Journal of Jilin University(Earth Science Edition) ›› 2018, Vol. 48 ›› Issue (5): 1378-1393.doi: 10.13278/j.cnki.jjuese.20170163

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Chemical Components and Boron Isotopic Composition of Tourmaline of Uranium Bearing Porphyroclastic Lava in Xiangshan, Jiangxi

Dai Jiaqi1, Li Guangrong1,2, Guo Fusheng1, Wang Chao1, Wang Zhe1, Zhang Wanliang3, Yu Yushuai4   

  1. 1. Fundamental Science on Radioactive Geology and Exploration Technology Laboratory/School of Earth Sciences, East China University of Technology, Nanchang 330013, China;
    2. State Key Laboratory for Mineral Deposits Research/School of Earth Sciences and Engineering, Nanjing University, Nanjing 210093, China;
    3. Research Institute No. 270, CNNC, Nanchang 330200, China;
    4. Wuhan Center of China Geological Survey, Wuhan 430205, China
  • Received:2017-12-06 Published:2018-11-20
  • Supported by:
    Supported by the National Natural Science Foundation of China (41402028,41572185) and Project of China Geological Survey (DD20160134,121201009000150007)

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Abstract: The Xiangshan uranium ore-field is the largest volcanic uranium ore-field in China, its ore-hosting rock is mainly of rhyodacite and porphyroclastic lava with a small amount of the Precambrian metamorphic rocks and Mesozoic granite porphyry. The porphyroclastic lava sub-facies yielde spherical tourmaline nodules with diameters of 10-20 cm, in which the main mineral assemblage is of tourmaline, quartz and minor feldspar, mixed with a small amount of uraninite. Tourmaline alterated early formed feldspar. A detailed mineralogical study for the tourmaline in porphyroclastic lava of the Ruyiting area in Xiangshan was performed by means of the microscope, electron probe, laser ablation multi-collector inductively coupled plasma mass spectrometry. The electron microprobe analysis shows that the tourmaline in porphyroclastic lava is the typical schorl characterized by the enrichment of Na, Fe. The volatile components are high in the tourmaline, of which the content of B2O3 is 9.38%-10.04%, and F is 0.10%-1.77%. The high volatile components such as B and F in ore-forming fluid with high oxygen fugacity in early stage of magma evolution made the U element more actively to form complex, which is more conducive to U migration and enrichment. The analysis of boron isotope in tourmaline from two porphyroclastic lava samples was performed by means of in-situ microanalysis of boron isotopes (LA-MC-ICP-MS). The results show that the content of δ11 B in tourmaline is (-13.15±0.72) ‰-(-12.28±0.63) ‰ with the mean value of (-12.72±0.94) ‰; which indicates that the Xiangshan volcano intrusive complex mainly comes from the partial melting of the Xiangshan crustal basement rocks.

Key words: boron isotope, tourmaline, porphyroclastic lava, Xiangshan uranium ore-field

CLC Number: 

  • P619.14
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