吉林大学学报(地球科学版) ›› 2018, Vol. 48 ›› Issue (4): 1154-1164.doi: 10.13278/j.cnki.jjuese.20170046

• 地质与资源 • 上一篇    下一篇

钻孔岩心黏土混浊水电导率、黄铁矿、pH相关性分析及其在古沉积环境复原的应用:以渤海湾西岸平原DC01孔为例

方晶1, 王福2, 方雨婷3, 潘隆1, 李杨1, 胡克4, 齐乌云5, 王中良6   

  1. 1. 天津师范大学地理与环境科学学院, 天津 300378;
    2. 中国地质调查局天津地质调查中心, 天津 300170;
    3. 日本名古屋大学环境学研究科, 名古屋 464-8601;
    4. 中国地质大学(北京)海洋学院, 北京 100083;
    5. 中国社会科学院考古研究所, 北京 100710;
    6. 天津师范大学水资源与水环境重点实验室, 天津 300387
  • 收稿日期:2017-11-07 出版日期:2018-07-26 发布日期:2018-07-26
  • 通讯作者: 王福(1979-),男,研究员,博士,主要从事海岸带与第四纪地质环境研究,E-mail:wfu@cgs.cn E-mail:wfu@cgs.cn
  • 作者简介:方晶(1963-),男,副教授,博士,主要从事海岸带全新世环境演变的研究,E-mail:mdfangjing@163.com
  • 基金资助:
    国家自然科学基金项目（41476074）；中国地质调查局项目（121201006000182401）；天津师范大学博士基金（52XB1207）；天津市高等学校创新团队培养计划项目（TD12-5073）

Correlation Analysis of Conductivity (EC), w(FeS2), pH of Drilled Clay Water and Its Application in Paleo-Environment Restoration: A Case Study of DC01 Core on West Plain of Bohai Bay

Fang Jing1, Wang Fu2, Fang Yuting3, Pan Long1, Li Yang1, Hu Ke4, Qi Wuyun5, Wang Zhongliang6   

  1. 1. College of Geography and Environmental Science, Tianjin Normal University, Tianjin 300387, China;
    2. Tianjin Center, China Geological Survey, Tianjin 300170, China;
    3. Graduated School of Environmental Studies, Nagoya University, Nagoya 464-8601, Japan;
    4. School of Ocean Sciences, China University of Geosciences, Beijing 100083, China;
    5. Institute of Archaeology, Chinese Academy of Social Sciences, Beijing 100710, China;
    6. Tianjin Key Laboratory of Water Environment and Resources, Tianjin Normal University, Tianjin 300387, China
  • Received:2017-11-07 Online:2018-07-26 Published:2018-07-26
  • Supported by:
    Supported by National Natural Science Foundation of China(41476074),Project of China Geological Survey(121201006000182401),Doctoral Fund of Tianjin Normal University(52XB1207) and Innovation Team Training Plan of Tianjin Education Committee (TD13-5073)

PDF (PC)

330

摘要： 为探讨复原海岸平原沉积环境和精确划分海陆相地层的有效方法，对渤海湾西岸海河以南平原深达30 m的DC01孔岩心以约20 cm间距取样，测试黏土混浊水电导率（EC）、黄铁矿质量分数（w（FeS2））和pH值，并开展相关分析研究。结果显示，EC与w（FeS2）正相关（相关系数r为0.47），而EC与pH以及w（FeS2）与pH均负相关（r分别为-0.43和-0.52）。根据EC值的大小将DC01孔自下至上分成5个带（Ⅰ—Ⅴ），进一步分别对5个带的EC、w（FeS2）及pH做相关分析，结果显示，Ⅱ带相关性最为突出：EC与w（FeS2）的相关系数为0.83，极强正相关；EC与pH的相关系数为-0.77，强负相关；w（FeS2）与pH的相关系数为-0.45，呈中等程度负相关。根据Ⅱ带的EC和w（FeS2）极强正相关、且EC和w（FeS2）均明显偏高以及多发育黑色泥炭和腐殖质黏土等特征，推断Ⅱ带为受海水影响的盐沼环境；结合AMS14C测年结果，推测8 260~7 470 cal.B.P.期间，海水曾经影响到DC01孔的位置。另外，Ⅳ带的EC值也偏高，但w（FeS2）却较低，其EC与w（FeS2）的相关系数为-0.03，不呈正相关关系，其原因是因为接近地表的上部沉积物因淋溶作用，在Ⅳ带形成淀积层导致EC异常偏高；最上层的Ⅴ带为淋溶层，这样就导致钻孔上部（深6.7 m以上）Ⅳ带和Ⅴ带EC与w（FeS2）的相关性出现异常。因此在讨论沉积物上部沉积环境时，将EC与w（FeS2）综合分析可以更精确地划分钻孔岩心的沉积环境。

关键词: 渤海湾西岸平原, 黏土混浊水电导率, 黄铁矿质量分数, pH, 相关分析, 沉积环境

Abstract: In order to explore the effective method for the reconstruction of the ancient environment of coastal plains and accurately divide the marine and continental stratum, the core DC01(30 m depth) was taken from the south of the Haihe River in the west plain of the Bohai Bay,and sampled at intervals of 20 cm;The electric conductivity (EC), w(FeS2) and pH were measured, and the correlations between EC and pH, w(FeS2) and pH were analyzed. The results show that EC is positively correlated with w(FeS2) (r=0.47), while EC is negatively correlated with pH, and so is w (FeS2) (r=-0.43 and -0.52, respectively). According to the EC value, the core DC01 was divided into five bands from bottom to top, and the correlations between EC, w(FeS2) and pH were further analyzed. The results show that the correlation of band Ⅱ is most obvious, and its EC is positively correlated with w(FeS2) (r=0.83), but strongly negatively correlated with pH(r=-0.77), while w(FeS2) is moderately negatively correlated with pH (r=-0.45). According to the strong positive correlation between EC and w(FeS2), the high EC, w(FeS2) and abundant black peat and humus clay, we can infer that the band Ⅱ was developed in a salt marsh environment close to the seawater. Combined with the AMS14C dating result, seawater once affected this position during the period of 8 260-7 470 cal. B. P. In band Ⅳ, the EC is high, but w(FeS2) is very low, and the correlation between EC and w(FeS2) is negative(r=-0.03), such a pattern was caused by the leaching effect of the upper surface sediments. The uppermost band Ⅴ(6.7 m on top) is a leaching layer, therefore its correlation between EC and w(FeS2) is abnormal. Obviously, a comprehensive analysis of EC and w(FeS2) can give a more reliable result for the discussion of the upper sedimentary environment of a drilling core.

Key words: coastal lowland of west Bohai bay, caly-water electric conductivity, pyrite content, pH, correlation analysis, sedimentary environment

中图分类号: 

  • P736.2
[1] 王福,李建芬,陈永胜,等. QX01孔记录的渤海湾西岸沿海低地MIS3晚期以来的河道充填与环境演化[J]. 地学前缘,2016,23(4):301-309. Wang Fu, Li Jianfen, Chen Yongsheng, et al. Paleo-Environment Change and River Channel Infilling Since MIS3 Recorded by Drilling Core QX01 Taken from the Coastal Lowland of Bohai Bay[J]. Earth Science Frontiers,2016,23(4):301-309.
[2] 陈永胜,王宏,裴艳东,等. 渤海湾西岸晚第四纪海相地层划分及地质意义[J]. 吉林大学学报(地球科学版),2012,42(2):747-759. Chen Yongsheng, Wang Hong, Pei Yandong, et al. Division and Its Geological Significannce of the Late Quaternary Marine Sedimentary Beds in the West Coast of Bohai Bay, China[J]. Journal of Jilin University (Earth Science Edition),2012,42(2):747-759.
[3] 陈永胜,李建芬,王福,等. 渤海湾西岸现代岸线钻孔记录的全新世沉积环境与相对海面变化[J].吉林大学学报(地球科学版),2016,46(2):499-517. Chen Yongsheng, Li Jianfen, Wang Fu, et al. Records of Holocene Sedimentation Environment and Relative Sea Level by the Boreholes Collected Along the Present Shoreline of the West Coast of Bohai Bay, China[J]. Journal of Jilin University (Earth Science Edition), 2016,46(2):499-517.
[4] 方晶,杨永强,商志文,等. 硅藻Auliscus caelatus对渤海湾西北岸大吴庄埋藏牡蛎礁形成环境的复原[J].吉林大学学报(地球科学版),2012,42(增刊2):343-351. Fang Jing, Yang Yongqiang, Shang Zhiwen, et al. Reconstruction of the Environment by Auliscus caelatus in Dawuzhuang Buried Oyster Reef on Northwest Coast of Bohai Bay[J]. Journal of Jilin University (Earth Science Edition),2012,42(Sup.2):343-351.
[5] 方晶,王宏,王福,等. 渤海湾西北岸埋藏牡蛎礁礁顶上下沉积物中硅藻对"礁泥转换"古沉积环境的重建[J].沉积学报,2012,30(5):879-890. Fang Jing, Wang Hong, Wang Fu, et al. Diatom Analysis in the Top and Bottom Muddy Sediments of Buried Oyster Reef for the Reef-Mud Conversion Palaeoenvironmental Reconstruction, Northwest Bohai Bay[J]. Acta Sedimentologica Sinica,2012,30(5):879-890.
[6] 佐藤万寿美,横山卓雄. 黏土混濁水の電気伝導度による古環境の推定~関西国際空港ボーリング·コアの場合[J].地质学杂志,1992,98(9):825-839. Sato M, Yokoyama T. Analysis of Paleo-Environment Based on Electric Conductivity of the STICS-Water:On Two Drilled Cores at Osaka Bay, Japan[J]. The Geological Society of Japan, 1992,98(9):825-839.
[7] 内園立男,森勇一. 濃尾平野南部ボ-リングコアの粘土混浊水の電気伝導度およびpH測定に基づく堆積環境の推定[J]. 第四纪研究,2004,43(5):375-382. Uchizono T, Mori Y. Sedimentary Environmental Analysis Based on Electric Conductivity and pH of Stirred Clayer Drilling Cores into Water Recovered from the Southern Part of Nobi Plain Central Japan[J]. The Quaternary Research, 2004,43(5):375-382.
[8] 白神宏.FeS2含有量からみた広島平野沖積層の堆積構造[J]. 地理学评论,1985,58(10):631-644. Shirakami H. the Structure of Alluvial Formations Deduced from FeS2 Contents of Cored Sediments Taken from Hiroshima Plain[J]. The Association of Japanese Geographers,1985,58(10):631-644.
[9] 方晶,李应硕,介冬梅,等. 黏土混浊水导电率在海陆变迁研究上的应用:以下辽河平原为例[J]. 第四纪研究,2006,26(3):493-494. Fang Jing, Li Yingshuo, Jie Dongmei, et al. Application of Clayey Water Electric Conductivity Recovered from the Sea-Land Changes:A Case Study in Xialiao River plain[J]. Quaternary Sciences, 2006,26(3):493-494.
[10] 方晶,武亚芳,李瑞武,等.辽宁沿海早、中期全新世海进中的一次海退事件[J]. 地学前缘,2009,16(2):376-403. Fang Jing, Wu Yafang, Li Ruiwu, et al. Discussion on Marine Regression Event during the Early-Middle Holocene in the Liaoning Coast[J]. Earth Science Frontiers, 2009,16(2):376-403.
[11] 方晶,范昌福,王海峰,等.黏土混浊水EC对牡蛎礁水平夹层成因的解释:以渤海湾西北岸大吴庄牡蛎礁为例[J].第四纪研究,2011,31(4):746-748. Fang Jing, Fan Changfu, Wang Haifeng, et al. Application of Clayey Water Electric Conductivity Recovered from Origins of Horizontal Interlayers in the Buried Oyster Reef:A Case Study of the Dawuzhuang Oyster Reef in the Northwest of Bohai Bay[J].Quaternary Sciences, 2011,31(4):746-748.
[12] 横山卓雄. 电气传导度测定法[M]//日本第四纪学会.第四纪试料分析法:2.东京:东京大学出版会,1993:109-118. Yokoyama T. Mensuration of Electric Conductivity[M]//Japan Association for Quaternary Researched. A Handbook of Quaternary Research:2. Tokyo:University of Tokyo Press,1993:109-118.
[13] Berner R A.Sedimentary Pyrite Formation[J]. Amer Jour Sci,1970,268:1-23.
[14] 中井信之,太田友子,藤沢寛,等.堆積物コアの炭素同位体比,C/N比およびFeS2含有量からみた名古屋港周辺の古気候,古海水準変動[J].第四纪研究,1982,21(3):169-177. Nakai N, Ohta T, Fujisawa H, et al. Paleoclimatic and Sea-Level Changes Deduced from Organic Carbon Isotope Ratios,C/N Ratios and Pyrite Contents of Cored Sediments from Nagoya Harbor, Japan[J]. The Quaternary Research,1982,21(3):169-177.
[15] 李世瑜.古代渤海湾西部海岸遗迹及地下文物的初步调查研究[J]. 考古,1962,11(12):652-657. Li Shiyu. Preliminary Study on Relics of Coast and Culture in the West Coast of Bohai Bay[J]. Acta Archaeology Sinica, 1962,11(12):652-657.
[16] 赵希涛,张景文,焦文强,等. 渤海湾西岸的贝壳堤[J]. 科学通报,1980,25(6):279-281. Zhao Xitao, Zhang Jingwen, Jiao Wenqiang, et al. Chenier Ridge on the West Coast of Bohai Sea[J]. Chinese Science Bulletin, 1980, 25(6):279-281.
[17] 苏盛伟. 渤海湾西岸全新世贝壳堤古环境重建[D].长春:吉林大学,2012:1-79. Su Shengwei. Palaeoenvironmental Reconstruction of the Holocene Cheniers in West Coast of Bohai Bay[D].Changchun:Jilin University, 2012:1-79.
[18] Reimer P J, Bard E, Bayliss A,et al. IntCal13 and MARINE13 Radiocarbon Age Calibration Curves 0-50000 Years cal. B. P.[J]. Radiocarbon,2013,55(4):1869-1887.
[19] Stuiver M, Braziunas T. Modelling Atmospheric 14C Influences and 14C Ages of Marine Samples to 10000 BC[J]. Radiocarbon,1993,35:137-189.
[20] Kellogg W W, Cadle R D, Allen E R, el al. The Sulfur Cycle[J]. Science,1972,175:587-596.
[21] Goldman C R, Horne A J.Limnology[M]. New York:Mc Graw-Hill,1983:464.
[22] 方晶,杨永强,马宏伟,等. 辽东半岛大孤山古溺谷平原沉积环境的复原:基于岩心黏土混浊水电导率和pH值以及硅藻组合[J]. 海洋学报,2012,34(6):133-141. Fang Jing, Yang Yongqiang, Ma Hongwei, et al. Edimentary Environmental Analysis Based on Electric Conductivity and pH of Stirred Clayed Drilling Cores in Water and Diatom Recovered from the of Old Drowned Valley Plain in the Dagu Mountain, Liaodong Peninsula in China[J]. Acta Oceanologica Sinica,2012,34(6):133-141.
[1] 柳蓉, 何天鑫, 张浩然, 刘强浩, 张苡铭. 中国典型含油气盆地热液作用及其对沉积环境的影响[J]. 吉林大学学报(地球科学版), 2025, 55(6): 1785-1805.
[2] 易定红, 刘应如, 李积永, 李红哲, 徐晓玲, 吴颜雄, 王爱萍, 马元琨, 涂加沙, 贾正良. 柴达木盆地南八仙地区渐新世沉积环境及储层物性控制因素[J]. 吉林大学学报(地球科学版), 2025, 55(3): 705-720.
[3] 周元发, 王腾飞, 周维维. 沉积型磷质岩粒度特征及其指示意义：以云南镇雄县羊场磷矿为例[J]. 吉林大学学报(地球科学版), 2025, 55(3): 758-774.
[4] 何中波, 冀华丽, 胡宝群, 孙萧, 钟军, 杨喆, 陈虹. 准噶尔盆地北部晚白垩世至新近纪沉积介质环境演化特征及其对铀成矿的制约[J]. 吉林大学学报(地球科学版), 2024, 54(3): 800-810.
[5] 郭春涛, 史江涛, 刘亮, 荆雪婷, 刘杨晋. 塔里木盆地塔河地区中下奥陶统沉积特征及其演化模式#br#[J]. 吉林大学学报(地球科学版), 2024, 54(1): 68-82.
[6] 王常明, 刘辛磊, 王飞. 品字形桩林防护结构对泥石流冲击桥墩作用的影响[J]. 吉林大学学报(地球科学版), 2023, 53(6): 1773-1784.
[7] 张斌, 陈圣波, 张梦娇, 张玉峰, 张澜, 赵秀影. 苏子河流域土地利用变化对大伙房水库水量的影响[J]. 吉林大学学报(地球科学版), 2023, 53(1): 320-327.
[8] 高家俊, 孟庆涛, 曾文人, 李金国, 李丽, 康嘉楠, . 依兰盆地始新统达连河组油页岩有机地球化学特征及沉积环境分析[J]. 吉林大学学报(地球科学版), 2023, 53(1): 60-72.
[9] 梁天意, 刘敬党, 李猛猛, 王刚, 李琛, 王利. 大兴安岭中段林西组砂岩LA-ICP-MS碎屑锆石U-Pb年代学及其地质意义[J]. 吉林大学学报(地球科学版), 2022, 52(2): 442-462.
[10] 李天军, 黄志龙, 王瑞, 苟红光, 张品, 殷越. 银根—额济纳旗盆地天草凹陷下白垩统巴音戈壁组有效烃源岩地球化学特征及其形成环境[J]. 吉林大学学报(地球科学版), 2021, 51(4): 957-972.
[11] 海连富, 王磊, 马治军, 徐清海, 宋扬, 白金鹤. 宁夏固原炭山地区中侏罗统延安组油页岩特征及其沉积环境[J]. 吉林大学学报(地球科学版), 2020, 50(3): 747-756.
[12] 张健, 张海华, 陈树旺, 郑月娟, 张德军, 苏飞, 黄欣. 松辽盆地北部上二叠统林西组地球化学特征及地质意义[J]. 吉林大学学报(地球科学版), 2020, 50(2): 518-530.
[13] 王嗣敏, 臧东升, 王熙琼, 李杰, 韩嵩, 李建中. 辽西建昌盆地油页岩发育特征及沉积环境[J]. 吉林大学学报(地球科学版), 2020, 50(2): 326-340.
[14] 孟庆涛, 李金国, 刘招君, 胡菲, 徐川. 茂名盆地羊角含矿区始新统油柑窝组油页岩有机地球化学特征及沉积环境[J]. 吉林大学学报(地球科学版), 2020, 50(2): 356-367.
[15] 董清水, 何春生, 楼仁兴, 任锡钢, 张超, 张渝金, 许圣传. 大兴安岭南段阿鲁科尔沁旗地区林西组沉积环境特征及其时限的地质意义[J]. 吉林大学学报(地球科学版), 2020, 50(2): 425-441.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
[1] 崔建军, 刘晓春, 胡娟, 曲玮. 桐柏杂岩中印支期变质岩包体的变质作用[J]. J4, 2009, 39(4): 618 -629 .
[2] 尤敏鑫，刘建民. 同位素地球化学在峨眉山大火成岩省研究中的应用现状与进展[J]. 吉林大学学报(地球科学版), 2014, 44(4): 1231 -1243 .
[3] 杨春梅, 李洪奇,陆大卫,张方礼,高 原,邵英超. 不同驱替方式下岩石电阻率与饱和度的关系[J]. J4, 2005, 35(05): 667 -671 .
[4] 祝洪臣，张炯飞，权 恒. 大兴安岭中生代两期成岩成矿作用的元素、同位素特征及其形成环境[J]. J4, 2005, 35(04): 436 -0442 .
[5] 朱建伟, 赵刚, 刘博, 郭巍, 成俊. 油页岩测井识别技术及应用[J]. J4, 2012, 42(2): 289 -295 .
[6] 陈力，梁海安，张文娟，荣帆. 模糊数学方法在城市工程地质环境区划中的应用--以抚顺市城区为例[J]. J4, 2008, 38(5): 837 -0840 .
[7] 高桂梅,苏 克,王文颖,甘树才,刘招君. 吉林省桦甸油页岩中稀土元素和微量元素的研究[J]. J4, 2006, 36(6): 974 -0979 .
[8] 吴孔运，蒋忠诚，叶 晔. 不同植物群落对灰岩试块溶蚀速率的影响[J]. J4, 2007, 37(5): 967 -0971 .
[9] 周彦章，迟宝明，刘中培. 山东夏甸金矿床充水机理构造控制模式[J]. J4, 2008, 38(2): 255 -0260 .
[10] 张渊，刘连登，孙景贵，陈国华，张洪喜，闫复传,杨开春. 胶东西北部黄埠岭金矿床两期次叠加成矿[J]. J4, 2008, 38(1): 21 -0026 .
版权所有 © 《吉林大学学报(地球科学版)》编辑部
地址：长春市西民主大街938号(130026)　电话：+86-431-88502374；13756165364　E-mail: xuebao1956@jlu.edu.cn
本系统由北京玛格泰克科技发展有限公司设计开发