Journal of Jilin University(Earth Science Edition) ›› 2019, Vol. 49 ›› Issue (5): 1285-1300.doi: 10.13278/j.cnki.jjuese.20180089

Previous Articles     Next Articles

Geological Characteristics and Diagenetic Age of Ore-Bearing Rock of Taojiang Muguayuan Tungsten Deposit in Hunan Province

Li Hongying1, Yang Lei2, Chen Jianfeng3   

  1. 1. Institute of Mineral Resources, CAGS/MLR Key Laboratory of Metallogeny and Mineral Assessment, Beijing 100037, China;
    2. Research Institute, CNOOC, Beijing 100027, China;
    3. Hunan Institute of Geology Survey, Changsha 410116, China
  • Received:2018-04-28 Online:2019-09-26 Published:2019-10-10
  • Supported by:
    Supported by National Natural Science Foundation of China (41602074, 41430314); Project of China Geological Survey (DD20190606, DD20160124) and Special Fund for Basic Scientific Research Business of Central Public Research Insititutes (K1408,YYWF201510)

PDF (PC)

529

Abstract: The Muguayuan W deposit in Taojiang County of Hunan Province is a newly discovered large W deposit in the west part of the Jiangnan massif, which is hosted in the Sanxianba granite porphyry. The main ore-forming types include disseminated, veinlet, and reticular types.The major alteration types of wall rocks are comprise of potassium alteration, silicification, sericitization, pyritization, and carbonation etc., typical alteration characteristics of porphyry W deposits. The different mineralizing types of molybdenum-bearing samples were selected for precise Re-Os dating, and the model ages are from 228 to 223 Ma, indicating that the deposit was formed in the Late Triassic. The Re content of molybdenite is (70-181)×10-6, indicating that they were derived from mixed crust and mantle sources. The metallogenic environment was the post collision in the period of Late Indosinian.

Key words: Muguayuan tungsten deposit, Re-Os dating, geological features of ore deposit, ore-bearing rock body, Hunan Province

CLC Number: 

  • P618.67
[1] Song G X, Qin K Z, Li G M, et al. Geochronologic and Isotope Geochemical Constraints on Magmatism and Associated W-Mo Mineralization of the Jitoushan W-Mo Deposit, Middle-Lower Yangtze Valley[J]. International Geology Review, 2012,54:1532-1547.
[2] Mao Z H, Cheng Y B, Liu J J, et al. Geology and Molybdenite Re-Os Age of the Dahutang Granite-Related Veinlets-Disseminated Tungsten Ore Field in the Jiangxi Province, China[J]. Ore Geology Reviews, 2013,53:422-433.
[3] Mao J W, Pirajno P, Lehmann B, et al. Distribution of Porphyry Deposits in the Eurasian Continent and Their Corresponding Tectonic Settings[J]. Journal of Asian Earth Sciences, 2014,79:576-584.
[4] Mao J W,Pirajno F, Nigel C N. Mesozoic Metallogeny in East China and Corresponding Geodynamic Settings:An Introduction to the Special Issue[J]. Ore Geology Reviews, 2011, 43:1-7.
[5] 项新葵, 汪石林, 詹国年,等.赣北石门寺矿区钨多金属矿床成矿地质条件[J]. 地质找矿论丛,2012,27(2):143-155. Xiang Xinkui, Wang Shilin, Zhan Guonian, et al. Metallogenic Geological Conditions of Shimensi Tungsten-Polymetallic Deposit in North Jiangxi Province[J]. Contributions to Geology and Mineral Resources Research, 2012, 27(2):143-155.
[6] 项新葵,王朋,詹国年,等.赣北石门寺超大型钨多金属矿床地质特征[J]. 矿床地质, 2013,32(6):1171-1187. Xiang Xinkui, Wang Peng, Zhan Guonian, et al. Geological Characteris of Shimensi Tungsten Polymentallic Deposit in Northern Jiangxi Province[J]. Mineral Deposits, 2013, 32(6):1171-1187.
[7] 陈国华, 万浩章, 舒良树,等.江西景德镇朱溪铜钨多金属矿床地质特征与控矿条件分析[J]. 岩石学报, 2012,28(12):3901-3914. Chen Guohua, Wan Haozhang, Shu Liangshu, et al. An Analysis on Ore-Controlling Conditionsand Geological Features of the Cu-W Polymetallic Ore Deposit in the Zhuxi Area Jingdezhen, Jiangxi Province[J]. Acta Petrologica Sinica, 2012, 28(12):3901-3914.
[8] 王先广,刘战庆,刘善宝,等.江西朱溪铜钨矿区细粒黑云母花岗岩LA-ICP-MS锆石U-Pb定年和岩石地球化学研究[J]. 岩矿测试, 2015, 34(5):592-599. Wang Xianguang, Liu Zhanqing, Liu Shanbao, et al. LA-ICP-MS Zircon U-Pb Dating and Petrologic Geochemistry of Fine-Granined Granite from Zhuxi Cu-W Deposit, Jiangxi Province and Its Geological Significance[J]. Rock and Mineral Analysis, 2015, 34(5):592-599.
[9] 朱明新,王河锦. 长沙-澧陵-浏阳一带冷家溪群及板溪群的甚低级变质作用[J].岩石学报, 2001, 17(2):291-300. Zhu Mingxin, Wang Hejin. Very Low-Grade Metamorphism of the Lengjiaxi and Banxi Groups Around the Area of Changsha-Liling-Liuyang, Hunan Province, China[J]. Acta Petrologica Sinica, 2001, 17(2):291-300.
[10] 湖南省地质矿产局.湖南省区域地质志[M]. 北京:地质出版社,1988. Hunan Bureau of Geology and Mineral Resources. Regional Geology of Hunan Province[M]. Beijing:Geological Publishing House, 1988.
[11] 侯可军,李延河,田有荣. LA-MC-ICP-MS锆石微区原位U-Pb定年技术[J]. 矿床地质, 2009, 28(4):481-492. Hou Kejun, Li Yanhe, Tian Yourong. In Situ U-Pb Zircon Dating Using Laser Ablation-Multi Ion Counting-ICP-MS[J]. Mineral Deposits, 2009, 28(4):481-492.
[12] 李晶,孙亚莉,何克,等.辉钼矿Re-Os同位素定年方法的改进与应用[J].岩石学报, 2010,26(2):642-648. Sun Jing, Sun Yali, He Ke, et al. The Improved Molybdenite Dating Method and Its Application[J]. Acta Petroligica Sinica, 2010, 26(2):642-648.
[13] 吴元保,郑永飞.锆石成因矿物学研究及其对U-Pb年龄解释的制约[J]. 科学通报, 2004, 49(16):1589-1604. Wu Yuanbao, Zheng Yongfei. Genetic Mineralogy of Zircon and It's Restricts for the Age of U-Pb[J]. Science Bulletin, 2004, 49(16):1589-1604.
[14] 续海金,马昌前,钟玉芳,等. 湖南桃江、大神山花岗岩的锆石SHRIMP定年:扬子与华夏拼合的时间下限[C]//2004年全国岩石学与地球动力学研讨会.北京:地质出版社, 2004:312-314. Xu Haijin, Ma Changqian, Zhong Yufang, et al. The Zircon SHRIMP Dating of the Taojiang and Dashenshan Granitoids:The Lower Limit Time Between the Cathaysia and Yangtzed Block[C]//The Seminar of Petrology and Geodynamic in China, 2004. Beijing:Geological Publishing House, 2004:312-314.
[15] Wang K X, Chen P R, Chen W F, et al. Magma Mingling and Chemical Diffusion in the Taojiang Granitoids in the Hunan Province, China:Evidences from Petrography, Geochronology and Geochemistry[J]. Mineral Petrology, 2012, 106:243-264.
[16] 丁兴,陈培荣,陈卫锋,等.湖南沩山花岗岩中锆石LA-ICP-MS U-Pb定年:成岩启示和意义[J].中国科学:D辑,2005, 35(7):606-616. Ding Xing, Chen Peirong, Chen Weifeng, et al. LA-ICP-MS Zircon Dating of Weishan Granitic Plutions in Hunan Province:Petrogenisis and Tectonic Implications[J]. Science in China:Series D, 2005,35(7):606-616.
[17] Smoliar, Michael I, Walker, et al. Re-Os Ages of Group ⅡA, ⅢA, ⅣA, and ⅣB Iron Meteorites[J]. Science Magazine, 1996, 271:1099-1102.
[18] 毛景文, 谢桂青, 郭春丽, 等.华南地区中生代主要金属矿床时空分布规律和成矿环境[J]. 高校地质学报, 2008,14(4):510-526. Mao Jingwen, Xie Guiqing, Guo Chunli, et al. Spatial-Temporal Distribution of Mesozoic Ore Deposits in South China and Their Metallogenic Settings[J]. Geological Journal of China Universities, 2008,14(4):510-526.
[19] Gilder S A,Gill J,Coe R S, et al. Isotopic and Paleomagnetic Constraints on the Mesozoic Tectonic Evolution of South China[J]. Journal of Geophysical Research:B,1996,101(7):16137-16155.
[20] Hong D W,Xie X L, Zhang J S. Isotopic Geochemistry of Granitoids in South China and Their Metallogeny[J]. Resource Geology,1998, 48(4):251-263.
[21] 赵振华,包志伟,张伯友,等. 柿竹园超大型钨多金属矿床形成的壳幔相互作用背景[J]. 中国科学:D辑,2000,28(增刊):7-14. Zhao Zhenhua,Bao Zhiwei,Zhang Boyou, et al. Crust-Mantle Interaction Background of the Ore Formation in the Giant Shizhuyuan Tin Polymetallic Deposit[J]. Science in China:Series D,2000, 28(Sup.):7-14.
[22] 朱金初,黄革非,张佩华,等.湖南骑田岭岩体菜岭超单元花岗岩侵位年龄和物质来源研究[J]. 地质论评,2003, 46(3):245-252. Zhu Jinchu,Huang Gefei,Zhang Peihua, et al. On the Emplacement Age and Material Sources for the Granites of Cailing Superunit,Qitianling Pluton,Southern Hunan[J]. Geological Review,2003, 46(3):245-252.
[23] 朱金初,谢才富,张佩华,等. 桂北牛庙闪长岩和同安石英二长岩:岩石学、锆石SHRIMP U-Pb年代学和地球化学[J]. 岩石学报,2005, 21(3):665-676. Zhu Jinchu,Xie Caifu,Zhang Peihua, et al. Niumiao and Tong'an Intrusive Bodies of NE Guangxi:Petrology,Zircon SHRIMP U-Pb Geochronology and Geochemistry[J]. Acta Petrologica Sinica,2005,21(3):665-676.
[24] Li Z L,Hu R Z,Peng J T, et al. Helium Isotope Geochemistry of Ore-Forming Fluids from Furong Tin Orefield in Hunan Province,China[J]. Resource Geology,2006, 56(1):9-15.
[25] Wu L Y,Hu R Z,Peng J T, et al. Helium and Argon Isotope Compositions of Fluid Inclusions in Pyrite from Shizhuyuan W-Sn-Mo-Bi Deposit,Hunan Province[J]. Journal of China University of Geosciences,2007, 18(Sup.):297-299.
[26] 蔡明海,韩凤彬,何龙清,等. 湘南新田岭白钨矿床He、Ar同位素特征及Rb-Sr测年[J]. 地球学报,2008,29(2):167-173. Cai Minghai,Han Fengbin,He Longqing, et al. He,Ar Isotope Characteristics and Rb-Sr Dating of the Xintianling Skarn Scheelite Deposit in Southern Hunan, China[J]. Acta Geoscientia Sinica, 2008, 29(2):167-173.
[27] 张龙升,彭建堂,张东亮,等. 湘西大神山印支期花岗岩的岩石学和地球化学特征[J]. 大地构造与成矿学, 2012, 36(1):137-148. Zhang Longsheng, Peng Jiantang, Zhang Dongliang, et al. Geochemistry and Petrogenesis of the Indosinian Dashenshan Granite, Western Hunan[J]. South China Geotectonica et Metallogenia, 2012, 36(1):137-148.
[28] Mao J W,Zhang Z C,Zhang Z H, et al. Re-Os Isotopic Dating of Molybdenites in the Xiaoliugou W (Mo) Deposit in the Northern Qilian Mountains and Its Geological Significance[J]. Geochimical Cosmochimical Acta, 1999, 63(11/12):1815-1818.
[29] 耿艳光,简伟,李洪英,等.中条山篦子沟铜矿辉钼矿铼-锇同位素年龄及其地质意义[J].吉林大学学报(地球科学版),2017,47(5):1405-1418. Geng Yanguang, Jian Wei, Li Hongying, et al. Re-Os Isotopic Dating of Molybdenite from Bizigou Cu Deposit in Zhongtiao Mountain and Its Implication[J]. Journal of Jilin University (Earth Science Edition), 2017,47(5):1405-1418.
[30] Parrish I S, Tully J V. Porphyry Tungsten Zones at Mt Pleasant, New Brunswick[J]. CIM Bull, 1978, 71:93-100.
[31] Noble S R, Spooner E T C, Harris F H. The Logtung Large Tonnage, Low-Grade W (Scheelite)-Mo Porphyry Deposit, South-Central Yukon Territory[J]. Economic Geology, 1984, 79(5):848-868.
[32] So C S, Shelton K L, Seidemann D E, et al. The DaeHwa Tungsten-Molybdenum Mine, Republic of Korea:A Geochemical Study[J]. Economic Geology, 1983, 78(5):920-930.
[33] Shelton K L, Taylor R P, So C S. Stable Isotope Studies of the Dae Hwa Tungsten-Molybdenum Mine, Republic of Korea:Evidence of Progressive Meteoric Water Interaction in a Tungsten-Bearing Hydrothermal System[J]. Economic Geology, 1987, 82(2):471-481.
[34] Zhang Y X. Geological Characteristics and Origin of Yangchuling Porphyry W-Mo-Deposit[J]. Geochimica, 1982, 2:122-132.
[35] Mao J W, Xiong B K, Liu J, et al. Molybdenite Re/Os Dating, Zircon U-Pb Age and Geochemistry of Granitoids in the Yangchuling Porphyry W-Mo Deposit (Jiangnan Tungsten Ore Belt), China:Implications for Petrogenesis, Mineralization and Geodynamic Setting[J]. Lithos, 2017, 286/287:35-52.
[36] Liu P, Mao J W, Pirajno F, et al. Ore Genesis and Geodynamic Setting of the Lianhuashan Porphyry Tungsten Deposit, Eastern Guangdong Province, SE China:Constraints from Muscovite 40Ar-39Ar and Zircon U-Pb Dating and Hf Isotopes[J].Mineralium Deposita,2018,53(6):797-814.
[37] 谭运金.广东莲花山斑岩钨矿床地质地球化学特征及矿床成因[J].地球化学, 1983(2):121-132. Tan Yunjin. Geological-Geochemical Characteristics of Lianhuashan Porphyry Tungsten Deposit, and Its Origin[J]. Geochemistry, 1983(2):121-132.
[38] 柳少波,王联. 莲花山斑岩型钨-金矿床蚀变矿化过程中元素迁移定量研究[J]. 地质科学, 1998, 33(1):102-114. Liu Shaobo, Wang Lian. Element Gains and Loss in the Process of Alteration in Lianhuashan W-Au Porphyry-Type Deposit[J]. Science Geology, 1998, 33(1):102-114.
[39] 古菊云. 中国主要斑岩钨矿床地质特征[J]. 矿产与地质, 1988, 2(1):13-21. Gu Juyun. The Characteristics of Dominant Porphyry Tungsten Deposits of China[J]. Mineral Resource Geology, 1988, 2(1):13-21.
[40] 唐勇明,赵乔辉,罗仕长.湖南桃江木瓜园斑岩型钨矿床地质特征及成矿规律[J]. 西部资源, 2016, 32(3):94-95. Tang Yongming, Zhao Qiaohui, Luo Shizhang. Geological Characteristics and Metallogeny of Muguayuan W Deposit in Taojiang County, Hunan Province[J]. Western Resources, 2016, 32(3):94-95.
[1] Huang Shuchun, Li Hongtao, Deng Bo, Wang Dan, Zhang Gaohua.

Hydrochemistry and Its Driving Factors in Hexi Area, Xiangtan, Hunan Province over the Past Two Decades [J]. Journal of Jilin University(Earth Science Edition), 2025, 55(4): 1269-1287.

[2] Zhang Yajing, Liu Wanzhen, Lu Yuhan, Nie Xitao, Zhang Jianan. Mineralization Age, Fluid Properties and Sources of Ore-Forming Materials for Huajiling Molybdenum Deposit in Helong Area of Yanbian, Jilin Province [J]. Journal of Jilin University(Earth Science Edition), 2024, 54(6): 2154-2170.
[3] Chen Lei, Yan Zhen, Liu Kai, Dai Junzhi, Guo Xianqing, Nie Xiao, Pang Xuyong.  Geochronology of Lengshuigou Cu-Mo-Au Deposit in the Shanyang-Zhashui Area of South Qinling and Its Geological Significance [J]. Journal of Jilin University(Earth Science Edition), 2023, 53(3): 713-727.
[4] Zhang Yuanhou, Liu Jinwei, Wen Bin, Du Shangze, Qu Wenjun. Mineralization Types,Re-Os Dating of Dahu-Qinnan Molybdenum Deposit and Exploration in Xiaoqinling Mt, Central China [J]. Journal of Jilin University(Earth Science Edition), 2020, 50(3): 815-824.
[5] Yang Xihao, Hu Wenjie, Zhong Qihong, Zhu Changjie, Wan Huan, Hu Zhenghua. Geological Characteristics, Ore Controlling Factors and Prospecting Indicators of Dongping Quartz Vein Type Wolframite Deposit in Jiangxi [J]. Journal of Jilin University(Earth Science Edition), 2019, 49(5): 1301-1316.
[6] Geng Yanguang, Jian Wei, Li Hongying, Ye Huishou, Bi Minfeng, Hu Qiaoqing, Li Chao, Fan Chenglong, Wang Mengqi. Re-Os Isotopic Dating of Molybdenite from Bizigou Cu Deposit in Zhongtiao Mountain and Its Implication [J]. Journal of Jilin University(Earth Science Edition), 2017, 47(5): 1405-1418.
[7] Ouyang Fei, Luo Xianrong, Fu Lichun. Mechanism of Geoelectrochemical Extraction from Dagenlong Tungsten Deposit in Hunan [J]. Journal of Jilin University(Earth Science Edition), 2015, 45(6): 1879-1885.
[8] Li Jianhua, Zhang Yueqiao, Xu Xianbing, Li Hailong, Dong Shuwen, Li Tingdong. SHRIMP U-Pb Dating of Zircons from the Baimashan Longtan Super-Unit and Wawutang Granites in Hunan Province and Its Geological Implication [J]. Journal of Jilin University(Earth Science Edition), 2014, 44(1): 158-175.
[9] Zhao Zheng,Chen Yuchuan,Zeng Zailin,Chen Zhenghui,Wang Denghong,Zhao Bin,Zhang Jiajing. Geological Characteristics and Petrogenic & Metallogenic Ages of the Yanqian Tungsten Deposit in Eastern Nanling Region [J]. Journal of Jilin University(Earth Science Edition), 2013, 43(6): 1828-1839.
[10] Chu Yating, Liu Xianfan, Zhao Fufeng, Lu Qiuxia, Li Chunhui, Xiao Jixiong, Wu Ran, Song Xiangfeng, Cai Yongwen，Cai Feiyue. Dating of Ore-Bearing Porphyritic Granite from the Machangqing Mo-Cu-Au Deposit in Western Yunnan Province and Its Geologic Significance [J]. Journal of Jilin University(Earth Science Edition), 2013, 43(5): 1377-1392.
[11] Li Shengmiao, Xiao Keyan, Luo Xiaoya. Mineral Prediction and Quantified Research on Tin Potential in Hunan Province, China [J]. Journal of Jilin University(Earth Science Edition), 2013, 43(4): 1200-1209.
[12] Tan Hong-yan,Shu Guang-long,Lü Jun-chao,Han Ren-ping,Zhang Sen,Kou Lin-lin. LA-ICP-MS Zircon U-Pb and Molybdenite Re-Os Dating for the Luming LargeScale Molybdenum Deposit in Xiao Hinggan Mountains and Its Geological Implication [J]. Journal of Jilin University(Earth Science Edition), 2012, 42(6): 1757-1770.
[13] KUANG Wen-long, YANG Shao-xiang, LIU Xin-hua，CHEN Xin-yue, YU Pei-ran, LAO Ke-tong. Significance of Tempestite from the Cambrian Qingxudong Formation in Yutang Area of Northwestern Hunan Province [J]. J4, 2008, 38(2): 225-0232.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
[1] YU Ping， LI Rui-lei， FU Lei， HAO Xue， ZHANG Xiang-jun，LIAN Guo-fen. Regional Tectonic Characteristics and Significance of North Harbin Area in Songliao Basin: Evidenced from Long Seismic Profiles[J]. J4, 2005, 35(05): 611 -615 .
[2] ZHANG Yuan-qing, SONG Bing-zhong, WANG Yu-fu, ZHANG Ning. Metallogenetic Rules and Prediction of Gold Deposits Around Tongshi Complex,Western Shandong Province[J]. J4, 2010, 40(6): 1287 -1294 .
[3] LI Jian-ping, LI Tong-lin, ZHANG Hui, XU Kai-jun. Study and Application of the TEM Forward and Inversion Problem of Irregular Loop Source over the Layered Medium[J]. J4, 2005, 35(06): 790 -0795 .
[4] GAO Song，SONG Ying，WANG Lin，JIANG Buxin. Study on the Screening and Characterization of Special Effective Bacteria of Degrading Thiuram in the Waterbody[J]. J4, 2006, 36(03): 455 -457 .
[5] ZHANG Feng-jun, LI Qing, MA Jiu-tong, YU Guang-ju. Experimental Study on Treatment of Furfural Wastewater with Membrane Distillation[J]. J4, 2006, 36(02): 270 -0273 .
[6] LU Shuang-fang, LI Ji-jun, XUE Hai-tao, XU Li-heng. Chemical Kinetics of Carbon Isotope Fractionation of Oil-Cracking Methane and Its Initial Application[J]. J4, 2006, 36(05): 825 -829 .
[7] DING Zhi-hong,FENG Ping,MAO Hui-hui. Research and Application of a Method Considering Runoff Distribution Through A Year During Partitioning Runoff into Abundant and Low State[J]. J4, 2009, 39(2): 276 -0280 .
[8] REN He-jun, LIU Na, GAO Song,ZHANG Lan-ying，ZHANG Yu-ling，ZHOU Rui. Degradation of Polychlorinated Biphenyls and Confirm of bphA1 Gene Core by Pseudomonas DN2[J]. J4, 2009, 39(2): 312 -0316 .
[9] Huang Qibo, Qin Xiaoqun, Liu Pengyu, Kang Zhiqiang, Tang Pingping. Applicability of Karst Carbon Sinks Calculation Methods in Semi-Arid Climate Environment[J]. Journal of Jilin University(Earth Science Edition), 2015, 45(1): 240 -246 .
[10] Xiong Xiaoliang，Sun Hongyue，Zhang Shihua，Cai Yueliang. Analysis of Condition of Ensuring High-Lift Siphon Drainage and Numerical Simulation of Choice of Optimum Diameter[J]. Journal of Jilin University(Earth Science Edition), 2014, 44(5): 1595 -1601 .
Copyright © Journal of Jilin University(Earth Science Edition), All Rights Reserved.
Tel: +86-431-88502374；13756165364　E-mail: xuebao1956@jlu.edu.cn
Powered by Beijing Magtech Co. Ltd