of the Baltic Sea:Composition,Helium Isotopes,and Growth Rate[J].Lithology and Mineral Resources,2007,42(3):240-245.
[13] Lysyuk G,Lysyuk A.Mineralogy and Geochemistry of the Ferromanganese Nodules of Baltic Sea[J].Geochimical et Cosmochimica Acta Supplement,2009,73(13):A808.
[14] González F J,Somoza L,Lunar R,et al.Fe-Mn Nodules Associated with Hydrocarbon Seeps:A New Discovery in the Gulf of Cadiz (Eastern Central Atlantic)[J].Episodes,2007,30(3):187.
[15] Amakawa H,Ingri J,Masuda A,et al.Isotopic Compositions of Ce,Nd,and Sr in Ferromanganese Nodules from the Pacific and Atlantic Oceans,the Baltic and Barents Seas,and the Gulf of Bothnia[J].Earth and Planetary Science Letters,1991,105(4):554-565.
[16] Bazilevskaya E S,Skolotnev S G.Fe-MnNodules of the Mendeleev Ridge,Arctic Ocean:Part 2[J].Doklady Earth Sciences,2015,464:1015-1017.
[17] 张振国.南海北部陆缘多金属结核地球化学特征及成矿意义[D].北京:中国地质大学,2007. Zhang Zhenguo.Approach to Geochemical Characteri-stics and Minerogenetic Environment of Polymetallic Nodules from the Northern Continental Margin of the South China Sea[D].Beijing:China University of Geosciences,2007.
[18] 吴长航.南海北部陆缘大型多金属结核的生长及元素地球化学特征研究[D].北京:中国地质大学,2009. Wu Changhang.Research on the Growth and Elemental Geochemical Characteristics of Large-Scale Polymetallic Nodules from the Northern Continental Margin of the South China Sea[D].Beijing:China University of Geosciences,2009.
[19] 张振国,方念乔,杜远生,等.南海西北陆缘多金属结核地球化学特征及成因[J].地球科学:中国地质大学学报,2009,34(6):955-962. Zhang Zhenguo,Fang Nianqiao,Du Yuansheng,et al.Geochemical Characteristics and Their Causative Mechanism of Polymetallic Nodules from the Northwest Continental Margin of the South China Sea[J].Earth Science:Journal of China University of Geosciences,2009,34(6):955-962.
[20] 张振国,高莲凤,沈鹏飞,等.南海西北陆缘新型多金属结核的发现及意义[J].海洋地质动态,2010,26(4):32-35. Zhang Zhenguo,Gao Lianfeng,Shen Pengfei,et al.Discovery and Implication of New-Type Polymetallic Nodules at the Northwest Continental Margin of the South China Sea[J].Marine Geology Letters,2010,26(4):32-35.
[21] 张振国,高莲凤,李昌存,等.多金属结核/结壳中稀土元素的富集特征及其资源效应[J].中国稀土学报,2011,29(5):630-636. Zhang Zhenguo,Gao Lianfeng,Li Changcun,et al.Enrichment Characteristics and Resource Effects of Rare Earth Elements in Polymetallic Nodules/Crusts[J].Journal of the Chinese Society of Rare Earths,2011,29(5):630-636.
[22] 张振国,杜远生,吴长航,等.南海西北陆缘大型多金属结核的生长过程及其对晚新生代古海洋环境变化的响应[J].中国科学:地球科学,2013,43(7):1168-1178. Zhang Zhenguo,Du Yuansheng,Wu Changhang,et al.Growth of a Polymetallic Nodule from Northwes-tern Continental Margin of the South China Sea and Its Response to Changes in Paleoceanographical Environment of the Late Cenozoic[J].Science China:Earth Sciences,2013,43(7):1168-1178.
[23] 张振国,方念乔,杜远生,等.南海西北陆缘多金属结核地球化学及其与大洋结核的对比[J].海洋地质与第四纪地质,2008,28(4):51-56. Zhang Zhenguo,Fang Nianqiao,Du Yuansheng,et al.Comparison Between Northwestern Continental Margin of the South China Sea and Other Oceans of Geochemical Characteristics of Polymetallic Nodules[J].Marine Geology & Quaternary Geology,2008,28(4):51-56.
[24] Guan Y,Sun X M,Shi G Y,et al.Rare Earth Elements Composition and Constraint on the Genesis of the Polymetallic Crusts and Nodules in the South China Sea[J].Acta Geologica Sinica,2017,91(5):801-818.
[25] Zhong Y,Chen Z,González F J,et al.Composition and Genesis of Ferromanganese Deposits from the Northern South China Sea[J].Journal of Asian Earth Sciences,2017,138:110-128.
[26] Kennett J.Marine Geology[M].Englewood Cliffs:Prentice Hall,1982.
[27] 许东禹,金庆焕,梁德华.太平洋中部结核及其形成环境[M].北京:地质出版社,1994:140-150. Xu Dongyu,Jin Qinghuan,Liang Dehua.A Study of Polymetallic Nodules in the Central Pacific Ocean[M].Beijing:Geological Publishing House,1994:140-150.
[28] Koschinsky A,Hein J R.Marine Ferromanganese Encrustations:Archives of Changing Oceans[J].Elements,2017,13(3):177-182.
[29] Aplin A,Cronan D.Ferromanganese Oxide Deposits from the Central Pacific Ocean:Ⅱ:Nodules and Associated Sediments[J].Geochimica et Cosmochi-mica Acta,1985,49:437-451.
[30] Callender E,Bowser C.Manganese and Copper Geochemistry of Interstitial Fluids from Manganese Nodule-Rich Pelagic Sediments of the Northeastern Equatorial Pacific Ocean[J].American Journal of Science,1980,280:1063-1096.
[31] Landing W,Bruland K.Manganese in the North Pacific[J].Earth and Planetary Science Letters,1980,49:45-56.
[32] Miller S,Cronan D.ElementSupply to Surface Sediments and Interrelationships with Nodules Along the Aitutaki-Jarvis Transect,South Pacific[J].Journal of the Geological Society,1994,151:403-412.
[33] Glasby G,Emelyanov E,Zhamoida V,et al.Environ-ments of Formation of Ferromanganese Concretions in the Baltic Sea:A Critical Review[J].Geological Society of London,Special Publication,1997,119:213-237.
[34] 徐兆凯.东菲律宾海铁锰结壳(核)成因与古海洋环境响应[D].青岛:中国科学院研究生院(海洋研究所),2007. Xu Zhaokai.Origin and Paleoceanographic Environ-ments Response of Ferromanganese Crusts (Nodules) in the East Philippine Sea[D].Qingdao:Institute of Oceanology,China Academy of Science(Institute of Oceanology),2007.
[35] 邓晓东,刘军亮,蔡树群.南海西沙群岛陆架区的潮流特征分析[J].热带海洋学报,2013,32(4):8-12. Deng Xiaodong,Liu Junliang,Cai Shuqun.Analyses of the Tidal Current Characteristics on the Continental Shelf of Xisha Islands in the South China Sea[J].Journal of Tropical Oceanography,2013,32(4):8-12.
[36] 李志珍,张富元.南海深海铁锰微粒的元素地球化学特征[J].海洋通报,1990,9(6):41-50. Li Zhizhen,Zhang Fuyuan.Geochemistry of Elements in Ferromanganese Particles at Depths of South Sea[J].Marine Science Bulletin,1990,9(6):41-50.
[37] 鲍根德,李全兴.南海铁锰结核(壳)的元素地球化学研究[J].热带海洋,1991,10(3):44-50. Bao Gende,Li Quanxing.Geochemistry of Elements in Ferromanganese Nodules (Crusts) from the South China Sea[J].Tropic Oceanology,1991,10(3):44-50.
[38] 鲍根德,李全兴.南海铁锰结核(壳)的稀土元素地球化学[J].海洋与湖沼,1993,24(3):304-313. Bao Gende,Li Quanxing.Geochemistry of Rare Earth Elements in Ferromanganese Nodule (Crusts) of the South China Sea[J].Oceanologia et Limnologia Sinica,1993,24(3):304-313.
[39] 梁宏锋,姚德,刘新波,等.南海尖峰海山多金属结壳地球化学[J].海洋地质与第四纪地质,1991,11(4):49-58. Liang Hongfeng,Yao De,Liu Xinbo,et al.Geoche-mistey of Polymetallic Crust from Jianfeng Seamount,South China Sea[J].Marine Geology & Quaternary Geology,1991,11(4):49-58.
[40] Guan Y,Sun X,Ren Y,et al.Mineralogy,Geoche-mistry and Genesis of the Polymetallic Crusts and Nodules from the South China Sea[J].Ore Geology Reviews,2017,89:206-227.
[41] 王瑜,张振国.南海北部陆缘多金属结核的内部显微构造特征及其地质意义[J].河北联合大学学报(自然科学版),2011,33(4):5-8. Wang Yu,Zhang Zhenguo.Internal Microstructure Characteristics and Geological Significance of Polymetallic Nodules from the Northern Continental Margin of the South China Sea[J].Journal of Hebei Polytechnic University (Natural Science Edition),2011,33(4):5-8.
[42] 朱而勤,王琦.中国沿岸海域的铁锰结核[J].地质论评,1985,31(5):404-410. Zhu Erqin,Wang Qi.Ferromanganese Nodules in the Offshore Areas of China[J].Geological Review,1985,31(5):404-410.
[43] 姚伯初.中美合作调研南海地质专报[M].武汉:中国地质大学出版社,1994:34-191. Yao Bochu.The Geological Memoir of South China Sea Surveyed Jointly by China and the USA[M].Wuhan:China University of Geological Press,1994:34-191.
[44] 梁美桃,陈绍谋,吴必豪,等.南海海盆和陆坡锰结核的特征及地球化学的初步研究[J].热带海洋,1988,7(3):10-18. Liang Meitao,Chen Shaomou,Wu Bihao,et al.A Preliminary Study on Characteristics and Geochemistry of Manganses Nodules from the Basin and Continental Slope of the South China Sea[J].Tropic Oceanology,1988,7(3):10-18.
[45] 杨慧宁,陈忠,颜文,等.南海海域固体矿产资源与分布[C]//我国专属经济区和大陆架勘测研究专项学术.北京:海洋出版社,2002:102-109. Yang Huining,Chen Zhong,Yan Wen,et al.Solid Mineral Resource and Its Distribution in South China Sea Area[C]//Proceedings of China's EEZ and Continental Shelf Survey Conference.Beijing:China Ocean Press,2002:102-109.
[46] 林振宏,季福武,张富元,等.南海东北陆坡区铁锰结核的特征和成因[J].海洋地质与第四纪地质,2003,23(1):7-12. Lin Zhenhong,Ji Fuwu,Zhang Fuyuan,et al.Characteristics and Origin of Ferromanganese Nodules from the Northeastern Continental Slope of the South China Sea[J].Marine Geology & Quaternary Geology,2003,23(1):7-12.
[47] Guan Y,Sun X M,Jiang X D,et al.The Effect of Fe-Mn Minerals and Seawater Interface and Enrichment Mechanism of Ore-Forming Elements of Polymetallic Crusts and Nodules from the South China Sea[J].Acta Oceanologica Sinica,2017,36(6):34-46.
[48] Craig J D,Andrews J E,Meylan M A.Ferroman-ganese Deposits in the Hawaiian Archipelago[J].Marine Geology,1982,45:127-157.
[49] Hein J R,Koschinsky A,Bau M,et al.Cobalt-Rich Ferromanganese Crusts in the Pacific[M]//Cronan D S.Handbook of Marine Mineral Deposits.Boca Raton:CRC Press,2000:239-279.
[50] Usui A,Someya M.Distribution and Composition of Marine Hydrogenetic and Hydrothermal Manganese Deposits in the Northwest Pacific[M]//Nicholson K,Hein J R,Buhn B,et al.Manganese Minerali-zation:Geochemistry and Mineralogy of Terrestrial and Marine Deposits.London:Geological Society of London,Geological Society Special Publication,1997:177-198.
[51] Piper D Z.Rare Earth Elements in Ferromanganese Nodules and Other Marine Phases[J].Geochimica et Cosmochimica Acta,1974,38:1007-1022.
[52] Banakar V K.Deep-Sea Ferromanganese Deposits and Their Resource Potential for India[J].Journal of the Indian Institute of Science,2012,90(4):535-541.
[53] Dymond J,Lyle M,Finny B,et al.Ferromanganese Nodules from MANOP Sites H,S,and R-Control of Mineralogical and Chemical Composition by Multiple Accretionary Processes[J].Geochimica et Cosmochimica Acta,1984,48:931-949.
[54] Halbach P,Hebisch U,Scherhag C.Geochemical Variations of Ferromanganese Nodules and Crusts from Different Provinces of the Pacific Ocean and Their Genetic Control[J].Chemical Geology,1981,34(1/2):3-17.
[55] Jiang X,Lin X,Yao D,et al.Geochemistry of Lithium in Marine Ferromanganese Oxide Deposits[J].Deep Sea Research:Part I:Oceanographic Research Papers,2007,54:85-98.
[56] Bonatti E,Kraemer T,Rydell H.Classification and Genesis of Submarine Iron-Manganese Deposits[M]//Horn D R.Ferromanganese Deposits on the Ocean Floor.Washington D C:National Science Foundation,1972:149-166.
[57] 何高文,孙晓明,薛婷.太平洋多金属结核和富钴结壳地质地球化学特征与成矿机制对比[M].北京:地质出版社,2011:39-45. He Gaowen,Sun Xiaoming,Xue Ting.A Comparative Study of the Geology,Geochemistry and Metallogenetic Mechanism of Polymetallic Nodules and Cobalt-Rich Crusts from the Pacific Ocean[M].Beijing:Geological Publishing House,2011:39-45.
[58] Koschinsky A,Hein J R.Uptake of Elements from Seawater by Ferromanganese Crusts:Solid-Phase Associations and Seawater Speciation[J].Marine Geology,2003,198:331-351.
[59] Murray J W,Dillard J G.The Oxidation of Cobalt:Ⅱ:Adsorbed on Manganese Dioxide[J].Geochimica et Cosmochimica Acta,1979,43:781-788.
[60] Goldberg E D,Koide M,Schmitt R A.Rare-Earth Distributions in the Marine Environment[J].Journal of Geophysical Research,1963,68(14):4209-4217.
[61] Takahashi Y,Manceau A,Geoffroy N,et al.Chemical and Structural Control of the Partitioning of Co,Ce,and Pb in Marine Ferromanganese Oxides[J].Geochimica et Cosmochimica Acta,2007,71:984-1008.
[62] Halbach P,Kriete C,Prause B,et al.Mechanisms to Explain the Platinum Concentration in Ferroman-ganese Seamount Crusts[J].Chemical Geology,1989,76(1/2):95-106.
[63] Hein J R,Koschinsky A,Halliday A N.Global Occurrence of Tellurium-Rich Ferromanganese Crusts and a Model for the Enrichment of Tellurium[J].Geochimica et Cosmochimica Acta,2003,67:1117-1127.
[64] Bau M,Koschinsky A,Dulski P,et al.Comparison of the Partitioning Behaviours of Yttrium,Rare Earth Elements and Titanium Between Hydrogenetic Marine Ferromanganese Crusts and Seawater[J].Geochimica et Cosmochimica Acta,1996,60(10):1709-1725.
[65] Jiang X J,Lin X H,Yao D,et al.Enrichment Mechanisms of Rare Earth Elements in Marine Hydrogenic Ferromanganese Crusts[J].Science China:Earth Sciences,2011,54(2):197-203.
[66] Jochum K P,Seufert H M,Spettel B,et al.The Solar-System Abundances of Nb,Ta,and Y,and the Relative Abundances of Refractory Lithophile Elements in Differentiated Planetary Bodies[J].Geochimica et Cosmochimica Acta,1986,50(6):1173-1183.
[67] McLennan S M.Rare Earth Elements in Sedimentary Rocks:Influence of Provenance and Fedimentary Processes[J].Review in Mineralogy and Geochemi-stry,1989,21(1):169-200.
[68] 武光海,周怀阳,杨树锋,等.富钴结壳生长过程中铁锰氧化物矿物组合的变化[J].矿物学报,2001,21(2):137-143. Wu Guanghai,Zhou Huaiyang,Yang Shufeng,et al.Variations in Fe-Mn Oxide Mineral Assemblage in Co-Rich Crust During Its Growth[J].Acta Mineralogica Sinica,2001,21(2):137-143.
[69] Frank D J,Meylan M A,Craig J D,et al.Ferroman-ganese Deposits of the Hawaiian Archipelago[M].Hawaii:Hawaii Institute of Geophysics,University of Hawaii,1976:HIG-76-4.
[70] Friedrich G,Schmitz-Wiechowski A.Mineralogy and Chemistry of a Ferromanganese Crust from a Deep-Sea Hill,Central Pacific,"Valdivia" Cruise VA 132[J].Marine Geology,1980,37(1/2):71-90.
[71] 方银霞,金翔龙.东太平洋多金属结核的矿物组成及元素赋存特征[J].海洋与湖沼,2000,31(4):419-425. Fang Yinxia,Jin Xianglong.Mineral Composition and Occurrence Characteristics of Polymetallic Nodule in the Eastern Pacific Ocean[J].Oceanologia et Limnologia Sinica,2000,31(4):419-425.
[72] 许东禹,阎葆瑞.海底铁锰结核纹层和柱状构造成因的探讨[J].海洋地质与第四纪地质,1998,18(3):31-36. Xu Dongyu,Yan Baorui.Discussion on Laminar and Columnar Structures of Ferromanganese Nodules on the Sea Floor[J].Marine Geology & Quaternary Geology,1998,18(3):31-36.
[73] Wegorzewski A V,Kuhn T.The Influence of Suboxic Diagenesis on the Formation of Manganese Nodules in the Clarion Clipperton Nodule Belt of the Pacific Ocean[J].Marine Geology,2014,357:123-138.
[74] Menendez A,James R,Shulga N,et al.Linkages Between the Genesis and Resource Potential of Ferromanganese Deposits in the Atlantic,Pacific,and Arctic Oceans[J].Minerals,2018,8(5):197.
[75] Halbach P E,Jahn A,Cherkashov G.Marine Co-Rich Ferromanganese Crust Deposits:Description and Formation,Occurrences and Distribution,Estimated World-Wide Resources[M]//Sharma R.Cham Switzerland:Deep-Sea Mining.Cham,Switzerland:Springer International Publishing AG,2017:65-141.
[76] Usui A,Mita N.Geochemistry and Mineralogy of a Modern Buserite Deposit from a Hot Spring in Hokkaido,Japan[J].Clays and Clay Minerals,1995,43(1):116-127.
[77] Koschinsky A,Hein J R.Uptake of Elements from Seawater by Ferromanganese Crusts:Solid-Phase Associations and Seawater Speciation[J].Marine Geology,2003,198(3/4):331-351.
[78] 王海峰,刘永刚,朱克超.中太平洋海盆多金属结核分布及其与CC区中国多金属结核开辟区多金属结核特征对比[J].海洋地质与第四纪地质,2015,35(2):73-79. Wang Haifeng,Liu Yonggang,Zhu Kechao.Polymetallic Nodules Distribution on the Central Pacific Basin and Comparison with Nodules in China Pioneer Area,CC Zone[J].Marine Geology & Quaternary Geology,2015,35(2):73-79.
[79] Marchig V,Stackelberg U V,Hufnagel H,et al.Compositional Changes of Surface Sediments and Variability of Manganese Nodules in the Peru Basin[J].Deep Sea Research Ⅱ:Topical Studies in Oceanography,2001,48(17/18):3523-3547.
[80] 何高文,邓希光,杨胜雄.中印度洋海盆多金属结核地质特征[J].海洋地质与第四纪地质,2011,31(2):21-30. He Gaowen,Deng Xiguang,Yang Shengxiong.Geological Characteristics of Polymetallic Nodules in the Central Indian Ocean and Comparison with Those from CC Zone in the Eastern Pacific[J].Marine Geology & Quaternary Geology,2011,31(2):21-30.
[81] Pratima J,Sridhar D I.A Comprehensive View of Manganese Nodules and Volcanics of the Central Indian Ocean Basin[J].Marine Georesources & Geotechnology,2008,26(4):231-258.
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