吉林省典型废水COD与TOC的相关关系及其形成机制和影响因素

J4 ›› 2012, Vol. 42 ›› Issue (5): 1446-1455.

吉林省典型废水COD与TOC的相关关系及其形成机制和影响因素

董德明|宋兴|花修艺|袁懋|梁建海|郭志勇|梁大鹏

地下水资源与环境教育部重点实验室/水资源与水环境吉林省重点实验室/吉林大学环境与资源学院|长春130012

收稿日期:2012-03-26 出版日期:2012-09-26 发布日期:2012-09-26
通讯作者: 花修艺（1976-），男，副教授，主要从事环境化学方面的研究 E-mail:huaxy@jlu.edu.cn
作者简介:董德明(1957-)|男|教授|博士生导师|主要从事环境化学和环境规划与评价方面的研究|E-mail:dmdong@jlu.edu.cn
基金资助:
国家“水体污染控制与治理”科技重大专项(2009ZX07208-006-001, 2012ZX07202009)

Relationship Between COD and TOC of Typical Wastewaters in Jilin Province and Mechanism and Main Influencing Factors

DONG De-ming, SONG Xing, HUA Xiu-yi, YUAN Mao, LIANG Jian-hai, GUO Zhi-yong, LIANG Da-peng

Key Lab of Groundwater Resources and Environment of Ministry of Education/ Key Lab of Water Resources and Aquatic Environment of Jilin Province/College of Environment and Resources, Jilin University, Changchun130012, China

Received:2012-03-26 Online:2012-09-26 Published:2012-09-26

摘要/Abstract

摘要：

为了解吉林省典型废水的化学需氧量(COD)与总有机碳(TOC)间的相关关系及其形成机制，在对吉林省典型废水的ρ(COD)与ρ(TOC)进行测定的基础上，分析了各类废水ρ(COD)与ρ(TOC)的相关关系，研究了其形成作用和有机组分的挥发性与可氧化特征对其的影响。结果表明：所研究废水水样的ρ(COD)与ρ(TOC)间均存在显著的线性相关关系(α≤0.050)，各类废水ρ(COD)/ρ(TOC)为1.711~12.280；废水ρ(COD)与ρ(TOC)的相关关系主要由废水的有机化学成分决定，其中废水有机组分的元素组成起主导作用，有机组分的挥发性和可氧化特征对废水ρ(COD)与ρ(TOC)的相关性和比值均存在影响。

关键词: 典型废水, 化学需氧量, 总有机碳, 相关关系, 有机污染物

Abstract:

Chemical oxygen demand(COD) and total organic carbon(TOC) of typical wastewaters in Jilin Province were investigated. The possibilities of establishing linear regression equations were studied through analyzing relationship between COD contents and TOC contents of wastewaters. Based on this, influences of volatility and oxidization properties of organic compounds on relationship between COD contents and TOC contents of the wastewaters were discussed via analyzing organic compounds of some wastewaters. The mechanisms of the relationship of wastewaters were discussed. The results indicated that there were significant linear correlations between COD contents and TOC contents of all the samples of the typical wastewaters(α≤0.050). The range of COD/TOC of all kinds of wastewaters were from 1.711 to 12.280. The relationship was mainly controlled by the composition of the wastewaters. Elemental composition of the typical organic pollutants in the wastewaters played a key role in determining the correlations between COD contents and TOC contents of the wastewaters. The volatility and oxidization properties of the main organic pollutants in the waters also played important but divers roles in these correlations and the ratios of COD to TOC of the wastewater samples.

Key words: wastewater, chemical oxygen demand, total organic carbon, relationship, organic pollutants

中图分类号:

X 52

董德明, 宋兴, 花修艺, 袁懋, 梁建海, 郭志勇, 梁大鹏. 吉林省典型废水COD与TOC的相关关系及其形成机制和影响因素[J]. J4, 2012, 42(5): 1446-1455.

DONG De-ming, SONG Xing, HUA Xiu-yi, YUAN Mao, LIANG Jian-hai, GUO Zhi-yong, LIANG Da-peng. Relationship Between COD and TOC of Typical Wastewaters in Jilin Province and Mechanism and Main Influencing Factors[J]. J4, 2012, 42(5): 1446-1455.

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