吉林大学学报(地球科学版) ›› 2020, Vol. 50 ›› Issue (5): 1418-1432.doi: 10.13278/j.cnki.jjuese.20190293

• 整装勘查区矿床成因与成矿作用研究专辑 • 上一篇    下一篇

甘肃花牛山铅锌矿床闪锌矿LA-ICP-MS微量元素组成及其地质意义

康凯1, 杜泽忠2,3, 于晓飞2,3, 李永胜2,3, 吕鑫2,3, 孙海瑞2,3, 杜轶伦2,3   

  1. 1. 中国地质大学(北京)地球科学与资源学院, 北京 100083;
    2. 中国地质调查局发展研究中心, 北京 100037;
    3. 自然资源部矿产勘查技术指导中心, 北京 100083
  • 收稿日期:2019-12-20 出版日期:2020-09-26 发布日期:2020-09-29
  • 通讯作者: 杜泽忠(1986-),男,高级工程师,博士,主要从事矿床学和找矿预测方面的研究,E-mail:27793009@qq.com E-mail:27793009@qq.com
  • 作者简介:康凯(1993-),男,硕士研究生,主要从事矿物学、岩石学、矿床学方面的研究,E-mail:kangk.beijing@qq.com
  • 基金资助:
    中国地质调查局项目（121201004000160901-83）

LA-ICP-MS Trace Element Analysis of Sphalerite in Huaniushan Pb-Zn Deposit in Gansu Province and Its Geological Significance

Kang Kai1, Du Zezhong2,3, Yu Xiaofei2,3, Li Yongsheng2,3, Lü Xin2,3, Sun Hairui2,3, Du Yilun2,3   

  1. 1. School of Earth Science and Mineral Resources, China University of Geosciences, Beijing 100083, China;
    2. Development and Research Center, China Geological Survey, Beijing 100037, China;
    3. Mineral Exploration Technical Guidance Center, Ministry of Natural Resources, Beijing 100083, China
  • Received:2019-12-20 Online:2020-09-26 Published:2020-09-29
  • Supported by:
    Supported by Project of China Geological Survey (121201004000160901-83)

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摘要： 天山—北山铅锌成矿带位于中亚造山带、塔里木板块和华北板块的交汇地带，是我国西北地区重要的金属资源产地之一。花牛山铅锌矿是天山—北山地区具典型成因意义的铅锌矿床，矿床成因机制一直存在争议。本文通过LA-ICP-MS对其闪锌矿微量组成进行分析，结果表明：该矿床闪锌矿形成于中—高温环境，以富集Fe、Mn、In、Cd、Cu等元素，贫Ga、Ge、Ni等元素为特征，其中Fe、Mn、In、Cd、Cu以类质同象的形式赋存于闪锌矿中，Ag、Pb以显微包裹体的形式赋存于闪锌矿中；其微量元素组成与岩浆热液为主导的矿床（都龙、黄岗梁、孟恩陶勒盖、赤土店）类似，除此之外，闪锌矿Tl元素质量分数以及Cd/Fe和Cd/Mn值均显示岩浆热液属性，在微量元素判别图中样品也落入岩浆热液区域。野外调研发现，矿体底部未见角砾状和网脉状矿体，矿体均发育在岩性界面及层间破碎带中。结合矿床地质特征、闪锌矿微量元素地球化学特征，认为花牛山铅锌矿床成因类型属于中高温岩浆热液型。

关键词: 天山—北山铅锌成矿带, 花牛山铅锌矿, 闪锌矿, 微量元素, LA-ICP-MS

Abstract: Tianshan-Beishan Pb-Zn metallogenic belt is located in the intersection of Central Asian orogenic belt, Tarim Craton,and North China craton, which is one of the important metal resources in Northwest China. Huaniushan Pb-Zn deposit is a typical genetic deposit in Tianshan-Beishan area. The results of LA-ICP-MS analysis on the trace element composition of sphalerite show that the sphalerite was formed in the medium-high temperature environment and characterized by rich in Fe, Mn, Cd, In, Cu and poor in Ga,Ge,Ni. Among them, Mn, Fe, In, Cd, Cu are in the lattice of sphalerite in the form of isomorphism, whereas Ag and Pb may exist in the form of micro-inclusions. The trace element composition is similar to that of the magmatic hydrothermal deposits (Dulong, Huanggangliang, Meng'entaolegai,Chitudian);in addition, the mass fraction of Tl element and the values of Cd/Fe and Cd/Mn of sphalerite show magmatic hydrothermal properties, and the trace element discrimination figure also falls into magmatic hydrothermal region. The field investigation shows that there are no brecciated or reticular ore bodies at the bottom of the deposit, and the ore bodies are developed in the lithologic interfaces and interlayer fracture zones. Based on the geological characteristics of the deposit and the geochemistry of sphalerite, it is conclude that the genetic type of Huaniushan Pb-Zn deposit belongs to magmatic hydrothermal type formed at medium-high temperature.

Key words: Tianshan-Beishan Pb-Zn metallogenic belt, Huaniushan Pb-Zn deposit, sphalerite, trace elements, LA-ICP-MS

中图分类号: 

  • P618.42
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