吉林大学学报(地球科学版) ›› 2017, Vol. 47 ›› Issue (5): 1383-1404.doi: 10.13278/j.cnki.jjuese.201705105

• 地质与资源 • 上一篇    下一篇

河南瓦房铅锌矿床地质、流体包裹体和稳定同位素特征

陈晶源1, 王长明1,2, 贺昕宇1, 陈良3, 吴彬1, 王乔1, 张端1, 姚恩亚1, 董猛猛1   

  1. 1. 中国地质大学(北京)地球科学与资源学院, 北京 100083;
    2. 西澳大利亚大学CET研究中心, 澳大利亚 珀斯 6009;
    3. 五矿资源勘探和开发有限公司, 北京 100010
  • 收稿日期:2016-12-07 出版日期:2017-09-26 发布日期:2017-09-26
  • 通讯作者: 王长明(1974-),男,副教授,博士生导师,主要从事矿床学及矿产普查与勘探方面的研究,E-mail:wangcm@cugb.edu.cn E-mail:wangcm@cugb.edu.cn
  • 作者简介:陈晶源(1992-),男,研究生,主要从事矿物学、岩石学、矿床学方面的研究,E-mail:493383716@qq.com
  • 基金资助:
    国家重点基础研究发展计划("973"计划)项目(2015CB452603,2009CB421008);高等学校学科创新引智计划("111"计划)(B07011);中央高校基本科研业务费(2652016341);五矿勘查开发有限公司科技项目(2013KC0201)

Characteristics of Geology, Fluid Inclusions and Stable Isotope of Wafang Pb-Zn Deposit in Henan

Chen Jingyuan1, Wang Changming1,2, He Xinyu1, Chen Liang3, Wu Bin1, Wang Qiao1, Zhang Duan1, Yao Enya1, Dong Mengmeng1   

  1. 1. School of Earth Sciences and Resource, China University of Geosciences, Beijing 100083, China;
    2. Centre for Exploration Targeting of University of Western Australia, Perth 6009, Australia;
    3. Minmetals Exploration and Development Co., Ltd, Beijing 100010, China
  • Received:2016-12-07 Online:2017-09-26 Published:2017-09-26
  • Supported by:
    Supported by the National Basic Research Program of China("973"Program)(2015CB452603, 2009CB421008), the Programme of Introducing Talents of Discipline to Universities("111" Programme) (B07011), the Fundamental Research Funds for the Central Universities (2652016341) and the China Minmetals Corporation Program (2013KC0201)

摘要: 河南瓦房铅锌矿床位于华北克拉通南缘熊耳山—外方山矿集区,矿体赋存于熊耳群鸡蛋坪组上段(Chj3)的地层中,矿石矿物有黄铁矿、方铅矿、闪锌矿和少量黄铜矿、赤铁矿、褐铁矿。该矿床热液成矿过程划分为3个阶段:石英-黄铁矿阶段(早阶段),石英-多金属阶段(中阶段),石英-碳酸盐脉阶段(晚阶段)。矿石中石英和方解石中捕获的原生包裹体类型有NaCl-H2O型两相、NaCl-CO2-H2O型三相和纯气相。气液两相包裹体3个阶段均一温度范围分别为150~260、150~230和110~160 ℃,3个阶段盐度(w(NaCl))平均值分别为12.22%、8.55%和6.29%。中阶段方解石的δ13CVPDB平均值为-7.34‰,δ18OSMOM平均值为15.56‰;晚阶段方解石的δ13CVPDB平均值为-3.05‰,δ18OSMOW平均值为2.21‰。早阶段硫化物的δ34S值为2.747‰~7.737‰,中阶段硫化物的δ34S值为-11.187‰~7.286‰。认为早中阶段成矿流体为变质流体,与中生代扬子克拉通和华北克拉通发生陆陆碰撞诱发中—新元古代时期的俯冲板片变质脱水有关,成矿晚阶段流体有大气降水的混入。硫同位素表明硫来源于中—新元古代的沉积地层,是海相硫酸盐的还原产物,在晚阶段,由于大气降水的混入导致δ34S出现负值。瓦房铅锌矿床地质特征、成矿流体特征与造山型矿床相似,因此,瓦房铅锌矿床属于造山型铅锌矿床。

关键词: 流体包裹体, S同位素, C-O同位素, 瓦房铅锌矿床

Abstract: Wafang Pb-Zn deposit is located in the Xiong'er-Waifang Mountains of the southern margin of the North China craton. The ore bodies are existed in the upper Jidanping Formation of Xiong'er Group, and the ore minerals are pyrite, galena, sphalerite and little chalcopyrite, limonite, and hematite. The hydrothermal ore-forming processes are divided into three stages:quartz-pyrite stage (early stage), quartz-polymetal stage (middle stage), and quartz-carbonate vein stage (late stage). The fluid inclusions in quartz and calcite of ores are NaCl-H2O two-phase, NaCl-CO2-H2O three-phase,and pure gas. The homogeneous temperatures the two-phase inclusions in the three stages are 150-260℃,150-230℃ and 110-160℃, respectively. The average salinity w(NaCl) in the three stages are 12.22%, 8.55%, 6.29%,respectively. The δ13CVPDB and δ18OSMOW of the calcites of the middle stage are high with the mean of -7.34‰ and 15.56‰, respectively, showing the characteristics of freshwater carbonate. The δ13CVPDB and δ18OSMOW of the late stage are at an average of -3.05‰ and 2.21‰,respectively. The δ34S values of sulfides in the early and middle stages are 2.747‰-7.737‰ and -11.187‰-7.286‰, respectively. We conclude that the ore-forming fluid in the early and middle stages was metamorphic fluid, which was related to the metamorphic dehydration of the Meso-Neoproterozoic slab subduction during Mesozoic continental collision between Yangtze and North China craton, then mixed with meteoric water in the late stage. The S isotope indicates that sulfur was derived from Meso-Neoproterozoic sedimentary stratigraphy by the reduction of marine sulfate. In the middle and late stages, negative δ34S values occurred due to the mixing with meteoric waters. The characteristics of geology and ore-forming fluid in Wafang Pb-Zn deposit are similar to orogenic deposits.

Key words: fluid inclusion, S isotope, C-O isotope, Wafang Pb-Zn deposit

中图分类号: 

  • P618.4
[1] 陈衍景,倪培,范宏瑞,等. 不同类型热液金矿系统的流体包裹体特征[J]. 岩石学报,2007,23(9):2085-2108. Chen Yanjing,Ni Pei, Fan Hongrui, et al. Diagnostic Fluid Inclusions of Different Types Hydrothermal Gold Deposits[J]. Acta Petrologica Sinca, 2007, 23(9):2085-2108.
[2] Roedder E, Bodnar R J. Geologic Pressure Determina-tions from Fluid Inclusion Studies[J]. Annual Rev Earth Planet Sci,1980, 8:263-301.
[3] Li H, Liu Y J, Wei G. Geochemistry and Gensis of the Kendekeke Iron-Gold Polymetallic Deposit at Yushu, China:Evidence from Ore Geochemistry and Fluid Inclusions[J]. Acta Geologica Sinica(English Edition), 2013, 87(2):486-500.
[4] Huang M, Lai J Q, Mo Q Y. Fluid Inclusions and Metallization of the Kendekeke Polymetallic Deposit in Qinghai Province, China[J]. Acta Geologica Sinica(English Edition), 2014, 88(2):570-583.
[5] 李士辉,张静,邓军,等.哀牢山南段长安金矿床成矿流体特征及成因类型探讨[J].岩石学报,2011,27(12):3777-3786. Li Shihui, Zhang Jing, Deng Jun, et al. The Characteristics of Ore-Forming Fluid and Genetic Type of the Chang'an Gold Deposit in Southern Ailaoshan Metallogenic Belt[J]. Acta Petrologica Sinca, 2011, 27(12):3777-3786.
[6] Kalin K, Thomas P, Christoph A H. Direct Analysis of Ore-Precipitating Fluids:Combined IR Microscopy and LA-ICP-MS Study of Fluid Inclusions in Opaque Ore Minerals[J]. Economic Geology, 2010, 105:351-373.
[7] Stoffell B, Appold M S, Wilkinson J J, et al. Geo-chemistry and Evolution of Mississippi Valley-Type Mineralizing Brines from the Tri-State and Northern Arkansas Districts Determined by LA-ICP-MS Microanalysis of Fluid Inclusions[J]. Economic Geology, 2008, 103:1411-1435.
[8] Todd A B, Paul G S, Panagiotis C V, et al. The Geochemistry of Carbonate-Replacement Pb-Zn-Ag Mineralization in the Lavrion District, Attica, Greece:Fluid Inclusion, Stable Isotope, and Rare Earth Element Studies[J]. Economic Geology, 2011, 106:619-651.
[9] Duan S G, Xue C J, Chi G X, et al. Ore Geology, Fluid Inclusion, and S-and Pb-Isotopic Constraints on the Genesis of the Chitudian Zn-Pb Deposit, Southern Margin of the North China Craton[J]. Resource Geology, 2011, 61(3):224-240.
[10] Liu J, Wen S M, Deng J S, et al. Contribution of Fluid Inclusions to Variations in Solution Composition for Sphalerite/Quartz Samples from the Yunnan Province, PRC[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2013, 436:287-293.
[11] Wang C M, Deng J,Carranza E J M, et al. Nature, Diversity and Temporal-Spatial Distributions of Sediment-Hosted Pb-Zn Deposits in China[J]. Ore Geology Reviews, 2014, 56:327-351.
[12] Wang C M, Deng J, Carranza E J M, et al. Tin Metallogenesis Associated with Granitoids in the Southwest Sanjiang Tethyan Domain:Natur, Types, and Tectonic Setting[J]. Gondwana Research, 2014, 26:576-593.
[13] Wang C M, Deng J, Santosh M, et al. Timing, Tectonic Implications and Genesis of Gold Mineralization in the Xincheng Gold Deposit, China:C-H-O Isotopes, Pyrite Rb-Sr and Zircon Fission Track Thermochronometery[J]. Ore Geology Reviews, 2015, 65(3):659-673.
[14] Wang C M, Zhang D, Wu G G, et al. Geological and Isotopic Evidence for a Magmatic-Hydrothermal Origin of the Ag-Pb-Zn Deposits in the Lengshuikeng District, East-Central China[J]. Mineralium Deposita, 2014, 49(6):733-749.
[15] 姚玉增,黄菲,彭艳东,等. 山西耿庄金矿床流体包裹体特征及矿床成因[J]. 吉林大学学报(地球科学版),2013,43(1):93-101. Yao Yuzeng, Huang Fei, Peng Yandong, et al. Characteristics of Fluid Inclusion and Metallogenesis of Gengzhuang Gold Deposit, Shanxi Province[J]. Journal of Jilin University(Earth Science Edition), 2013,43(1):93-101.
[16] 王长明, 邓军, 张寿庭, 等. 河南雈香洼金矿原生晕地球化学特征和深部成矿预测[J]. 地质与勘探, 2007, 43(1), 58-63. Wang Changming, Deng Jun, Zhang Shouting, et al. Characteristic of Prmary Halo and Prediction of Deep Orebody in the Huanxiangwa Gold Deposit, Henan[J]. Geology and Prospecting, 2007, 43(1):58-63.
[17] 王长明, 邓军, 张寿庭. 河南雈香洼金矿找矿综合模型[J].黄金, 2006, 27(6):11-14. Wang Changming, Deng Jun, Zhang Shouting. Integrated Ore Prospecting Model of the Huanxiangwa Gold Deposit, Henan[J]. Gold, 2006, 27(6):11-14.
[18] 王长明, 邓军, 张寿庭, 等. 河南雈香洼金矿围岩蚀变与金矿化的关系[J]. 黄金, 2006, 27(4):9-14. Wang Changming, Deng Jun, Zhang Shouting, et al. Relationship Between Wall Rock Alteration and Gold Mineralization of Huanxiangwa Deposit, Henan Province[J]. Gold, 2006, 27(4):9-14.
[19] 陈衍景, 李欣. 河南上宫金矿成矿流体研究及其对碰撞造山体制流体作用指示意义[J]. 自然科学进展, 1998,8(1):73-76. Chen Yanjing, Li Xin. Studies on Ore-forming Fluid of the Shanggong Gold Deposit, Henan and Its Significances for Fluid Processes in Collisional Orogenic Regime[J].Progress in Nature Science, 1998,8(1):73-76.
[20] 吕伟庆,刘建军. 河南北岭金矿床地质特征及深部找矿远景[J]. 矿产勘查, 2014, 5(3):436-440. Lü Weiqing, Liu Jianjun. Geological Characteristics of the Beiling Gold Deposit and Prospecting Targets at the Depth, Henan[J]. Mineral Exploration, 2014, 5(3):436-440.
[21] 李永峰,毛景文,胡华斌,等.豫西公峪金矿床流体包裹体及其He、Ar、S、H、O同位素组成对成矿流体来源的示踪[J]. 岩石学报, 2005, 21(5):1347-1358. Li Yongfeng, Mao Jingwen, Hu Huabin, et al. The Fluid Inclusions and Their He-Ar-S-H-O Isotopic Compositions and Tracing to the Source of Ore-Forming Fluids for the Gongyu Gold Deposit, Western Henan[J]. Acta Petrologica Sinica, 2005, 21(5):1347-1358.
[22] 杨立强,王中亮,吴发富,等. 河南前河金矿床成矿流体特征与来源:流体包裹体地球化学与同位素约束[J]. 矿物学报, 2009, 29(1):259-260. Yang Liqiang, Wang Zhongliang, Wu Fafu, et al. Characteristics and Source of Ore-Forming Fluids for Qianhe Gold Deposit, Henan:Constraints from Geochemistry of Fluid Inclusions and Isotope[J]. Acta Mineralogica Sinca, 2009, 29(1):259-260.
[23] Groves D I, Goldfarb R J, Gebre-Mariam M, et al. Orogenic Au Deposits:A Propsed Classification in the Context of Their Crustal Distribution and Relationship to Other Au Deposit Types[J]. Ore Geology Reviews, 1998, 13:7-27.
[24] 陈衍景. 造山型矿床、成矿模式及找矿潜力[J]. 中国地质, 2006, 33(6):1181-1196. Chen Yanjing. Orogenic-Type Deposits and Their Metallogenic Model and Exploration Potential[J]. Geology in China, 2006, 33(6):1181-1196.
[25] Chen Y J, Pirajno F, Sui Y H. Isotope Geochemistry of the Tieluping Silver-Lead Deposit, Henan, China:A Case Study of Orogenic Silver-Dominated Deposited and Related Tectonic Setting[J]. Mineralium Deposita, 2004, 39:560-575.
[26] 张静,杨艳,胡海珠,等. 河南银洞沟造山型银矿床碳硫铅同位素地球化学[J]. 岩石学报, 2009, 25(11):2833-2842. Zhang Jing, Yang Yan, Hu Haizhu, et al. C-S-Pb Isotope Geochemistry of the Yindonggou Orogenic-Type Silver Deposit in Henan Province[J]. Acta Petrologica Sinca, 2009, 25(11):2833-2842.
[27] Li Z K, Li J W, Zhao X F, et al. Crustal-Extension Ag-Pb-Zn Veins in the Xiong'ershan District,Southern North China Craton:Constraints from the Shagou Deposit[J]. Economic Geology, 2013, 188:1703-1729.
[28] 姚军明,赵太平,魏庆国,等. 河南王坪西沟铅锌矿床流体包裹体特征和矿床成因类型[J]. 岩石学报,2008, 24(9):2113-2123. Yao Junming, Zhao Taiping, Wei Qingguo, et al. Fluid Inclusion Features and Genetic Type of the Wangpingxigou Pb-Zn Deposit, Henan Province[J]. Acta Geologica Sinica, 2008, 24(9):2113-2123.
[29] 邓小华,李文博,李诺,等.河南嵩县纸房钼矿床流体包裹体研究及矿床成因[J]. 岩石学报, 2008, 24(9):2133-2148. Deng Xiaohua,Li Wenbo, Li Nuo, et al. Fluid Inclusion Constraints on the Origin of Zhifang Mo Deposit Songxian County, Henan Province[J]. Acta Petrologica Sinica, 2008, 24(9):2133-2148.
[30] 燕长海, 刘国印, 彭翼, 等. 豫西南地区铅锌银成矿规律[M]. 北京:地质出版社, 2009. Yan Changhai, Liu Guoyin, Peng Yi, et al. Pb-Zn-Ag Metallogeny of the Southwestern Henan[M]. Beijing:Geological Publishing House, 2009.
[31] 燕长海,刘良才.汝阳西灶沟铅锌矿床地球化学异常特征[J]. 河南地质, 1992, 10(1):6-14. Yan Changhai, Liu Liangcai. Anomalous Geochemical Characteristics of the Xizaogou Pb-Zn Deposit in Ruyang[J]. Henan Geology, 1992, 10(1):6-14.
[32] 黄海涛. 河南省汝阳县上寨铅锌矿床地质特征及找矿方向[J]. 西部探矿工程, 2014(12):135-139. Huang Haitao. Geological Characteristics and Prospecting Directions of Shangzhai Pb-Zn Deposit from Ruyang County, Henan Province[J].West-China Exploration Engineering, 2014(12):135-139.
[33] 彭松民,许长钊,付恒一,等. 河南汝阳王坪西沟铅锌银矿床地质及矿石组构特征分析[J]. 资源导刊(地球科技版),2013(7):4-6. Peng Songmin, Xu Changzhao, Fu Hengyi, et al. Geology and Ore Fabric Characteristics Analysis of Lead-Zinc Silver Ore Deposit from Wangpingxigou in Ruyang County, Henan Province[J]. Resources Guide(Earth Science and Technology), 2013(7):4-6.
[34] 姚军明,赵太平. 河南汝阳王坪西沟铅锌矿床氢氧硫同位素组成[J]. 矿物学报,2009 (增刊):343-345. Yao Junming, Zhao Taiping. H-O-S Isotopic Compositions of the Wangpingxigou Lead-Zinc Deposit in Ruyang, Henan Province[J]. Acta Mineralogica Sinca, 2009 (Sup.):343-345.
[35] 王长明,邓军,张寿庭. 河南西灶沟构造蚀变岩型矿床金和铅锌的关系[J]. 黄金, 2005, 26(4):13-16. Wang Changming, Deng Jun, Zhang Shouting. The Relationship Between Gold and Lead-Zinc in Xizaogou Tectonoalteration Ore Deposit, Henan Province[J]. Gold, 2005, 26(4):13-16.
[36] 姚军明,赵太平,李向辉. 河南王坪西沟铅锌矿床单颗粒闪锌矿Rb-Sr定年[J]. 矿床地质, 2010, 29(增刊):535-536. Yao Junming, Zhao Taiping, Li Xianghui. Rb-Sr Dating of Single Sphalerite of the Wangpingxigou Pb-Zn Deposit, Henan[J]. Mineral Deposit, 2010, 29(Sup.):535-536.
[37] 陈衍景,富士谷.豫西金矿成矿规律[M].北京:地震出版社, 1992. Chen Yanjing, Fu Shigu. Metallogeny of Gold Deposits in Western Henan[M]. Beijing:Seismological Press, 1992.
[38] 马志和,李海平,计文化. 华北地块南缘向北的薄皮推覆构造及北秦岭加里东造山作用[J]. 陕西地质, 1996, 14(1):14-19. Ma Zhihe, Li Haiping, Ji Wenhua. Northward Thin-Skinned Nappe Structure in the Southern Margin of North China Landmass and Caledonian Orogeny in Northern Qinling[J]. Geology of Shaanxi, 1996, 14(1):14-19.
[39] Wang C M, Chen L, Bagas L, et al. Characteristics and Orgin of the Taishanmiao Aluminous A-Type Granites:Implications for Early Cretaceous Lithospheric Thinning of the North China Craton[J]. International Journal of Earth Sciences, 2016, 105(5):1563-1589.
[40] 祝朝辉,尉向东,宋锋,等. 豫西熊耳山多金属矿集区成矿物质来源研究:来自铅同位素的地球化学证据[J]. 地质论评, 2014, 60(6):1323-1336. Zhu Chaohui,Yu Xiangdong, Song Feng, et al. Tracing on Ore-Forming Metals for Xiong'er Mountain Poly-Metal Deposit Cluster, Western Henan:A Study from Pb Isotope Geochemistry[J]. Geological Review, 2014, 60(6):1323-1336.
[41] 王志光,崔豪,徐孟罗,等. 华北地块南缘地质构造演化与成矿[M]. 北京:冶金工业出版社, 1997. Wang Zhiguang, Cui Hao, Xu Mengluo, et al. Geological Tectonic Evolution and Mineralization in Southern Margin of North China Block[M]. Beijing:Metallurgy Industry Press, 1997.
[42] 王海华,陈衍景,高秀丽. 河南康山金矿同位素地球化学及其对成岩成矿及流体作用模式的印证[J]. 矿床地质, 2001, 20(2):190-198. Wang Haihua, Chen Yanjing, Gao Xiuli. Isotope Geochemistry of the Kangshan Gold Deposit in Henan and Its Illustration of the CPMF Model[J]. Mineral Deposits, 2001, 20(2):190-198.
[43] 王铁军,樊秉鸿,关康,等. 文峪金矿矿床成因讨论[J]. 地质找矿论丛, 2002, 17(2):85-91. Wang Tiejun, Fan Binghong, Guan Kang, et al. On the Genesis of Wenyu Gold Deposit[J]. Contributions to Geology and Minerlal Resources Research, 2002, 17(2):85-91.
[44] 施强,乔刚,李红松,等. 河南文峪金矿东闯矿床深部地质特征及找矿方向[J]. 西部探矿工程, 2013, 25(4):103-108. Shi Qiang, Qiao Gang, Li Hongsong, et al. Deep Geological Characteristics and Prospecting Directions of the Dongchuang Deposit of the Wenyu Deposits, Henan[J]. West-China Exploration Engineering, 2013, 25(4):103-108.
[45] 侯红星,张德会. 熊耳山地区红庄金矿床地质特征及成因[J]. 矿床地质, 2014, 33(2):350-360. Hou Hongxing, Zhang Dehui. Geological Characteristics and Genesis of Hongzhuang Gold Deposit in Xiong'ershan Area[J].Mineral Deposits, 2014, 33(2):350-360.
[46] 朱沛云,胡斌,赖峰,等. 河南省前河金矿矿床成因及成矿模式探讨[J]. 地质找矿论丛, 2014, 29(2):199-205. Zhu Peiyun, Hu Bin,Lai Feng, et al. Discussion on Genesis and Metallogenic Model of Qianhe Gold Deposit in Songxian County, Henan Province[J]. Contributions to Geology and Minerlal Resources Research, 2014, 29(2):199-205.
[47] 杨登美,郭建中. 河南康山金矿田近矿围岩蚀变及其找矿意义[J]. 西安工程学院学报, 2000, 22(3):19-22. Yang Dengmei, Guo Jianzhong. The Wall-Rock Alteration of Orebodies and Prospecting Significance of the Kangshan Gold Field in Henan Province[J]. Journal of Xi'an Engineering University, 2000, 22(3):19-22.
[48] 翟雷,叶会寿,周珂,等. 河南嵩县庙岭金矿地质特征与钾长石40Ar/39Ar定年[J]. 地质通报, 2012, 31(4):569-576. Zhai Lei, Ye Huishou, Zhou Ke, et al. Geological Characteristics and K-Feldspar 40Ar/39Ar Dating of the Miaoling Gold Deposit in Songxian County, Henan Province[J]. Geological Bulletion of China, 2012, 31(4):569-576.
[49] 邵济安,张履桥. 华北北部中生代岩墙群[J]. 岩石学报, 2002,18 (3):312-318. Shao Ji'an, Zhang Lüqiao. Mesozoic Dyke Swarms in the North of North China[J]. Acta Petrologica Sinaca, 2002,18 (3):312-318.
[50] 王团华,毛景文,王彦斌.小秦岭-熊耳山地区岩墙锆石SHRIMP年代学研究:秦岭造山带岩石圈拆沉的证据[J]. 岩石学报, 2008, 24(6):1273-1287. Wang Tuanhua, Mao Jingwen, Wang Yanbin. Research on SHRIMP U-Pb Chronology in Xiaoqinling-Xiong'ershan Area:The Evidence of Delamination of Lithosphere in Qingling Orogenic Belt[J]. Acta Petrologica Sinica, 2008, 24(6):1273-1287.
[51] 郭波,朱赖民,李犇,等. 华北陆块南缘华山和合峪花岗岩岩体锆石U-Pb年龄、Hf同位素组成与成岩动力学背景[J]. 岩石学报, 2009, 25(2):265-281. Guo Bo, Zhu Laimin, Li Ben, et al. Zircon U-Pb Age and Hf Isotope Composition of Huashan and Heyu Granite Plutons at the Southern Margin of North China Craton:Implications for Geodynamic Setting[J]. Acta Petrologica Sinica, 2009, 25(2):265-281.
[52] 张兴康,叶会寿,李正远,等. 小秦岭华山复式岩基大夫峪岩体锆石U-Pb年龄、Hf同位素和地球化学特征[J]. 矿床地质, 2015, 34(2):235-260. Zhang Xingkang, Ye Huishou, Li Zhengyuan, et al. Zircon U-Pb Ages, Hf Isotope Composition and Geochemistry of Dafuyu Granitoid Poluton from Huashan Complex Batholith in Xiaoqinling[J]. Mineral Deposits, 2015, 34(2):235-260.
[53] 肖娥,胡建,张遵忠,等. 东秦岭花山复式岩基中蒿坪与金山庙花岗岩体岩石地球化学、锆石U-Pb年代学和Lu-Hf同位素组成[J]. 岩石学报, 2012, 28(12):4031-4046. Xiao E, Hu Jian, Zhang Zunzhong, et al. Petrogeochemistry, Zircon U-Pb Dating and Lu-Hf Isotopic Compositions of the Haoping and Jinshanmiao Granites from the Huashan Complex Batholith in Eastern Qinling Orogen[J]. Acta Petrologica Sinica, 2012, 28(12):4031-4046.
[54] 聂政融,王晓霞,柯昌辉,等. 华北地块南缘花山、五丈山岩体LA-ICP-MS锆石U-Pb年龄、地球化学特征及成因[J]. 地质通报, 2015, 34(8):1502-1516. Nie Zhengrong, Wang Xiaoxia, Ke Changhui, at al. Age, Geochemistry and Petrogenesis of Huashan Granitonid Pluton on the Southern Margin of the North China Block[J]. Geological Bulletion of China, 2015, 34(8):1502-1516.
[55] Li N, Chen Y J, Pirajno F, et al. LA-ICP-MS Zircon U-Pb Dating, Trace Element and Hf Isotope Geochemistry of the Heyu Granite Batholith, Eastern Qinling, Central China:Implications for Mesozoic Tectono-Magmatic Evolution[J]. Lithos, 2012,142/143:34-47.
[56] Gao X Y, Zhao T P, Bao Z W, et al. Petrogenesis of the Early Cretaceous Intermediate and Felsic Intrusions at the Southern Margin of the North China Craton:Implications for Crust-Mantle Interaction[J]. Lithos, 2014,206/207:65-78.
[57] 李永峰,毛景文,刘敦一,等. 豫西雷门沟斑岩钼矿SHRIMP锆石U-Pb和辉钼矿Re-Os测年及其地质意义[J]. 地质论评, 2006, 52(1):122-131. Li Yongfeng, Mao Jingwen, Liu Dunyi, et al. SHRIMP Zircon U-Pb and Molybdenite Re-Os Dating for Leimengou Porphyry Molybdenum Deposit, Western Henan and Its Geological Implication[J]. Geological Review, 2006, 52(1):122-131.
[58] Wang C M, Lu Y J, He XY, et al. The Paleo-proterozoic Diorite Dykes in the Southern Margin of the North China Craton:Insight into Rift-Related Magmatism[J]. Precambrian Research, 2016, 227:26-46.
[59] Hall D L, Sterner S M, Bodnar R J. Freezing Point Depression of NaCl-KCl-H2O Solutions[J]. Economic Geology, 1988, 83:197-202.
[60] Roedder E. Fluid inclusions. Reviews in Mineralogy[J]. Mineral Soc Amer, 1984, 12:644.
[61] 王长明, 徐贻赣, 吴淦国, 等. 江西冷水坑Ag-Pb-Zn矿田碳、硫、铅 同位素及成矿物质来源[J]. 地学前缘, 2011, 18(1):179-193. Wang Changming, Xu Yigan, Wu Ganguo, et al. C, O, S and Pb Isotopes Characteristics and Sources of the Ore Metals of the Leishuikeng Ag-Pb-Zn Ore Field, Jiangxi[J]. Earth Science Frontiers, 2011, 18(1):179-193.
[62] 王铭生,燕建设,星玉才,等. 马超营断裂带金矿床δ34S特征及有关问题讨论[J]. 河南地质, 1998, 16(2):81-86. Wang Mingsheng, Yan Jianshe, Xing Yucai, et al. The δ34S-Properties of Gold Deposits in the Machaoying Faulted Zone and Some Related Problems[J]. Henan Geology, 1998, 16(2):81-86.
[63] 李诺,赖勇,鲁颖淮,等. 河南祁雨沟金矿流体包裹体及矿床成因类型研究[J]. 中国地质, 2008, 35(6):1230-1239. Li Nuo, Lai Yong, Lu Yinghuai, et al. Study of Fluid Inclusions and Ore Genetic Type of the Qiyugou Gold Deposit, Henan[J]. Geology in China, 2008, 35(6):1230-1239.
[64] 卢焕章,范宏瑞,倪培,等.流体包裹体[M]. 北京:科学出版社, 2004:207. Lu Huanzhang, Fan Hongrui,Ni Pei, et al. Fiuid Inclusion[M]. Beijing:Science Press, 2004:207.
[65] Collins P L F. Gas Hydrates in CO2-Bearing Fluid Inclusions and the Use of Freezing Data for Estimation of Salinity[J]. Economic Geology, 1979, 74:1435-1444.
[66] 郭春影. 胶东三山岛-仓上金矿带构造-岩浆-流体金成矿系统[D]. 北京:中国地质大学, 2009. Guo Chunying. Tectonic Setting, Magmatic Sequence and Fluid of Gold Metallogenic System of the Sanshandao-Cangshang Fault in Jiaodong, China[D]. Beijing:China University of Geosciences, 2009.
[67] Hoefs J. Stable Isotope Geochemistry:Fourth Edition[M]. Berlin:Springer Verlag, 1997:201.
[68] Chen, Y J, Pirajno F, Qi J P. The Shanggong Gold Deposit, Eastern Qingling Orogeny, China:Isotope Geochemistry and Implications for Ore Genesis[J]. Journal of Asian Earth Sciences, 2008, 33:252-266.
[69] 王帅,赵永刚. 鄂尔多斯盆地东缘奥陶系碳酸盐岩碳氧同位素偏负原因探讨[J]. 中国石油和化工标准与质量, 2014(5):209. Wang Shuai, Zhao Yonggang. Discussion on the Reason for C-O Isotope Negative Anomalies for Ordocician Carbonate Rocks in the Eastern Ordos Basin[J]. China Petroleum and Chemical Standard and Quality, 2014(5):209.
[70] 杨华,王宝清,孙六一,等. 鄂尔多斯盆地中奥陶统马家沟组碳酸盐岩碳、氧稳定同位素特征[J]. 天然气地球科学, 2012, 23(4):616-625. Yang Hua, Wang Baoqing, Sun Liuyi, et al. Characteristics of Oxygen and Carbon Stable Isotope for Middle Ordocician Majiagou Formation Carbonate Rocks in the Ordos Basin[J]. Natural Gas Geoscience, 2012, 23(4):616-625.
[71] Fature G. Principles of Isotope Geology:Second Edition[M]. New York:John Wiley&Sons, 1986:589.
[72] 姜盛洪,王长明,赵海,等.新城金矿稳定同位素地球化学特征及成矿物质来源探讨[J]. 地质与勘探, 2015, 51(1):68-78. Jiang Shenghong, Wang Changming, Zhao Hai, et al. Geochemical Characteristics of Stable Isotope and Metallogenic Material Source in the Xincheng Gold Deposit[J]. Geology and Exploration, 2015, 51(1):68-78.
[73] 李楠,杨立强,张闯,等. 西秦岭阳山金矿带硫同位素特征:成矿环境与物质来源约束[J]. 岩石学报, 2012, 28(5):1577-1587. Li Nan, Yang Liqiang, Zhang Chuang, et al. Sulfur Isotope Characteristics of the Yangshan Gold Belt, West Qingling:Constrains on Ore-Forming Environment and Material Source[J]. Acta Petrologica Sinica, 2012, 28(5):1577-1587.
[74] 马星华,陈斌. 大兴安岭南段敖仑花斑岩钼(铜)矿床成矿流体来源与成矿作用:稳定同位素C、H、O、S和放射性Pb同位素约束[J]. 吉林大学学报(地球科学版),2011,41(6):1770-1783. Ma Xinghua, Chen Bin. The Source of Hydrothermal Fluids and Mineralization in the Aolunhua Porphyry Mo-Cu Deposit, Southern Da Hinggan Mountains:Constraints from Stable (C, H, O and S) and Radiogenic (Pb) Isotopes[J]. Journal of Jilin University (Earth Science Edition), 2011,41(6):1770-1783.
[75] 郑永飞. 稳定同位素地球化学[M]. 北京:科学出版社, 1999:62-118. Zheng Yongfei. Stable Isotope Geochemistry[M]. Beijing:Science Press, 1999:62-118.
[76] Emery D, Robinson A. Inorganic Geochemistry:Applications to Petroleum Geology[M].London:Wiley-Blackwell, 1993:73-101.
[77] 陈衍景,林治家,Pirajno Franco,等.东秦岭上宫金矿流体成矿作用:稳定同位素地球化学研究[J]. 矿物岩石, 2004, 24(3):13-21. Chen Yanjing, Lin Zhijia,Pirajno F, et al. Hydrothermal Metallogeny of the Shanggong Gold Deposit, East Qingling Study on the Stable Isotope Geochemistry[J]. Mineral Petrol, 2004, 24(3):13-21.
[78] 范宏瑞,谢奕汉,赵瑞,等. 豫西熊耳山地区岩石和金矿床稳定同位素地球化学研究[J]. 地质找矿论丛, 1994, 9(1):54-64. Fan Hongrui, Xie Yihan, Zhao Rui, et al. Stable Isotope Geochemistry of Rocks and Gold Deposits in the Xiong'ershan Area Western Henan Province[J]. Contributions to Geology and Minerlal Resources Research, 1994, 9(1):54-64.
[79] 卢欣祥,尉向东,于在平,等.小秦岭-熊耳山金成矿作用与区域构造的耦合[J]. 黄金地质, 2004, 10(1):1-5. Lu Xinxiang, Yu Xiangdong, Yu Zaiping, et al. Minerogenesis of Gold and Its Coupling with Tectonics in Xiaoqingling-Xiong'ershan Region[J]. Gold Geology, 2004, 10(1):1-5.
[80] Kerrich R. Nature's Gold Factory[J]. Science, 2000, 284:2101-2102.
[81] Goldfarb R J,Groves D I, Gardoll S. Orogenic Gold and Geologic Time:A Global Synthesis[J]. Ore Geology Review, 2001, 18:1-75.
[82] 陈衍景,隋颖慧,Pirajno Franco,等. CMF模式的排他性依据和造山型银矿实例:东秦岭铁炉坪银矿同位素地球化学[J]. 岩石学报, 2003, 19(3):551-568. Chen Yanjing, Sui Yinghui, Pirajno F, et al. Exclusive Evidences for CMF Model and a Case of Orogenic Silver Deposits:Isotope Geochemistry of the Tieluping Silver Deposit, East Qingling Orogen[J]. Acta Petrologica Sinica, 2003, 19(3):551-568.
[83] 张元厚,张世红,韩以贵,等. 华熊地块马超营断裂走滑特征及演化[J]. 吉林大学学报(地球科学版), 2006, 36(2):169-176, 193. Zhang Yuanhou, Zhang Shihong, Han Yigui, et al. Strik-Slip Features of the Machaoying Fault Zone and Its Evolution in the Huaxiong Terrane, Southern North China Craton[J]. Journal of Jilin University(Earth Science Edition), 2006, 36(2):169-176, 193.
[84] 倪志勇,李诺,管申进,等. 河南小秦岭金矿田大湖金-钼矿床流体包裹体特征及矿床成因[J]. 岩石学报, 2008, 24(9):2058-2068. Ni Zhiyong, Li Nuo, Guan Shenjin, et al. Characteristics of Fluid Inclusions and Ore Genesis of the Dahu Au-Mo Deposit in the Xiaoqinling Gold Field, Henan Province[J]. Acta Petrologia Sinca, 2008, 24(9):2058-2068.
[85] 张静,杨艳,鲁颖怀,等. 河南破山银矿床地质地球化学特征及成因研究[J]. 中国地质, 2008, 35(6):1220-1228. Zhang Jing, Yang Yan, Lu Yinghuai, et al. Geological and Geochemical Characteristics and Genesis of the Poshan Silver Deposit, Henan Province[J]. Geology in China, 2008, 35(6):1220-1228.
[86] Li W B, Zhong RC, Xu C, et al. U-Pb and Re-Os Geochronology of the Bainaimiao Cu-Mo-Au Deposit, on the Northern Margin of the North China Craton, Central Asia Orogenic Belt:Implications for Ore Genesis and Geodynamic Setting[J]. Ore Geology Reviews, 2012, 48:139-150.
[87] 祁进平. 河南栾川地区脉状铅锌银矿床地质地球化学特征及成因[D]. 北京:北京大学, 2006. Qi Jinping. The Characteristics of Geology and Geochemistry and Genesis of Vein Pb-Zn-Ag Deposits in Luanchuan Area, Henan Province[D]. Beijing:Peking University, 2006.
[1] 李向文, 张志国, 王可勇, 孙加鹏, 杨吉波, 杨贺. 大兴安岭北段宝兴沟金矿床成矿流体特征及矿床成因[J]. 吉林大学学报(地球科学版), 2018, 48(4): 1071-1084.
[2] 李文强, 郭巍, 孙守亮, 杨绪海, 刘帅, 侯筱煜. 塔里木盆地巴楚—麦盖提地区古生界油气藏成藏期次[J]. 吉林大学学报(地球科学版), 2018, 48(3): 640-651.
[3] 陈瑞莉, 陈正乐, 伍俊杰, 梁志录, 韩凤彬, 王永, 肖昌浩, 韦良喜, 沈滔. 甘肃合作早子沟金矿床流体包裹体及硫铅同位素特征[J]. 吉林大学学报(地球科学版), 2018, 48(1): 87-104.
[4] 和成忠, 张德会, 吴鸣谦, 夏岩, 张荣臻, 胡铁军. 辽宁青城子姚家沟斑岩型钼矿流体包裹体[J]. 吉林大学学报(地球科学版), 2017, 47(6): 1717-1731.
[5] 门兰静, 孙景贵, 王好均, 柴鹏, 赵克强, 古阿雷, 刘城先. 延边浅成高硫化热液金矿床的成矿流体起源与演化:以杜荒岭和九三沟矿床为例[J]. 吉林大学学报(地球科学版), 2017, 47(5): 1365-1382.
[6] 耿艳光, 简伟, 李洪英, 叶会寿, 毕珉烽, 胡乔青, 李超, 范成龙, 王梦琦. 中条山篦子沟铜矿辉钼矿铼-锇同位素年龄及其地质意义[J]. 吉林大学学报(地球科学版), 2017, 47(5): 1405-1418.
[7] 张艳, 韩润生, 魏平堂, 邱文龙. 云南会泽矿山厂铅锌矿床流体包裹体特征及成矿物理化学条件[J]. 吉林大学学报(地球科学版), 2017, 47(3): 719-733.
[8] 赵彦德, 齐亚林, 罗安湘, 程党性, 李继宏, 黄锦绣. 应用流体包裹体和自生伊利石测年重构鄂尔多斯盆地侏罗系油藏烃类充注史[J]. 吉林大学学报(地球科学版), 2016, 46(6): 1637-1648.
[9] 张朋, 杨宏智, 李斌, 寇林林, 杨凤超. 辽东青城子矿集区姚家沟钼矿床成矿物质来源、成矿年代及成矿动力学背景[J]. 吉林大学学报(地球科学版), 2016, 46(6): 1684-1696.
[10] 王力, 孙丽伟. 山东省寺庄金矿床成矿流体特征[J]. 吉林大学学报(地球科学版), 2016, 46(6): 1697-1710.
[11] 张延军, 孙丰月, 李碧乐, 李良, 陈扬. 青海湟中县三岔金矿流体包裹体特征及矿床成因[J]. 吉林大学学报(地球科学版), 2016, 46(5): 1342-1353.
[12] 王晰, 段明新, 任云生, 侯召硕, 孙德有, 郝宇杰. 内蒙古额尔古纳地区八大关铜钼矿床流体包裹体特征与成矿时代[J]. 吉林大学学报(地球科学版), 2016, 46(5): 1354-1367.
[13] 吴海枝, 韩润生, 吴鹏. 楚雄盆地六苴砂岩型铜矿床成矿流体性质及演化[J]. 吉林大学学报(地球科学版), 2016, 46(2): 398-411.
[14] 王可勇, 付丽娟, 韦烈民, 王志高. 辽宁榛子沟铅锌矿床热液叠加成矿作用特征及成矿流体来源[J]. 吉林大学学报(地球科学版), 2016, 46(1): 80-90.
[15] 韩润生, 李波, 倪培, 邱文龙, 王旭东, 王天刚. 闪锌矿流体包裹体显微红外测温及其矿床成因意义——以云南会泽超大型富锗银铅锌矿床为例[J]. 吉林大学学报(地球科学版), 2016, 46(1): 91-104.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!