吉林大学学报(地球科学版) ›› 2023, Vol. 53 ›› Issue (4): 1001-1015.doi: 10.13278/j.cnki.jjuese.20220104

• 地质与资源 •    下一篇

大杨树盆地南部坳陷九峰山组烃源岩地球化学特征及油气来源

付丽 1, 2   

  1. 1.大庆油田有限责任公司勘探开发研究院,黑龙江 大庆 163712
    2.黑龙江省陆相页岩油重点实验室,黑龙江 大庆 163712
  • 收稿日期:2022-04-14 出版日期:2023-07-26 发布日期:2023-08-09
  • 作者简介:付丽(1972—),女,高级工程师,主要从事油气资源评价及油气地球化学方面的研究,E-mail:flidy@petrochina.com.cn
  • 基金资助:
    国家科技重大专项(2016E-0202)

Geochemical Characteristics of Source Rocks and Oil Origins of Jiufengshan Formation in Southern Depression of Dayangshu Basin

Fu Li 1, 2   

  1. 1. Exploration and Development Research Institute of PetroChina Daqing Oilfield Co., Ltd., Daqing 163712,Heilongjiang, China
    2. Heilongjiang Provincial Key Laboratory of Continental Shale Oil,Daqing 163712,Heilongjiang, China
  • Received:2022-04-14 Online:2023-07-26 Published:2023-08-09
  • Supported by:
    the National Science and Technology Major Projects (2016E-0202)

摘要: 大杨树盆地勘探和研究程度较低,但近年来在其南部坳陷九峰山组部署的多口探井中获得了工业油流,显示出良好的勘探远景。目前对研究区九峰组烃源岩及油气来源缺乏系统地研究和认识,本文利用有机碳、岩石热解、气相色谱-质谱、碳同位素等地球化学分析资料,评价了九峰山组烃源岩生烃潜力,分析了原油性质,并探讨了油气来源。结果表明:九峰山组一段(九一段)和九峰山组三段(九三段)发育一般—优质的烃源岩,w (TOC)分别平均为1.76%和2.59%,w (S1+S2)分别平均为4.44 mg/g和7.36 mg/g,w (氯仿沥青“A”) 分别平均为0.21%和0.09%;九一段烃源岩有机质类型以Ⅱ1型为主,其次为Ⅰ型,而九三段以Ⅱ1型为主,其次为Ⅱ2型;九一段烃源岩镜质体反射率(Ro)主要为0.70%~1.60%,处于成熟—高成熟演化阶段,而九三段Ro主要为0.50%~1.10%,处于成熟演化阶段。烃源岩成熟生烃门限深度约为1 300 m,生烃高峰约为1 750 m,具有生烃早的特点。原油为轻—中质原油,具有高黏、高蜡、低硫、高饱和烃特点。原油富集碳的轻同位素,δ13C油为-30.40‰~-29.38‰,δ13C饱和烃为-30.78‰~-29.07‰,δ13C芳烃为-29.73‰~-27.91‰,具有以湖相腐泥型有机质为母质的特点。原油分子标志化合物的主峰碳为nC19和nC21,OEP(奇偶优势)为1.07~1.08,Pr/Ph为0.83~1.10;利用甾萜类标志物将原油划分为两类,其中第一类为YC1和Y3井原油,具有相对高的三环萜烷、C30D、Ts/Tm、C29Ts/C29藿烷、甾烷C27R/C29R、规则甾烷/藿烷、重排甾烷/规则甾烷、C29甾烷20S/20(S+R)、C29甾烷ββ/(ββ+αα)及低的β-胡萝卜烷特点,第二类为YX4和Y6井原油,具有高β-胡萝卜烷及相对低的甾萜烷值,表明第一类原油成熟度高于第二类,二者的沉积环境和母质来源上略有差异。油岩对比反映出第一类原油主要来源于九一段源岩,第二类原油主要来源于九三段源岩,反映该地区存在自生自储和下生上储2种类型油藏。

关键词: 大杨树盆地, 南部坳陷, 九峰山组, 烃源岩, 地球化学, 油气来源

Abstract: Dayangshu basin is a Late Mesozoic residual basin with a low degree of exploration and research. It shows a good exploration prospect with the industrial oil flows obtained from several wells in recent years in the southern depression. A systematic understanding of the source rocks and the hydrocarbon origin of Jiufengshan Formation is still uncertain. Based on the geochemical analysis data of source rocks and crude oils, including TOC、Rock-Eval、GC-MS, and carbon isotope, the hydrocarbon generation potential of source rocks of Jiufengshan formation are evaluated, the properties of crude oils and oil source are studied. The results show that medium-good source rocks are developed in the first member (K1j1) and the third member(K1j3) of Jiufengshan Formation, with w(TOC) of 1.76% and 2.59%, w( S1 + S2) of 4.44 mg/g and 7.36 mg/g, bitumen of 0.21% and 0.09% respectively. The organic matter type of the K1j1 is mainly type Ⅱ1 including some typeⅠ, K1j3 is mainly type Ⅱ1 including some typeⅡ2, and the vitrinite reflectance (Ro) of the source rocks in K1j1 is mainly 0.70% to 1.60%, at the mature to high mature evolution stage. Ro in K1j3 is mainly from 0.50% to 1.10% and at the mature evolution stage. The hydrocarbon generation threshold of the source rock is about 1 300 m, and the hydrocarbon generation peak is about 1 750 m. The source rock has the characteristics of early hydrocarbon generation. The crude oils are light to medium, characterized by high viscosity, high wax, low sulfur, and high saturated hydrocarbon. The crude oil enriches light carbon isotope with δ13Coil from -30.40‰ to -29.38‰, δ13C sat from -30.78‰ to -29.07‰, and δ13Caro from -29.73‰ to -27.91‰, which indicates the source of lacustrine algae. The main peaks of alkane in oil are nC19 and nC21, OEP is 1.07 to 1.08, and Pr / Ph is 0.83 to 1.10. The crude oil can be divided into two groups based on terpenoid steroid marker. Group one includes the crude oil of Wells YC1 and Y3, with relatively high tricyclic terpane, C30D, Ts/Tm, C29Ts/C29 hopane, sterane C27R/C29R, regular sterane / hopane, rearranged sterane / regular sterane, C2920S / 20 (S+R), C29ββ/(ββ++αα) and low β-carotene. Group two includes the crude oil of Well YX4 and Well Y6, with high β-carotene and relatively low sterane terpane ratios, indicating that the maturity of Well YC1 and Well Y3 oil is higher than that of Well YX4 and Well Y6, and there are slight differences in sedimentary environment and parent material source. The oil and rock correlation of biomarkers shows that the crude oil of Wells YC1 and Y3 mainly comes from the source rock of K1j1, and the crude oil of YX4 and Y6 wells mainly comes from the source rock of K1j3. The potential hydrocarbon accumulations in this area are source-reservoir integrated accumulations and lower source rocks generation-upward migration accumulations.

Key words: Dayangshu basin;Southern depression;Jiufengshan Formation;source rocks;geochemical, oil source

中图分类号: 

  • P618.13
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