2(3)-四-(2-异丙基-5-甲基苯氧基)酞菁铜的合成、 光特性及电化学性质

Synthesis, Optical and Electrochemical Properties of Copper Tetra-(2-isopropyl-5-methylphenoxy) Phthalocyanine

HE Wei¹,², MA Chunyu¹, CHENG Chuanhui¹,², YU Shukun²,FAN Zhaoqi², XIA Daocheng¹, DU Xiguang³, DU Guotong¹

1. School of Physics and Optoelectronic Technology of DUT, Dalian University of Technology, Dalian 116023, Liaoning Province, China; 2. State Key Laboratory of Integrated Optoelectronics, Jilin University, Changchun 130012, China; 3. School of Chemistry, Northeast Normal University, Changchun 130024, China

Received:2007-07-12 Revised:1900-01-01 Online:2008-07-26 Published:2008-07-26
Contact: DU Guotong

Abstract

Abstract: Copper tetra-(2-isopropyl-5-methylphenoxy) phthalocyanine was prepared and characterized by MS and elemental analysis. Its photoluminescence (PL) spectra show a peak centered at about 1 180 nm, which indicates that it can be used as a nearinfrared functional material. Electrochemistry shows the redox of this complex is oneelectron processes which include two ringbased reductions and one ringbased oxidation. The identities of these electrode processes were further revealed by performing spectroelectrochemical experiments.

Key words: copper phthalocyanine, phenoxy, photoluminescence, electrochemistry, spectroelectrochemistry

CLC Number:

O627.12

HE Wei,, MA Chunyu, CHENG Chuanhui,, YU Shukun,FAN Zhaoqi, XIA Daocheng, DU Xiguang, DU Guotong. Synthesis, Optical and Electrochemical Properties of Copper Tetra-(2-isopropyl-5-methylphenoxy) Phthalocyanine[J].J4, 2008, 46(04): 769-773.

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Synthesis, Optical and Electrochemical Properties of Copper Tetra-(2-isopropyl-5-methylphenoxy) Phthalocyanine

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