水热组合方法在合成亚磷酸镓中的应用

Abstract

Abstract: Three gallium(Ⅲ) phosphites and gallium phosphate were synthesized by hydrothermal/solvothermal combinative technique under autogeneou s pressure in the system of Ga-H₃PO₃-1,2-dap-EG/H₂O(1,2-dap: 1,2-diaminopropane, EG: ethyl glycol). Their structures were determined by means of singlecrystal Xray diffraction analysis, IR spectroscopy, inductively coupled plasma(ICP). In our work, we stressed the synthetic factors on the influence of the crystallization of such materials.

Key words: hydrothermal combinative technique, crystal structure, gallium phosphite, open-framework

CLC Number:

YANG Lei, ZHAO Xiao lei, ZHANG Ruyi, BI Wenyan, LI Suping. Application of Hydrothermal Combinative Technique to Synthesis of Gallium Phosphite[J].J4, 2009, 47(01): 125-129.

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Application of Hydrothermal Combinative Technique to Synthesis of Gallium Phosphite

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