新型钨-氧簇化合物［Ni(en)3］2(BO3)(WO4)2(3H3Ｏ)的水热合成

Hydrothermal Syntheses and Structure Characterization of a New Tungsten-Oxyg en Cluster ［Ni(en)₃］₂(BO,sub>3)(WO_４） ,sub>2(3H₃Ｏ)

CUI Wei^1,3, LI Ya-feng¹, GUO Yang-hong¹, LIU Wei², ZHU Guang-shan¹, QIU Shi-lun¹, ZHANG Li-ping^1,4

1. College of Chemistry, Jilin University, Changchun 130023, China； 2. College of Materials Science and Engineering, Jilin University, Changchun 130023, China； 3. Department of Chemical Engineering, Fushun Employee Technique College, Fu shun 113006, China； 4. Department of Foundation, Jilin Grain College, Changchun 130061, China

Received:2003-04-09 Revised:1900-01-01 Online:2003-10-26 Published:2003-10-26
Contact: QIU Shi-lun

Abstract

Abstract: A new tungsten-oxygen cluster ［Ni(en)₃］₂(BO3)(WO₄）₂(3H₃O) has been hy drothermally synthesized at a mild temperature. The results of X-ray single cry stal structure analysis indicate that the title compound crystallized in a trigo nal system and space group P-3m1 with a=b=0.9335(13) nm, c=1.2536(3) nm, α=90° ，β=90°，γ=120°， V=0.9461(3) nm³, Z=1, D_c=1.912 Mg/ m³, μ=7.104 mm^-1, F(000)=534, R=0.0323, R_W=0 .1459.

Key words: hydrothermal synthesis, crystal structure, polyoxometalate

CLC Number:

O614

CUI Wei, LI Ya-feng, GUO Yang-hong, LIU Wei, ZHU Guang-shan, QIU Shi-lun, ZHANG Li-ping. Hydrothermal Syntheses and Structure Characterization of a New Tungsten-Oxyg en Cluster ［Ni(en)₃］₂(BO,sub>3)(WO_４） ,sub>2(3H₃Ｏ)[J].J4, 2003, 41(04): 516-520.

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Hydrothermal Syntheses and Structure Characterization of a New Tungsten-Oxyg en Cluster ［Ni(en)₃］₂(BO,sub>3)(WO_４） ,sub>2(3H₃Ｏ)

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Hydrothermal Syntheses and Structure Characterization of a New Tungsten-Oxyg en Cluster ［Ni(en)3］2(BO,sub>3)(WO４） ,sub>2(3H3Ｏ)

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Hydrothermal Syntheses and Structure Characterization of a New Tungsten-Oxyg en Cluster ［Ni(en)₃］₂(BO,sub>3)(WO_４） ,sub>2(3H₃Ｏ)