不同侧基对磺化聚醚醚酮质子交换膜的影响

不同侧基对磺化聚醚醚酮质子交换膜的影响

刘晨光，钟双玲，赵成吉，那辉，吴忠文

吉林大学麦克德尔米德实验室，吉林大学化学学院，长春 130012

收稿日期:2005-03-04 修回日期:1900-01-01 出版日期:2006-01-26 发布日期:2006-01-26
通讯作者: 那辉

Influence of Different Side Groups on SPEEK Proton Exchange Membrane

LIU Chen-guang, ZHONG Shuang-ling, ZHAO Cheng-ji, NA Hui, WU Zhong-wen

Alan G MacDiarmid Institiute， College of Chemistry, Jilin University, Changchun 130012, China

Received:2005-03-04 Revised:1900-01-01 Online:2006-01-26 Published:2006-01-26
Contact: NA Hui

摘要/Abstract

摘要： 以特丁基对苯二酚和邻甲基对苯二酚分别制备两个系列磺化聚醚醚酮. 对聚合物及其膜的一些性能进行了研究，探讨了不同取代侧基对聚合物溶解性、热性能、力学性能和质子传导性等性能的影响.

关键词: 聚醚醚酮, 质子交换膜, 邻甲基, 叔丁基

Abstract: Two series of sulfonated poly(ether ether ketone)s based on tert-butylhydroquione and o-methylhydroquione were synthesized via aromatic nucleophilic substitution reaction. The polymers and their membranes were characterized by means of DSC， TGA， mechanics testing and other methods. The influences of different groups on solubility, thermal property, mechanical property and proton transmission of the polymers were studied.

Key words: sulfonated poly(ether ether ketone), proton exchange membrane, o-methyl, tert-butyl

中图分类号:

O631

刘晨光，钟双玲，赵成吉，那辉，吴忠文. 不同侧基对磺化聚醚醚酮质子交换膜的影响[J]. J4, 2006, 44(01): 101-104.

LIU Chen-guang, ZHONG Shuang-ling, ZHAO Cheng-ji, NA Hui, WU Zhong-wen. Influence of Different Side Groups on SPEEK Proton Exchange Membrane[J]. J4, 2006, 44(01): 101-104.

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