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La0.7Ca0.3Mn1-xCuxO3的电输运特性

彭 刚1, 李冬妹1, 高忠民2   

  1. 1. 吉林大学 超硬材料国家重点实验室, 长春 130012; 2. 吉林大学 无机合成与制备化学国家重点实验室, 长春 130012
  • 收稿日期:2008-01-02 修回日期:1900-01-01 出版日期:2008-11-26 发布日期:2008-11-26
  • 通讯作者: 彭 刚

Electric Transport Properties of La0.7Ca0.3Mn1-xCuxO3

PENG Gang1, LI Dong mei1, GAO Zhong min2   

  1. 1. State Key Laboratory for Superhard Materials, Jilin University, Changchun 130012, China;2. State Key Laboratory of Inorganic Synthesis and Preparetive Chemistry, Jilin University, Changchun 130012, China
  • Received:2008-01-02 Revised:1900-01-01 Online:2008-11-26 Published:2008-11-26
  • Contact: PENG Gang

摘要: 通过固相反应法制备不同掺杂浓度的La0.7Ca0.3Mn1-xCuxO3(x=0~0.15)样品, 在77~300 K温度范围内测量了铜掺杂后样品电阻随温度的变化关系. 结果表明, 在未引入铜杂质时, 低温铁磁相的电阻率满足T2.5关系, 顺磁相符合小极化子近邻跳跃模型; 在低掺杂下, 铁磁区可用T4.5关系解释; 随着掺杂浓度的增加, 在铁磁区和顺磁区, 任何单一模型均与实验不相符, 表明高掺杂样品的电输运性质存在未知模型. 

关键词: La0.7Ca0.3Mn1-xCuxO3(, 钙钛矿, 电输运, 极化子

Abstract: La0.7Ca0.3Mn1-xCuxO3( bulk samples with different Cu contents (x=0~0.15) were prepared by solid reaction method. Temperature dependence of Cu doped samples was studied in a range of 77~300 K. The result indicates that the resistivity of the sample without Cu doped follows the T2.5 model in ferromagnetic phase at low temperatures, while in paramagnetic phase it obeys the small polaron hopping model. Low doped sample match the T4.5 model at low temperatures in ferromagnetic phase. With the doping content increasing, no single model satisfies our experiment in both ferromagnetic phase and paramagnetic phase. This indicates much more complicated electric transport mechanism of high doped samples.

Key words: La0.7Ca0.3Mn1-xCuxO3(, peroveskite, electric transport, polaron

中图分类号: 

  • O482.4