吉林大学学报(地球科学版) ›› 2021, Vol. 51 ›› Issue (1): 95-106.doi: 10.13278/j.cnki.jjuese.20190153

• 地质与资源 • 上一篇    

大兴安岭永新金矿床黄铁矿热电性特征及其指示意义

董娟1, 李成禄2   

  1. 1. 山西大同大学建筑与测绘工程学院, 山西 大同 037009;
    2. 黑龙江省地质调查研究总院, 哈尔滨 150036
  • 收稿日期:2019-08-02 发布日期:2021-02-02
  • 作者简介:董娟(1989-),女,硕士,主要从事成因矿物学与找矿矿物学方面的研究,E-mail:474398723@qq.com
  • 基金资助:
    国家自然科学基金项目(41872038);黑龙江省国土资源科研项目(201603)

Thermoelectric Characteristics of Pyrite from Yongxin Gold Deposit, Xing'an Great Range and Its Indicative Significance

Dong Juan1, Li Chenglu2   

  1. 1. School of Architecture and Geomatics Engineering, Shanxi Datong University, Datong 037009, Shanxi, China;
    2. Heilongjiang Institute of Geological Survey, Harbin 150036, China
  • Received:2019-08-02 Published:2021-02-02
  • Supported by:
    Supported by the National Natural Science Foundation of China(41872038) and the Heilongjiang Provincial Land and Resources Research Project(201603)

摘要: 永新金矿床位于大兴安岭东北部黑河—嫩江构造混杂岩带,是近年来在大兴安岭地区新发现的受构造带控制的大型蚀变岩型金矿床之一,其矿床成因和找矿预测的相关研究较少,许多地质问题还不清楚。为了给深部找矿提供依据,开展了永新金矿床黄铁矿热电性的研究,采用BHTE-6型热电仪,对从永新金矿床32个钻孔及探槽孔矿石样品中挑选出的3 200粒黄铁矿单晶进行了测试。结果表明,永新金矿床黄铁矿热电导型以N型为主,占比约99%,P型占比约1%,黄铁矿热电系数变化范围为-306.0~296.0 μV/℃。通过黄铁矿热电系数计算永新金矿床成矿温度为190.2~313.5℃,属于中低温型热液矿床。黄铁矿热电系数离散性、导型分布、剥蚀率变化梯度及矿物填图等均表明永新金矿床西北部深部仍具有很好的找矿前景。

关键词: 永新金矿床, 黄铁矿, 热电性, 剥蚀率, 成矿温度

Abstract: Yongxin gold deposit is located in the Heihe-Nenjiang tectonic melange belt in the northeast of the Great Xing'an Range, which is one of the newly discovered altered rock type gold deposit,and is controlled by the tectonic belt in this area. At present, there are few related studies on the genesis of the deposit and ore-prospecting prediction, and many geological problems are still unclear. This study on pyrite thermoelectricity in the deposit is to provide a basis for deep ore-prospecting. A total of 3 200 single crystal grains of pyrite ore samples from 32 drill holes were tested by the BHTE-6 type thermoelectric instrument,and the results show that the pyrite thermal conductance type is N type, which accounts for about 99%,and P type accounts for about 1%. The pyrite thermoelectric coefficient variation ranges from -306. 0 μV/℃ to 296.0 μV/℃. The ore-forming temperature of the Yongxin gold deposit calculated by the thermoelectric coefficient ranges from 190.2 ℃ to 313.5 ℃. The dispersion of pyrite thermoelectric coefficient, the distribution characteristics of conduction type, and the gradient of denudation rate and mapping of thermoelectric coefficient all indicate that the deep northwest part of Yongxin gold deposit still has a good prospecting potential.

Key words: Yongxin gold deposit, pyrite, thermoelectricity, denudation rate, ore-forming temperature

中图分类号: 

  • P574
[1] 申俊峰,李胜荣,马广钢,等. 玲珑金矿黄铁矿标型特征及其大纵深变化规律与找矿意义[J]. 地学前缘, 2013, 20(3):55-75. Shen Junfeng, Li Shengrong, Ma Guanggang, et al. Tyoomorphic Characteristics of Pyrite from the Linglong Gold Deposit:Its Vertical Variation and Prospecting Significance[J]. Earth Science Frontiers, 2013, 20(3):55-75.
[2] Wang Gongwen, Feng Yuan, Carranza E J M, et al. Typomorphic Characteristics of Pyrite:Criteria for 3D Exploration Targeting in the Xishan Gold Deposit, China[J]. Journal of Geochemical Exploration, 2016, 164:136-163.
[3] 刘东园. 黑龙江省黑河市孟德河金矿黄铁矿标型特征及成矿预测[D]. 北京:中国地质大学(北京), 2018. Liu Dongyuan. Pyrite Typomorphic Characteristicsand Metallogenic Prognosis on the Mengdehe Gold Deposits in Heihe City, Heilongjiang Province[D]. Beijing:China University of Geosciences(Beijing), 2018.
[4] 翟德高,刘家军,韩思宇,等. 黑龙江三道湾子碲金矿床黄铁矿标型特征及矿床变化保存过程分析[J]. 地质学报, 2013, 81(1):81-90. Zhai Degao,Liu Jiajun, Han Siyu, et al. Typomorphic Characteristics of Pyrite and Processes of Changes in Preservation of Sandaowanzi Telluride-Gold Deposit in Heilongjiang Province[J]. Acta Geological Sinica, 2013, 81(1):81-90.
[5] Zhao Zhonghai, Sun Jinggui, Li Guanghui, et al. Early Cretaceous Gold Mineralizationin the Lesser Xing'an Range of Ne China:The Yongxin Example[J]. International Geology Review, 2019, 61(12):1-28.
[6] 李成禄,徐文喜,李胜荣,等. 大兴安岭东北部霍龙门地区早二叠世花岗岩的锆石U-Pb年龄、地球化学特征及构造意义[J]. 矿物岩石, 2017, 37(3):46-54. Li Chenglu, Xu Wenxi, Li Shengrong,et al. Zircon U-Pb Ages, Geochemical Characteristics and Tectonic Implications of the Early Permian Granites on Huolongmen Area, Northeast Da Hinggan Mountains[J]. Journal of Mineralogy and Petrology, 2017, 37(3):46-54.
[7] 李成禄,徐文喜,于援帮,等. 小兴安岭西北部与永新金矿有关岩浆岩的年代学和地球化学及成矿构造环境[J]. 现代地质, 2017, 31(6):1114-1130. Li Chenglu, Xu Wenxi, Yu Yuanbang,et al. Geochronology and Geochemistry of the Ore-Related Magmatic Rocks from the Yongxin Gold Deposit, Northwest Xiao Hinggan Mountains and Their Ore-Forming Tectonic Implication[J]. Geoscience, 2017, 31(6):1114-1130.
[8] 袁茂文,曾勇杰,李成禄,等. 黑龙江省嫩江-黑河构造混杂岩区永新金矿热液蚀变与矿化关系定量及定位研究[J]. 现代地质, 2017, 31(2):278-289. Yuan Maowen, Zeng Yongjie, Li Chenglu,et al. Quantitative and Positioning Study on the Hydrothermal Alteration and Mineralization Relationship of the Yongxin Gold Deposit in the Nenjiang-Heihe Mélange Zone, Heilongjiang Province[J]. Geoscience, 2017, 31(2):278-289.
[9] Yuan Maowen, Li Shengrong, Li Chenglu, et al. Geochemical and Isotopic Composition of Auriferous Pyrite from the Yongxin Gold Deposit, Central Asian Orogenic Belt:Implication for Ore Genesis[J]. Ore Geology Reviews, 2018, 93:255-267.
[10] 李成禄,李胜荣,徐文喜,等. 黑龙江省嫩江县永新碲金矿床黄铁矿标型特征及稳定同位素研究[J]. 矿物岩石地球化学通报, 2018, 37(1):75-86. Li Chenglu, Li Shengrong, Xu Wenxi,et al. Typomorphic Characteristics and Stable Isotopes of Pyrite from the Yongxin Tellurium-Gold Deposit in Heilongjiang Province[J]. Bulletin of Mineralogy, Petrology and Geochemistry, 2018, 37(1):75-86.
[11] 杨国林,孟舞平. 黄铁矿热电性作为金矿找矿矿物学方法应用的机理探讨[C]//第三次全国重砂矿物学术会议交流资料. 济南:山东地质研究所, 1991:36-42. Yang Guolin, Meng Wuping. Discussion on the Application Mechanism of Pyrite Thermoelectricity as a Mineralogical Method for Gold Ore Prospecting[C]//Proceedings of 3th National Conference of Placer Mineral, China. Jinan:Shandong Institute of Geological Sciences, 1991:36-42.
[12] 李胜荣,陈光远,邵伟. 胶东乳山金矿田成因矿物学[M]. 北京:地质出版社, 1996:1-24, 78-93. Li Shengrong, Chen Guangyuan, Shao Wei. Genetic Mineralogy of Rushan Gold Deposit, Jiaodong[M]. Beijing:Geological Publishing House, 1996:1-24, 78-93.
[13] 陈光远,邵伟,孙岱生. 胶东金矿成因矿物学与找矿[M]. 重庆:重庆出版社, 1989:1-452. Chen Guangyuan, Shao Wei, Sun Daisheng. Genetic Mineralogy and Prospecting of Jiaodong Gold Deposit[M]. Chongqing:Chongqing Publishing House, 1989:1-452.
[14] 邵洁涟. 金矿找矿矿物学[M]. 武汉:中国地质大学出版社, 1988:38-45. Shao Jielian. Exploration Mineralogy of Gold Deposits[M]. Wuhan:China University of Geosciences Press, 1988:38-45.
[15] 宋焕斌,韩润生,祁斌.元阳大坪金矿床黄铁矿的标型特征及其地质意义[J]. 云南地质, 1989, 8(3):249-255. Song Huanbin, Han Runsheng, Qi Bin. Typomorphic Characteristics and Its Significance of Pyrite from the Daping Gold Deposit, Yuanyang[J]. Yunnan Geology,1989, 8(3):249-255.
[16] 曹烨,李胜荣,敖翀,等. 黄铁矿热电性特征在冀西石湖金矿床中的应用[J]. 中国地质, 2008, 35(4):746-753. Cao Ye, Li Shengrong, Ao Chong,et al. Application of Thermoelectric Properties of Pyrite in Gold Exploration in the Shihu Gold Deposit, Western Hebei[J]. Geology in China, 2008, 35(4):746-753.
[17] 李成禄,李胜荣,罗军燕,等. 山西繁峙义兴寨金矿黄铁矿热电系数与导型特征及其地质意义[J]. 现代地质, 2009, 23(6):1056-1063. Li Chenglu, Li Shengrong, Luo Junyan,et al. Thermoelectric Coefficient, Conductive Type and Significance of the Pyrite from Yixingzhai Gold Deposit in Fanshi County, Shanxi Province, China[J]. Geoscience,2009, 23(6):1056-1063.
[18] 陈海燕,李胜荣,张秀宝,等. 胶东金青顶金矿床黄铁矿热电性标型特征及其地质意义[J]. 矿床地质, 2010, 29(6):1125-1137. Chen Haiyan, Li Shengrong, Zhang Xiubao,et al. Thermoelectric Character of Pyrite from Jinqingding Glod Deposit in Eastern Shandong Province and Its Significance[J]. Mineral Deposits,2010, 29(6):1125-1137.
[19] 邵伟,陈光远,孙岱生. 黄铁矿热电性研究方法及其在胶东金矿的应用[J]. 现代地质, 1990, 4(1):46-57. Shao Wei, Chen Guangyuan, Sun Daisheng. Method of Investigating Thermoelectericity of Pyrite and Its Application to Pyrites from Gold Deposits in Jiaodong Region[J]. Geoscience, 1990, 4(1):46-57.
[20] 阴翠珍. 内蒙古撰山子金矿黄铁矿的热电性特征及其与金成矿作用的关系[J]. 矿物学报, 2003, 23(2):153-157. Yin Cuizhen. Pyroelectricity of Pyrite from the Zhuanshanzi Gold Deposit,Inner Mongolia and Its Relationship with Gold Mineralization[J]. Acta Mineralogica Sinica, 2003, 23(2):153-157.
[21] 许虹,李鸿超,李高山. 土岭-石湖金矿床黄铁矿找矿矿物学研究[J]. 地质找矿论丛, 1992, 7(4):67-74. Xu Hong, Li Hongchao, Li Gaoshan. Prospecting Mineralogy of Pyrite from the Tuling-Shihu Gold Deposit[J]. Contributions to Geology and Mineral Resources Research, 1992, 7(4):67-74.
[22] 周立宏,冯瑞. 黄铁矿找矿矿物学在白乃庙金矿床远景评价中的应用[J]. 长春地质学院学报, 1994, 24(3):265-270. Zhou Lihong, Feng Rui. Application of Pyrite Mineralogy in Prospect Evaluation of Bainaimiao Gold Deposit[J]. Journal of Changchun College of Geology, 1994, 24(3):265-270.
[23] 胡大千,姚杰,于洪林. 山东纪山金矿矿物标型的空间分布[J]. 吉林大学学报(地球科学版), 2003, 33(2):125-129. Hu Daqian, Yao Jie, Yu Honglin. Spatial Distribution of the Gold Standard of Jishan Gold Deposit in Shandong Province[J]. Journal of Jilin University(Earth Science Edition), 2003, 33(2):125-129.
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