|
Analyzing Effect of Li+ and Sr2+ Co-doping on Electrochemical Performance of Oxygen Ion Conductor Na0.52Bi0.48Ti0.99Mg0.01O3-δ
KONG Minghui, LI Run, ZHU Pei, GUO Cuiting, YANG Qiang, LIU Runru
Journal of Jilin University Science Edition. 2025, 63 (4):
1185-1191.
We characterized Na0.52Bi0.48-2xLixSrxTi0.99Mg0.01O3-δ(x=0,0.005,0.010,0.015) polycrystalline oxygen ion conductors prepared at a sintering temperature of 1 000 ℃ by using X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman spectrum, and AC impedance spectroscopy to study the effect of the co-doping concentration of Li+ and Sr2+ on the crystal structure, microstructure and electrochemical properties of the series of the samples. The results show that with increase of co-doping concentration of Li+ and Sr2+, no obvious impurity peaks were observed in all samples, and the unit cell parameters and unit cell volumes first decreases and then increases with the increase of doping concentration. When x=0.010, the grain conductivity reaches its maximum value, which is about twice that of the undoped sample. When x=0.010, the apparent grain-boundary conductivity and the macroscopic grain-boundary conductivity of the sample reach their optimal values, which are superior to other doped samples.
Related Articles |
Metrics
|