吉林大学学报(理学版)

• 材料科学 • 上一篇    下一篇

钠离子电池负极材料Na2Co2TeO6的合成及其电化学性质

陈红1, 刘子媛2, 张鑫1, 梁磊1, 洪源泽1, 王春忠3   

  1. 1. 北华大学 物理学院, 吉林 吉林 132013; 2. 吉林大学 物理学院, 长春130012;3. 吉林大学 新型电池物理与技术教育部重点实验室, 长春 130012
  • 收稿日期:2016-09-12 出版日期:2017-05-26 发布日期:2017-05-31
  • 通讯作者: 王春忠 E-mail:wcz@jlu.edu.cn

Synthesis and Electrochemical Properties of Na2Co2TeO6 as Negative Electrode Material for Sodium Ion Batteries

CHEN Hong1, LIU Ziyuan2, ZHANG Xin1, LIANG Lei1,HONG Yuanze1, WANG Chunzhong3   

  1. 1. College of Physics, Beihua University, Jilin 132013, Jilin Province, China;2. College of Physics, Jilin University, Changchun 130012, China; 3. Key Laboratory of Physics andTechnology for Advanced Batteries (Ministry of Education), Jilin University, Changchun 130012, China
  • Received:2016-09-12 Online:2017-05-26 Published:2017-05-31
  • Contact: WANG Chunzhong E-mail:wcz@jlu.edu.cn

摘要: 采用固相法合成纯相的Na2Co2TeO6材料. 利用X射线衍射(XRD)、 扫描电子显微镜(SEM)和X射线光电子能谱(XPS)研究其晶体结构和元素价态, 并用恒流充放电测试、 倍率及循环伏安测试研究该材料在3.0~0.01 V内的电化学性质和动力学性能. 结果表明:Na2Co2TeO6作为电池负极材料具有良好的循环性能, 稳定容量为200 mA·h/g, 充放电效率为95%; 该材料具有较好的倍率性能, 在电流密度500 mA/g下, 仍可保持50 mA·h/g的稳定容量.

关键词: 动力学性能, 电化学性质, 负极, 钠离子电池

Abstract: Na2Co2TeO6 was synthesized by solid state reaction and its structural and valence state of elements were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). Furthermore, the electrochemical and kinetic properties of the materials were tested by means of galvanostatic chargedischarge cycling, rate performance and cyclic voltammetry measurements between 30 V and 001 V. The results show that, as negative electrode material, Na2Co2TeO6 demonstrates good cycle performance with a reversible capacity of 200 mA·h/g and high coulombic efficiency of 95%. Meanwhile, the material shows good rate performance, and the stable capacity can still be maintained 50 mA·h/g under the current density of 500 mA/g.

Key words: sodiumion battery, kinetic property, cathode, electrochemical property

中图分类号: 

  • TM911