J4 ›› 2012, Vol. 42 ›› Issue (3): 827-831.

• 地质工程与环境工程 • 上一篇    下一篇

鄂尔多斯盆地北缘煤炭固体废弃物中铝的特征

杨殿范|魏存弟|蒋引珊|张培萍   

  1. 吉林大学材料科学与工程学院|长春130025
  • 收稿日期:2011-08-10 出版日期:2012-05-26 发布日期:2012-05-26
  • 通讯作者: 张培萍(1964-)女,教授,主要从事固体废弃物综合利用研究 E-mail:zhangpp@jlu.edu.cn
  • 作者简介:杨殿范(1953-)|男|教授|主要从事矿物岩石材料应用研究|E-mail:yangdf@jlu.edu.cn
  • 基金资助:

    中国地质调查局项目(1212010916074)

Aluminum Characteristics of Solid Wastes from Coal Fields in North Side of Ordose Basin

YANG Dian-fan, WEI Cun-di, JIANG Yin-shan, ZHANG Pei-ping   

  1. College of Material Science and Engineering, Jilin University, Changchun130025, China
  • Received:2011-08-10 Online:2012-05-26 Published:2012-05-26

摘要:

为了研究煤炭固体废弃物中铝的含量及赋存状态,探讨其中氧化铝提取的可能性,在处理煤炭固体废弃物的同时扩大我国自然铝资源,分别采用化学分析、XRD、SEM及粒度分布等方法对鄂尔多斯北缘准格尔等煤田煤矸石及粉煤灰进行了化学成分、物相组成及结构测定。结果表明:该地区的煤矸石和粉煤灰中氧化铝的质量分数均接近或大于40%, 达到了铝矿床的工业品位;煤矸石中铝主要赋存在高岭石和勃姆石中,OF灰中铝主要赋存在莫来石中,而CFB灰中铝则赋存在非晶态物质中;同时CFB灰与OF灰相比具颗粒细小且粒度分布均匀、颗粒形态呈絮状、结构活性高等特点;CFB灰中的铝活性高易提取,煤矸石中的铝只需要热活化即可提取,而OF灰中的铝则需要化学活化才可以提取。高铝煤炭固体废弃物中铝的有效提取可以补充铝资源的不足。

关键词: 煤矸石, 粉煤灰, 废弃物, 铝资源

Abstract:

To research the content and existence states of aluminum in gangues and fly ash, and to discuses the extraction possibility of aluminum oxide, and to increase the aluminum resource corresponding to make the use of solid wastes from coal fields, the compositions, constitutions and structures of gangues and fly ash from north side of Ordose basin were tested by chemical analysis, XRD, SEM and granularity distribution. The result is that the contents of aluminum oxide both in gangues and in fly ash are approximately or more than 40%, it is more than the industry grade of aluminum deposit. The aluminum of gangues is mainly in kaolinite and boehmitthe, the aluminum of OF ash is mainly in mollite, and the aluminum in CFB ash is mainly in the amorphous matters. At the same time CFB ash compare to OF ash has the character of smaller grain size and equality granularity, wadding grain form and high structure activity.  The conclusion is that the aluminum in CFB ash has high activation and can be extracted easily,the aluminum in gangues can be extracted when the gangues are baked, and the aluminum in OF ash can be extracted when it is activated by chemically methods. The problem of aluminum recourse shorting can be solved by the aluminum extracting of high aluminum solid wastes.

Key words: gangues, fly ash, wastes, aluminum resources

中图分类号: 

  • X752
[1] 李长雨, 马桂霞, 郝光, 徐亮. 季节冻土地区路基冷阻层温度场效应[J]. 吉林大学学报(地球科学版), 2018, 48(4): 1174-1181.
[2] 宋志伟,杨帆,任南琪. 膜生物反应器中膜污染机理及其防治[J]. J4, 2008, 38(4): 676-0680.
[3] 周睿,赵勇胜,张文静,任何军. 两种废物材料在地下水环境治理中的应用[J]. J4, 2008, 38(1): 112-0116.
[4] 王心义, 杨 建,郭慧霞. 煤矸石山周围地下水污染状况[J]. J4, 2007, 37(2): 326-330.
[5] 马明燕,张东丽,王玉洁,胡大强,朱怀志,蒋引珊. 碱活化条件对粉煤灰合成不同类型沸石的影响[J]. J4, 2006, 36(04): 663-667.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
[1] 尤敏鑫,刘建民. 同位素地球化学在峨眉山大火成岩省研究中的应用现状与进展[J]. 吉林大学学报(地球科学版), 2014, 44(4): 1231 -1243 .
[2] 杨春梅, 李洪奇,陆大卫,张方礼,高 原,邵英超. 不同驱替方式下岩石电阻率与饱和度的关系[J]. J4, 2005, 35(05): 667 -671 .
[3] 祝洪臣,张炯飞,权 恒. 大兴安岭中生代两期成岩成矿作用的元素、同位素特征及其形成环境[J]. J4, 2005, 35(04): 436 -0442 .
[4] 朱建伟, 赵刚, 刘博, 郭巍, 成俊. 油页岩测井识别技术及应用[J]. J4, 2012, 42(2): 289 -295 .
[5] 陈力,梁海安,张文娟,荣帆. 模糊数学方法在城市工程地质环境区划中的应用--以抚顺市城区为例[J]. J4, 2008, 38(5): 837 -0840 .
[6] 高桂梅,苏 克,王文颖,甘树才,刘招君. 吉林省桦甸油页岩中稀土元素和微量元素的研究[J]. J4, 2006, 36(6): 974 -0979 .
[7] 吴孔运,蒋忠诚,叶 晔. 不同植物群落对灰岩试块溶蚀速率的影响[J]. J4, 2007, 37(5): 967 -0971 .
[8] 周彦章,迟宝明,刘中培. 山东夏甸金矿床充水机理构造控制模式[J]. J4, 2008, 38(2): 255 -0260 .
[9] 张渊,刘连登,孙景贵,陈国华,张洪喜,闫复传,杨开春. 胶东西北部黄埠岭金矿床两期次叠加成矿[J]. J4, 2008, 38(1): 21 -0026 .
[10] 鲁程鹏, 束龙仓, 苑利波, 张蓉蓉, 黄币娟, 王彬彬. 基于示踪试验求解岩溶含水层水文地质参数[J]. J4, 2009, 39(4): 717 -721 .