油页岩,高温腐蚀,原位开采,J55,P110,3Cr ," /> 油页岩,高温腐蚀,原位开采,J55,P110,3Cr ,"/> oil shale,high temperature corrosion,in-situ mining;J55;P110;3Cr ,"/> <span class="cf0">油页岩原位开采中高温腐蚀下的选材</span>

吉林大学学报(地球科学版) ›› 2025, Vol. 55 ›› Issue (4): 1091-1102.doi: 10.13278/j.cnki.jjuese.20230322

• 地质与资源 • 上一篇    下一篇

油页岩原位开采中高温腐蚀下的选材

杨立红1,刘莹2,罗弋卜2,曾皓1,苏建政1,李迎超2   

  1. 1. 页岩油气富集机理与有效开发国家重点实验室/中国石油化工股份有限公司石油勘探开发研究院,北京 100083 2 .中国石油大学(北京)新能源与材料学院,北京 102249

  • 收稿日期:2023-11-21 出版日期:2025-07-26 发布日期:2025-08-05
  • 作者简介:杨立红(1976—),女,高级工程师,主要从事油气装备腐蚀与防护方面的研究,E-mail:yanglh.syky@sinopec.com
  • 基金资助:

    国家重点研发计划专项(2022YFB3707504);中石化科技部项目 (P23159);国家油页岩开采研发中心开放基金(33550000-22-ZC0613-0305)

Material Selection Under High Temperature Corrosion in In-Situ Exploitation of Oil Shale

Yang Lihong1, Liu Ying2, Luo Yipo2, Zeng Hao1Su Jianzheng1, Li Yingchao2   

  1. 1. State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development/Sinopec Petroleum Exploration and Production Research Institute, Beijing 100083, China

    2. College of New Energy and Materials, China University of Petroleum,Beijing 102249, China

  • Received:2023-11-21 Online:2025-07-26 Published:2025-08-05
  • Supported by:

    the National Key Research and Development Program of China (2022YFB3707504), the Sinopec Science and Technology Department Project (P23159) and the Open Fund of National Oil Shale Mining Research and Development Center (33550000-22-ZC0613-0305)

摘要:

油页岩原位开采技术具有多种优点,能够有效提高开采效率。然而,油页岩原位开采工况条件苛刻,管材在此工况下长时间服役会发生严重的高温腐蚀。因此,油页岩原位开采工况下的选材对于油页岩安全、高效开采至关重要。本文选取常见油井管材J55、P110和3Cr为研究对象,采用微观表征、截面观察和氧化动力学曲线等方法,研究其在600 ℃环境下的耐高温腐蚀性能。研究结果表明:随着腐蚀时间的延长,3种样品表面氧化膜厚度增加,其中J55表面氧化膜厚度最大,3Cr最小;3种样品的氧化增重随腐蚀时间延长而增加,其中J55氧化增重最大,3Cr最小;3种样品表面产物均含有Fe2O3,3Cr表面还有Cr的氧化物。以上结果表明,3种材料3Cr的耐高温腐蚀性能最好。在油页岩原位开采高温井下环境中,Cr质量分数是选材的重要参考。

关键词: 油页岩')">

油页岩, 高温腐蚀, 原位开采, J55, P110, 3Cr

Abstract:

Shale oil in-situ mining technology has many advantages and can effectively improve mining efficiency. However, the operating conditions for shale oil in-situ mining are harsh, and the pipes used in these conditions will experience severe high-temperature corrosion over a long period. Hence, the material selection is key to a safe and effective in-situ shale oil exploitation. In this study, common oil well pipe materials J55, P110, and 3Cr were selected as research objects. Microstructural characterization, cross-sectional observation, and oxidation kinetics curve were used to study their high-temperature corrosion resistance performance at 600 ℃. The research results show that with the increase of corrosion time, the thickness of the oxide film on the surface of the three samples increases, the J55 has the thickest oxide film, and the 3Cr has the thinnest. Secondly, the oxidation weight gain of the three samples increases with the extension of corrosion time, the J55 has the highest oxidation weight gain, and the 3Cr has the lowest. Finally, the surface products of the three samples all contain Fe2O3, and the surface of 3Cr also has chromium oxide. The above results indicate that the 3Cr has the best high-temperature corrosion resistance performance among the three materials. In the high-temperature underground environment of shale oil in-situ mining, the chromium content is an important reference for material selection.

Key words: oil shale')">

oil shale, high temperature corrosion, in-situ mining;J55;P110;3Cr

中图分类号: 

  • TE662
[1] 程瑶, 陆丹丹, 赵龙飞.

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[3] 瞿辉, 胡素云, 孟庆涛. 松辽及外围盆地油页岩资源潜力与政策建议[J]. J4, 2006, 36(6): 944-0948.
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