新型不对称酞菁的制备与表征

J4 ›› 2010, Vol. 48 ›› Issue (1): 137-139.

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Synthesis and Characterization of Novel Unsymmetric Phthalocyanine

XIA Daocheng^1,2, YAO Jihuan¹, LI Wancheng³, BAI Qinglong², DU Guotong^2,3

1. College of Chemistry, Yuncheng University, Yuncheng 044000, Shanxi Province, China|2. School ofPhysics and Optoelectronic Technology, Dalian University
of Technology, Dalian 116024, |Liaoning Province, China;
3. State Key Laboratory of Integrated Optoelectronics, Co
llege of Physics, Jilin University, Changchun 130012, China

Received:2009-03-16 Online:2010-01-26 Published:2010-01-27
Contact: 杜国同 E-mail:dugt@dlut.edu.cn.

Abstract

Abstract:

A novel unsymmetric substituted phthalocyanine: 2(3)-(p-tertbutylphenoxy) copper phthalocyanine was obtained from a mixture of 4-(p-tertbutylphenoxy)phthalonitrile, 1,3-diiminoisoindoline and Cu(AcO)₂·2H₂O that was added to 1-pentanol under stirring. The obtained unsymmetric substituted phthalocyanine was characterized by mass spectrum (MS), ultravioletvisible (UV\|Vis) spectrum, infrared spectroscopy (IR) and elemental analysis. The results are in agreement with the proposed structures.

Key words: unsymmetric phthalocyanine, synthesis, characterization

CLC Number:

O613.2

JIA Dao-Cheng, TAO Ji-Huan, LI Mo-Cheng, BAI Jing-Long, DU Guo-Tong-. Synthesis and Characterization of Novel Unsymmetric Phthalocyanine[J].J4, 2010, 48(1): 137-139.

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Synthesis and Characterization of Novel Unsymmetric Phthalocyanine

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