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Catalytic Oxidation of Alcohols with H2O2 in Mild Conditions over Catalyst Cu2(OH)PO4

LIN Kai-feng, MENG Xiang-ju, SUN Zhen-hua, YANG Miao, JIANG Da-zhen, XIAO Feng-shou   

  1. College of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China
  • Received:2003-03-13 Revised:1900-01-01 Online:2003-07-26 Published:2003-07-26
  • Contact: XIAO Feng-shou

Abstract: The catalytic oxidation of alcohols with hydrogen peroxide over coppe r hydroxyphosphate Cu2(OH)PO4 was studied. The catalytic data show that catalyst Cu2(OH)PO4 is very active for the oxidation of alcohols, especially for α-alcohols. Some important factors associated with the catalytic activity and selectivity have been investigated extensively.

Key words: Cu2(OH)PO4, hydrogen peroxide, alcohol, catalytic oxidation

CLC Number: 

  • O643.1