Journal of Jilin University(Earth Science Edition) ›› 2021, Vol. 51 ›› Issue (1): 247-255.doi: 10.13278/j.cnki.jjuese.20190207

Previous Articles    

Removal of Hexavalent Chromium from Simulated Groundwater by Variety of Iron-Modified and Unmodified Biochars

Wang Sheng1, Feng Xiang2, Li Bing2, Guo Lin2, Cao Kun1, Liu Peng1   

  1. 1. College of Environment, China University of Geosciences, Wuhan 430074, China;
    2. Henan Institute of Geological Survey, Zhengzhou 450001, China
  • Received:2019-09-24 Published:2021-02-02
  • Supported by:
    Supported by the National Natural Science Foundation of China (41877478) and the National Key R&D Program of China (2018YFC1801706-04)

PDF (PC)

199

Abstract: Biochar is usually used in Cr(Ⅵ) removal due to its micro porous structure and huge specific surface area, but different biochar has different removal efficiency. Choosing poplar, willow, peach,and pine as feedstocks, twenty types of biochar were prepared through pyrolysis of the FeCl3-modified and unmodified biomass with different particle sizes at 300 ℃ or 600 ℃, respectively. A batch of experiments were performed to evaluate the efficiency of different biochar in removing hexavalent chromium from the simulated groundwater. The mechanism of Cr(Ⅵ) removal by biochar was investigated using Fourier transform infrared (FTIR) spectroscopy and X-ray absorption near edge spectrum (XANES). The results showed that the removal efficiency of the modified biochar by pyrolysis at 300 ℃ was over 99.0% of Cr(Ⅵ); The biochar (<0.5 mm) showed better removal efficiency than the biochar with a particle size of 2 mm; The Cr (Ⅵ) removal process by FeCl3BC300Y could be well described by the pseudo-first-order equation; XANES analysis suggested that the chromium on FeCl3BC300Y was in a trivalent state, and FTIR analysis indicated that hydroxyl and carboxylate groups contributed to Cr(Ⅵ) removal. The mechanism of Cr(Ⅵ) removal by biochar included reduction and complexation. The biochar modified by iron is expected as a filler material of permeable reactive barriers, and will become a new material to repair groundwater contaminated by hexavalent chromium.

Key words: biochar, iron modified, removal of hexavalent chromium

CLC Number: 

  • X523
[1] Chen S, Yue Q, Gao B, et al. Adsorption of Hexavalent Chromium from Aqueous Solution by Modified Corn Stalk:A Fixed-Bed Column Study[J]. Bioresource Technology, 2012, 113(4):114-120.
[2] 张厚坚, 王兴润, 陈春云, 等. 高原地区铬渣污染场地污染特性研究[J]. 环境工程学报, 2010, 4(4):915-918. Zhong Houjian, Wang Xingrun, Chen Chunyun, et al. Study on the Polluting Property of Chrome Residue Contaminated Sites in Plateau Section[J]. Chinese Journal of Environmental Engineering, 2010, 4(4):915-918.
[3] 崔永高. 铬污染土壤和地下水的修复技术研究进展[J]. 工程地质学报, 2017, 25(4):1001-1009. Cui Yonggao. Research Progress on Remediation Technology of Chromium Contaminated Soils and Groundwater in Shanghai[J]. Journal of Engineering Geology, 2017, 25(4):1001-1009.
[4] Pellerin C, Booker S M. Reflections on Hexavalent Chromium:Health Hazards of an Industrial Heavyweight[J]. Environmental Health Perspectives, 2000, 108(9):A402-A407.
[5] 吴继明, 程胜高. 探讨六价铬对人体健康的影响及防治措施[J]. 现代预防医学, 2009, 36(24):4610-4611. Wu Jiming, Cheng Shenggao. The Influence and Precautionary and Therapeutic Measures of Human Health in Exposure of Hexavalent Chromium[J]. Modern Preventive Medicine, 2009, 36(24):4610-4611.
[6] 地下水质量标准:GB/T 14848-2017[S]. 北京:中国标准出版社, 2017. Quality Standard for Ground Water:GB/T 14848-2017[S]. Beijing:China Standards Press, 2017.
[7] 杨维, 王立东, 徐丽, 等. 铬污染地下水的PRB反应介质筛选及修复试验[J]. 吉林大学学报(地球科学版), 2008, 38(5):854-858. Yang Wei, Wang Lidong, Xu Li, et al. Experiment on Selection of PRB Media and Remediation of Chromium Contaminated Groundwater[J]. Journal of Jilin University (Earth Science Edition), 2008,38(5):854-858.
[8] Blowes D W, Ptacek C J, Jambor J L. In-Situ Remediation of Cr(Ⅵ)-Contaminated Groundwater Using Permeable Reactive Walls:Laboratory Studies[J]. Environ Sci Technol, 1997, 31(12):3348-3357.
[9] 董军, 赵勇胜, 赵晓波, 等. PRB技术处理污染地下水的影响因素分析[J]. 吉林大学学报(地球科学版), 2005, 35(2):226-230. Dong Jun, Zhao Yongsheng, Zhao Xiaobo, et al. Analysis of Influencing Factors on in Situ Remediation of Leachate Polluted Groundwater with PRB Technology[J]. Journal of Jilin University (Earth Science Edition), 2005, 35(2):226-230.
[10] Waybrant K R, Ptacek C J, Blowes D W. Treatment of Mine Drainage Using Permeable Reactive Barriers:Column Experiments[J]. Environmental Science & Technology, 2002, 36(6):1349-1356.
[11] Tytak A, Oleszczuk P, Dobrowolski R. Sorption and Desorption of Cr(Ⅵ) Ions from Water by Biochars in Different Environmental Conditions[J]. Environmental Science & Pollution Research International, 2015, 22(8):5985-5994.
[12] Choudhary B, Paul D. Isotherms, Kinetics and Thermodynamics of Hexavalent Chromium Removal Using Biochar[J]. Journal of Environmental Chemical Engineering, 2018, 6(2):2335-2343.
[13] Mohan D, Pittman C U. Activated Carbons and Low Cost Adsorbents for Remediation of Tri-and Hexavalent Chromium from Water[J]. Journal of Hazardous Materials, 2006, 137(2):762-811.
[14] Farghali A A, Tawab H A A, Moaty S A A, et al. Functionalization of Acidified Multi-Walled Carbon Nanotubes for Removal of Heavy Metals in Aqueous Solutions[J]. Journal of Nanostructure in Chemistry, 2017, 7(2):101-111.
[15] Boddu V M, Krishnaiah A, Talbott J L, et al. Removal of Hexavalent Chromium from Wastewater Using a New Composite Chitosan Biosorbent[J]. Environmental Science & Technology, 2003, 37(19):4449-4456.
[16] Gupta V K, Rastogi A, Nayak A. Adsorption Studies on the Removal of Hexavalent Chromium from Aqueous Solution Using a Low Cost Fertilizer Industry Waste Material[J]. Journal of Colloid & Interface Science, 2010, 342(1):135-141.
[17] Kumar S, Loganathan V A, Gupta R B, et al. An Assessment of U(Ⅵ) Removal from Groundwater Using Biochar Produced from Hydrothermal Carbonization[J]. Journal of Environmental Management, 2011, 92(10):2504-2512.
[18] Dong X, Ma L Q, Li Y. Characteristics and Mechanisms of Hexavalent Chromium Removal by Biochar from Sugar Beet Tailing[J]. Journal of Hazardous Materials, 2011, 190(1):909-915.
[19] Ouyang X, Han Y T, Cao X, et al. Magnetic Biochar Combining Adsorption and Separation Recycle for Removal of Chromium in Aqueous Solution[J]. Water Science & Technology:A Journal of the International Association on Water Pollution Research, 2017, 75(5):1177-1184.
[20] Qian L B, Liu S N, Zhang W Y, et al. Enhanced Reduction and Adsorption of Hexavalent Chromium by Palladium and Silicon Rich Biochar Supported Nanoscale Zero-Valent Iron[J]. Journal of Colloid and Interface Science, 2019, 533:428-436.
[21] Zhu S, Huang X, Wang D, et al. Enhanced Hexavalent Chromium Removal Performance and Stabilization by Magnetic Iron Nanoparticles Assisted Biochar in Aqueous Solution:Mechanisms and Application Potential[J]. Chemosphere, 2018, 207:50-59.
[22] 蒋旭涛, 迟杰. 铁改性生物炭对磷的吸附及磷形态的变化特征[J]. 农业环境科学学报, 2014, 33(9):1817-1822. Jiang Xutao, Chi Jie. Phosphorus Adsorption by and Forms in Fe-Modified Biochar[J]. Journal of Agro-Environment Science, 2014, 33(9):1817-1822.
[23] Zhang K,Sun P,Zhang Y. Decontamination of Cr(Ⅵ) Facilitated Formation of Persistent Free Radicals on Rice Husk Derived Biochar[J]. Frontiers of Environmental Science & Engineering, 2019(2):85-93.
[24] Chen S, Yue Q, Gao B, et al. Adsorption of Hexavalent Chromium from Aqueous Solution by Modified Corn Stalk:A Fixed-Bed Column Study[J]. Bioresource Technology, 2012, 113:114-120.
[25] Ahmad M, Rajapaksha A U, Lim J E, et al. Biochar as a Sorbent for Contaminant Management in Soil and Water:A Review[J]. Chemosphere, 2014, 99(3):19-33.
[26] 刘莹莹, 秦海芝, 李恋卿, 等. 不同作物原料热裂解生物质炭对溶液中Cd2+和Pb2+的吸附特性[J]. 生态环境学报, 2012, 21(1):146-152. Liu Yingying, Qin Haizhi, Li Lianqing, et al. Adsorption Characteristics of Cd2+ and Pb2+in Solution by Biochar Pyrolyzed from Different Crop Feedstock[J]. Ecology and Environmental Sciences, 2012, 21(1):146-152.
[27] Yu F, Peng L, Yanxin W, et al. Distribution and Speciation of Iron in Fe-Modified Biochars and Its Application in Removal of As(V), As(Ⅲ), Cr(Ⅵ), and Hg(Ⅱ):An X-Ray Absorption Study[J]. Journal of Hazardous Materials, 2020, 384.
[28] 沈叔平. 水中六价铬和总铬的测定:二苯基碳酰二肼分光光度法[J]. 环境污染与防治, 1982(2):24-27. Shen Shuping. Determination of Hexavalent Chromium and Total Chromium in Water:Diphenylcarbohydrazide Spectrophotometry[J]. Environmental Pollution & Control, 1982(2):24-27.
[29] Xiao X, Chen B L, Chen Z M, et al. Insight into Multiple and Multilevel Structures of Biochars and Their Potential Environmental Applications:A Critical Review[J]. Environmental Science & Technology, 2018, 52(9):5027-5047.
[30] 安增莉, 侯艳伟, 蔡超, 等. 水稻秸秆生物炭对Pb(Ⅱ)的吸附特性[J]. 环境化学, 2011, 30(11):1851-1857. An Zengli, Hou Yanwei, Cai Chao, et al. Adsorption Characteristics of Pb(Ⅱ) on Rice Straw Biochar[J]. Environmental Chemistry, 2011, 30(11):1851-1857.
[31] Zhang M, Gao B, Varnoosfaderani S, et al. Preparation and Characterization of a Novel Magnetic Biochar for Arsenic Removal[J]. Bioresource Technology, 2013, 130(1):457-462.
[32] Han Y, Cao X, Ouyang X, et al. Adsorption Kinetics of Magnetic Biochar Derived from Peanut Hull on Removal of Cr (Ⅵ) from Aqueous Solution:Effects of Production Conditions and Particle Size[J]. Chemosphere, 2016, 145:336-341.
[33] Papassiopi N, Vaxevanidou K, Christou C, et al. Synthesis, Characterization and Stability of Cr(Ⅲ) and Fe(Ⅲ) Hydroxides[J]. Journal of Hazardous Materials, 2014, 264(9):490-497.
[34] Baoliang C, Dandan Z, Lizhong Z. Transitional Adsorption and Partition of Nonpolar and Polar Aromatic Contaminants by Biochars of Pine Needles with Different Pyrolytic Temperatures[J]. Environmental Science & Technology, 2008, 42(14):5137-5143.
[35] 常春, 王胜利, 郭景阳, 等. 不同热解条件下合成生物炭对铜离子的吸附动力学研究[J]. 环境科学学报, 2016, 36(7):2491-2502. Change Chun, Wang Shengli, Guo Jingyang, et al. Adsorption Kinetics and Mechanism of Copper Ion on Biochar with Different Pyrolysis Condition[J].Acta Scientiae Circumstantiae, 2016, 36(7):2491-2502.
[36] Sharma M, Joshi M, Nigam S, et al. Zno Tetrapods and Activated Carbon Based Hybrid Composite:Adsorbents for Enhanced Decontamination of Hexavalent Chromium from Aqueous Solution[J]. Chemical Engineering Journal, 2019, 358:540-551.
[37] Liu P, Ptacek C J, Blowes D W, et al. Aqueous Leaching of Organic Acids and Dissolved Organic Carbon from Various Biochars Prepared at Different Temperatures[J]. Journal of Environmental Quality, 2015, 44(2):684-695.
[38] Gupta V K, Agarwal S, Saleh T A. Chromium Removal by Combining the Magnetic Properties of Iron Oxide with Adsorption Properties of Carbon Nanotubes[J]. Water Research, 2011, 45(6):2207-2212.
[39] Kluepfel L, Keiluweit M, Kleber M, et al. Redox Properties of Plant Biomass-Derived Black Carbon (Biochar)[J]. Environmental Science & Technology, 2014, 48(10):5601-5611.
[40] Prévoteau A, Ronsse F, Cid I, et al. The Electron Donating Capacity of Biochar Is Dramatically Underestimated[J]. Scientific Reports, 2016, 6:32870.
[41] Rajapaksha A U, Alam M S, Chen N, et al. Removal of Hexavalent Chromium in Aqueous Solutions Using Biochar:Chemical and Spectroscopic Investigations[J]. Science of the Total Environment, 2018, 625:1567-1573.
[42] Diao Z H, Xu X R, Chen H, et al. Simultaneous Removal of Cr(Ⅵ) and Phenol by Persulfate Activated with Bentonite-Supported Nanoscale Zero-Valent Iron:Reactivity and Mechanism[J]. Journal of Hazardous Materials, 2016, 316:186-193.
[1] Liu Na, Yang Yadong, Alberto Bento Charrua, Wang Hang, Ye Kang, Lü Chunxin. Optimization of Atrazine Removal from Aqueous Solution by Biochar Using Response Surface Methodology [J]. Journal of Jilin University(Earth Science Edition), 2016, 46(4): 1199-1207.
[2] Liu Na, Wang Liu, Qiu Hua, Alberto Bento Charrua, Wang Hang, Wang Rui. Biochar Catalyzed Persulfate Decoloration of Azo Dye Acid Orange 7 [J]. Journal of Jilin University(Earth Science Edition), 2014, 44(6): 2000-2009.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
Copyright © Journal of Jilin University(Earth Science Edition), All Rights Reserved.
Tel: +86-431-88502374；13756165364　E-mail: xuebao1956@jlu.edu.cn
Powered by Beijing Magtech Co. Ltd