Journal of Jilin University(Earth Science Edition) ›› 2015, Vol. 45 ›› Issue (1): 188-197.doi: 10.13278/j.cnki.jjuese.201501115

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Very Low Grade Metamorphic Temperatures of the Upper Paleozoic Strata in Northern Daxing'anling Area, NE China:Evidence from Raman Spectrum Studies of Carbonaceous Materials

Hu Daqian, Wang Yanquan, Sha Qian, Wang Chunguang, Chen Xu, Ma Rui   

  1. Colloge of Earth Sciences, Jilin University, Changchun 130061, China
  • Received:2014-03-03 Published:2015-01-26

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Abstract:

Using the Renishaw System-1000 laser Raman spectrometer, authors have studied the laser Raman spectrum characteristics of the carbonaceous materials in pelitic rocks outcropped in northern Daxing'anling area and its indication to the metamorphic temperature. The relationship between the various parameters of the Raman spectrum and the vitrinite reflectance (Ro) of the carbonaceous materials is also discussed. The study shows that the carbonaceous material of Upper Paleozoic pelitic rock has not the Raman spectrum absorption peak of graphite, revealing its metamorphic grade below the low-greenschist facies. Using Raman spectroscopy constructed and proposed by Barker et al. (1986) and by Rahl et al.(2005), the metamorphic temperature of Upper Paleozoic pelitic rock in the studied area is estimated at 270℃ to 320℃, indicating the Paleozoic strata of the area have merely undergone very low grade metamorphism and metamorphic grade belongs to anchizone. Based on the relationship between the laser Raman spectrometer of carbonaceous materials and the vitrinite reflectance(Ro) proposed by Wang Y, et al.(2002), the Ro values (maturity of organic materials) of pelitic rocks are estimated to be from 3.03% to 4.23%, consistent with the measured values, showing that the evolution of organic matter of the area is at the over-mature stage, and the pelitic rocks in the area are capable to be generate the hydrocarbon generation and part of the them may have the potential for oil and gas resources.

Key words: Northern Daxing'anling area, Upper Paleozoic pelitic rock, Raman spectrum of carbonaceous material, vitrinite reflectance, geothermometer, very low grade metamorphism

CLC Number: 

  • P574.1

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