J4

• 环境科学 • 上一篇    

基于BP神经网络模型的催化湿式氧化正丁酸反应条件的优化

李 鱼1,2, 郑 爽1, 王江玲2, 陈 宇1   

  1. 1. 吉林大学 环境与资源学院, 长春 130012; 2. 华北电力大学 能源与环境研究中心, 北京 102206
  • 收稿日期:2008-08-11 修回日期:1900-01-01 出版日期:2009-03-26 发布日期:2009-03-26
  • 通讯作者: 李 鱼

Reaction Condition Optimization of Butyric Acid underCatalytic Wet Air Oxidation Based onBP Artificial Neural Network Model

LI Yu1,2, ZHENG Shuang1, WANG Jiangling2, CHEN Yu1   

  1. 1. College of Environment and Resources, Jilin University, Changchun 130012, China;2. Energy and Environmental Research Centre, North China Electric Power University, Beijing 102206, China
  • Received:2008-08-11 Revised:1900-01-01 Online:2009-03-26 Published:2009-03-26
  • Contact: LI Yu

摘要: 研究正丁酸原液TOC质量浓度、 催化剂用量、 反应温 度、 氧气分压对MnCe催化剂催化湿式氧化正丁酸恒温反应过程的影响, 建立了催化湿式氧化降解正丁酸恒温反应过程的BP神经网络模型. 经计算, 模型的模拟效率系数NSC=0.973 2>0.80, 表明所建模型可以较准确地预测催化湿式氧化过程中残余的正丁酸质量浓度; 在BP神经网络模型上研究了催化湿式氧化降解正丁酸恒温反应过程影响因素的最优取值, 结果表明, 在最优反应条件下, 催化湿式氧化降解正丁酸的效率可提高约20%.

关键词: BP神经网络, 催化湿式氧化, 正丁酸, 降解, 数学模拟与优化

Abstract: Effects of initial TOC of butyric acid, catalyst dosage, reaction temperature, and initial oxygen pressure on the degradation reaction process of butyric acid under catalytic wet air oxidation were investigated, and a BP artificial neural network model for the degradation process of butyric acid under catalytic wet air oxidation was established. The simulated efficiency factor of the model was calculated to be 0.973 2 (more than 0.80), indicating the model established could well and truly forecast the residual butyric acid in the degradation reaction process of catalyticwet air oxidation. Meanwhile, the reaction condition optimization of butyric acid under catalytic wet air oxidation based on the BP artificial neural network model was carried out, and the results show that the degradation efficiency of butyric acid under catalytic wet air oxidation was nearly enhanced by 20%.

Key words: BP artificial neural network, catalytic wet air oxidation, butyric acid, degradation, mathematic simulation and optimization

中图分类号: 

  • X132