Journal of Jilin University(Earth Science Edition) ›› 2015, Vol. 45 ›› Issue (5): 1493-1501.doi: 10.13278/j.cnki.jjuese.201505204

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Interaction of Rock-Brine-Supercritical CO2 in CO2-EGS Reservoir

Na Jin, Xu Tianfu, Wei Mingcong, Feng Bo, Bao Xinhua, Jiang Xue   

  1. College of Enviroment and Resources, Jilin University/Key Lab of Groundwater Resources and Environment, Ministry of Education, Changchun 130021, China
  • Received:2014-12-23 Published:2015-09-26

Abstract:

Enhanced geothermal system (EGS) is an engineered reservoir that has been created to extract economical amounts of heat from geothermal resources with low permeability and/or porosity. CO2 enhanced geothermal system is a technology of geological storage of carbon with geothermal energy development. When the supercritical CO2 is injected into a deep reservoir, the surrounding rock will be dissolved or precipitated, and the porosity and permeability of the rock will also be changed. The interaction of rock-brine-supercritical CO2 in CO2-EGS was simulated by high-temperature & pressure reactor. The changes of ion compositions in the solution and scanning electron microscope of rock core showed that K-feldspar and calcite dissolved after the experiment, especially dissolution of calcite is too strong to be saturated. Meanwhile a very small amount of secondary calcite and albite were generated, with the generation of a new kind of mineral which is likely to be the intermediate product of siderite composed of C,O,Si, and Fe. The chemical reactions in the experiments were simulated by reactive transport modelling using TOUGHREACT. The information currently available by numerical simulations is generally consistent with the results from the laboratory experiment. This study provided geochemical evidences for chemical interaction mechanisms in CO2-EGS.

Key words: CO2-EGS, interaction of rock-brine-supercritical CO2, reactive transport simulations, hot dry rock, Songliao basin

CLC Number: 

  • P641

[1] Liu L,Suto Y,Bignall G,et al.CO2 Injection to Granite and Sandstone in Experimental Rock/Hot Water Systems[J]. Energy Conversion & Management, 2003, 44:1399-1410.

[2] Ueda A, Kato K, Ohsumi T, et al. Experimental Studies of CO2-Rock Interaction at Elevated Temperatures Under Hydrothermal Conditions[J]. Geochem, 2005, 39:417-425.

[3] Kaieda H, Ueda A, Kubota K, et al. Field Experiments for Studying on CO2 Sequestration in Solid Minerals at the Ogachi HDR Geothermal Site, Japan[C]// Proceedings 34th Workshop on Geothermal Reservoir Engineering. Stanford:Stanford University, 2009.

[4] Wan Yuyu, Pruess K, Xu Tianfu. Impact of Fluid-Rock Interactions on Enhanced Geothermal Systems With CO2 as Heat Transmission Fluid[C]//Procee-dings 36th Workshop on Geothermal Reservoir Engineering. Stanford:Stanford University, 2011.

[5] Xu T, Pruess K. Reactive Transport Modeling to Study Fluid-Rock Interactions in Enhanced Geothermal Systems (EGS) with CO2 as Working Fluid[C]//World Geothermal Congress. Bali: International Geothermal Association, 2010: 25-29.

[6] 刘伟.大庆徐家围子地区水性分布规律及预测[D].杭州:浙江大学, 2010. Liu Wei. Water Distribution and Prediction in Xujiaweizi,Daqing[D]. Hangzhou: Zhejiang University, 2010.

[7] 杨晓辉.徐家围子断陷地层水地化特征与油气藏的关系[D].大庆:大庆石油学院, 2009. Yang Xiaohui. Chemical Features of Formation Water and the Relationships with Oil/Gas Pool in Xujiaweizi Fault Depression[D]. Daqing:Daqing Petroleum Institute, 2009.

[8] 王广华, 赵静, 张凤君, 等.砂岩储层中CO2-地层水-岩石的相互作用[J].中南大学学报:自然科学版, 2013(3):1167-1173. Wang Guanghua, Zhao Jing, Zhang Fengjun,et al. Interactions of CO2-Brine-Rock in Sandstone Reservoir[J]. Journal of Central South University:Science and Technology, 2013(3): 1167-1173.

[9] Borgia A, Pruess K, Kneafsey T J, et al. Numerical Simulation of Salt Precipitation in the Fractures of a CO2 Enhanced Geothermal System[J]. Geothermics, 2012, 44(3): 13-22.

[10] 朱焕来, 曲希玉, 刘立, 等. CO2流体-长石相互作用实验研究[J]. 吉林大学学报:地球科学版,2011, 41(3):697-706. Zhu Huanlai, Qu Xiyu, Liu Li, et al.Study on Inter-action Between the Feldspar and CO2 Fluid[J]. Journal of Jilin University:Earth Science Edition,2011, 41(3):697-706.

[11] Wandrey M, Fischer S, Zemke K, et al. Monitoring Petrophysical, Mineralogical, Geochemical and Microbiological Effects of CO2 Exposure:Results of Long-Term Experiments Under in Situconditions[J]. Energy Procedia, 2011, 4: 3644-3650.

[12] 于志超, 杨思玉, 刘立.饱和CO2地层水驱过程中的水-岩相互作用实验[J].石油学报,2012, 33(6):1032-1042. Yu Zhichao, Yang Siyu, Liu Li. An Experimemtal Study on Water-Rock Interaction During Water Flooding in Formations Saturated with CO2[J]. Acta Petrolei Sinica, 2012, 33(6): 1032-1042.

[13] Huq F,Blum P,Marks M A W,et al.Chemical Chan-ges in Fluid Composition Due to CO2 Injection in the Altmark Gas Field: Preliminary Results from Batch Experiments[J]. Environmental Earth Sciences, 2012, 67(2): 385-394.

[14] Dove P M, Crerar D A. Kinetics of Quartz Dissolution in Electrolyte Solutions Using a Hydrothermal Mixed Flow Reactor[J]. Geochimica et Cosmochimica Acta, 1990, 54(4): 955-969.

[15] 万玉玉.鄂尔多斯盆地深部咸水层CO2地质储存中的迁移转化特征[D].长春:吉林大学,2012. Wan Yuyu. Migration and Transformation of CO2 in CO2 Geological Sequestration Process of Shiqianfeng Saline Aquifers in Orods Basin[D]. Changchun: Jilin University, 2012.

[16] 许天福, 金光荣, 岳高凡, 等.地下多组分反应溶质运移数值模拟:地质资源和环境研究的新方法[J]. 吉林大学学报:地球科学版, 2012, 42(5): 1410-1425. Xu Tianfu, Jin Guangrong, Yue Gaofan, et al. Subsurface Reactive Transport Modeling :A New Research Approach for Geo-Resources and Evironment[J]. Journal of Jilin University:Earth Science Edition, 2012, 42(5): 1410-1425.

[17] Xu T. Numerical Simulation to Study the Feasibility of Using CO2 as a Stimulation Agent for Enhanced Feothermal Systems[R].Berkeley: Lawrence Berkeley National Laboratory, 2010.

[18] Xu T, Rose P, Fayer S, et al. On Modeling of Chemical Stimulation of an Enhanced Geothermal System Using a High pH Solution with Chelating Agent[J]. Geofluids, 2009, 9(2): 167-177.

[19] Labus K,Bujok P.CO2 Mineral Sequestration Mechanisms and Capacity of Saline Aquifers of the Upper Silesian Coal Basin (Central Europe)-Modeling and Experimental Verification[J]. Energy, 2011, 36(8): 4974-4982.

[20] 沈照理, 朱宛华. 水文地球化学基础[M].北京:地质出版社,1993. Shen Zhaoli, Zhu Wanhua. Hydrogeochemical Basis[M]. Beijing: Geology Publishing House, 1993.

[21] 侯大力,罗平亚,王长权, 等.高温高压下CO2在水中溶解度实验及理论模型[J]. 吉林大学学报:地球科学版,2015,45(2):564-572. Hou Dali,Luo Pingya,Wang Changquan, et al. Experimental Reseachandthe TheoreticalModelforCO2 Solubility in WaterUnderHighTemperatureand HighPressure[J]. Journal of Jilin University:Earth Science Edition, 2015,45(2):564-572.

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