Journal of Jilin University(Earth Science Edition) ›› 2023, Vol. 53 ›› Issue (3): 822-839.doi: 10.13278/j.cnki.jjuese.20210363

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 Geochronology and Ore-Forming Fluid Characteristics of Baituyingzi Molybdenum Deposit, Inner Mongolia

Zhao Keqiang1,2, Sun Jinggui3, Cheng Lin4, Ma Shengming1,2, Wang Zhenliang1,2, Gu Alei5   

  1. 1. Institute of Geophysical and Geochemical Exploration, Chinese Academy of Geological Sciences, Langfang 065000, Hebei, China
    2. Key Laboratory for Geochemical Exploration Technology, Ministry of Natural Resources, Langfang 065000, Hebei, China
    3. College of Earth Sciences, Jilin University, Changchun 130061, China
    4. Hebei Regional Geological Survey Institute, Langfang 065000,  Hebei, China
    5. Tianjin Center of China Geological Survey, China Geological Survey,Tianjin 300170, China
  • Received:2021-11-16 Online:2023-05-26 Published:2023-05-26
  • Supported by:
    Supported by the National Key R&D Program of China (2018YFE0208300), the Project of China Geological Survey (AS2020Y05,DD20190571) and the National Natural Science Foundation of China (42072085)

Abstract: Baituyingzi molybdenum deposit is located in the south of the Xilamulun molybdenum metallogenic belt, which is a new exploration discovered medium porphyry type molybdenum deposit in recent years. This paper reports the geological characteristics, Re-Os age of molybdenite, fluid inclusions and H-O-S-Pb isotope data of  Baituyingzi molybdenum deposit to determine its metallogenic age and fluid characteristics. Molybdenum mineralization mainly exists in veinlet-disseminated, breccia-type and vein-type forms in Indosinian granite porphyry. The Re-Os isochron age of (245.4 ± 4.1) Ma for the molybdenite indicates that molybdenum mineralization occurred in the Middle Triassic. Four types of inclusions were identified: gas-liquid two-phase inclusions (W), CO2-bearing three-phase inclusions (C),  daughter crystals-bearing three-phase inclusions (S) and pure gas-phase inclusions. The Ore-forming fluid in the early stage of mineralization belongs to the CO2-H2O-NaCl system with medium-high temperature and medium-low salinity, while the main mineralization stage is characterized by medium temperature, high-salt and low-salinity coeval, and the gas-phase composition is gradually transformed into H2O-based. The fluid undergoes immiscibility during the ore-forming process, accompanied by the separation and precipitation of a large number of metal minerals. With the continuous reduction of temperature and pressure, and the addition of atmospheric water, the fluid evolved into H2O-NaCl system with medium-low temperature and low salinity and low CO2 in the late stage of mineralization. Combined with the H-O-S-Pb isotopic data, it is believed that the ore-forming materials are mainly derived from the mantle, the crust-derived materials are added in the late stage of mineralization, and the source of the crust-mantle mixture as a whole. The ore-forming fluid is derived from magmatic hydrothermal solution in the early stage, atmospheric water is added in the late stage. Therefore, we suggest that  Baituyingzi porphyry-type molybdenum deposit was formed in the post-orogenic extension environment in the Early-Middle Triassic. The source of the ore-forming materials in porphyry molybdenum deposits is mainly crust-mantle mixed or crust, while the source of ore-forming materials of copper is mantle. The oxygen fugacity and pH value of the fluid are two of the main factors for the precipitation of molybdenite.

Key words:  , Baituyingzi molybdenum deposit, Triassic, metallogenic chronology, ore-forming fluid, Inner Mongolia ,

CLC Number: 

  • P618.65
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