溶剂效应对对苯醌C=O键伸缩振动费米共振的影响

Influence of Solvent Effect on Fermi Resonance of C=O Stretching Vibration

JIANG Yong heng¹, ZHANG Ya nan², LI Yue¹, ZHANG Liu yang¹, HUANG Bao kun¹, GAO Shu qin¹

1. College of Physics, Jilin University, Changchun 130021, China;2. College of Chemistry, Jilin University, Changchun 130012, China

Received:2008-05-27 Revised:1900-01-01 Online:2009-05-26 Published:2009-06-23
Contact: GAO Shu qin

Abstract

Abstract: The infrared spectra of p-benzoquinone were measured in 13 solvents. The rule of Fermi resonance was validated by Bertvan changing solvent method. The Fermi resonance mechanism studied by changing solvent method was explained by means of KBM equation and electron donor-receptor model. The relationship between Fermi resonance intensity ratio (R) and the solvent dielectric constant (ε) was given.

Key words: Fermi resonance, solvent effect, dielectric constant, infrared spectrum

CLC Number:

O435.1

JIANG Yong heng, ZHANG Ya nan, LI Yue, ZHANG Liu yang, HUANG Bao kun, GAO Shu qin. Influence of Solvent Effect on Fermi Resonance of C=O Stretching Vibration[J].J4, 2009, 47(03): 579-582.

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Influence of Solvent Effect on Fermi Resonance of C=O Stretching Vibration

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