电感耦合等离子体质谱法测定植物灰分中稀土元素

电感耦合等离子体质谱法测定植物灰分中稀土元素

王松君^1,2，常平³，甘树才⁴，侯天平⁵

1. 苏州科技学院基础教学实验中心, 苏州 215009; 2. 吉林大学地球科学学院能源科学系, 长春 130061; 3. 吉林大学地球探测科学与技术学院地球化学系, 长春 130026; 4. 吉林大学化学学院化工与应化系, 长春 130026; 5. 吉林工程技术师范学院信息工程学院, 长春 130052

收稿日期:2003-09-11 修回日期:1900-01-01 出版日期:2004-07-26 发布日期:2004-07-26
通讯作者: 王松君

Determination of rare earth elements in the ash of plant by inductively coupled plasma mass spectroscopy

WANG Song-jun^1,2，　CHANG Ping³， GAN Shu-cai⁴ ， HＯＵ Tian-ping⁵

1.Center of Basic Experiment,Suzhou University of Science and Technology，Suzhou 215009,China;2.Department of Energy Sources Science,College of Earth Science，Jilin University,Changchun 130061,China; 3.Department of Geochemistry,College of Geoexploration Science and Technology,Jilin University,Changchun 130026, China;4. Department of Chemical Engineering and Applied Chemistry,College of Che mistry,Jilin University, Changchun 130026, China;

Received:2003-09-11 Revised:1900-01-01 Online:2004-07-26 Published:2004-07-26
Contact: WANG Song-jun

摘要/Abstract

摘要： 根据植物示踪地球化学找矿理论，建立植物中稀土元素的分析方法，为植物示踪地球化学找矿寻求快捷可靠的新手段. 采用高温灰化植物样本，氢氟酸-盐酸-硝酸-硫酸一次溶解植物灰分，电感耦合等离子体质谱法（ICP-MS）同时测定15种稀土元素. ICP-MS法可以减少化学分离富集的复杂操作程序引进的误差，操作简便，检测快速，以国家标准物质GBW07603检验方法的准确度，结果与标准值相符，该方法的准确度用相对误差衡量在3.00%~14.10%之间，精密度（RSD， n=8）在3.22%～20.00%之间.

关键词: 电感耦合等离子体质谱法, 植物灰分, 稀土元素

Abstract: On the basis of the theory of plant trace geochemistry prospect mine an analytic method of rare elements in plant is established, providing a rapid credible new means for plant was ashed by the method of high temperature furnace bake over a weak flame. The hydrof luoric acid-hydrochloric acid-nitric acid-vitriol (HF-HCl-HNO₃-H₂SO₄) system was used for the determination of 15 rare earthelements in the ash of plant by inductively coupled plasma mass spectroscopy (ICP-MS). The method of inductively coupled plasma mass spectroscopy can reduce the error introduced by chemistry separate and enrichment complex operating process, the operation is simple and the examine is quickly. The result of method is in agreement with the standard of nationality standard substance GBW07603. The experiment method measurement accuracy is 3.00%～14.10% in relative error, t heprecision(relatively standard deviation, number=8) is in the range of 3.22%~20.00%.

Key words: inductively coupled plasma mass spectroscopy, plant ash, rare ea rth element

中图分类号:

O657.63

王松君，常平，甘树才，侯天平. 电感耦合等离子体质谱法测定植物灰分中稀土元素[J]. J4, 2004, 42(03): 455-457.

WANG Song-jun，　CHANG Ping， GAN Shu-cai ， HＯＵ Tian-ping. Determination of rare earth elements in the ash of plant by inductively coupled plasma mass spectroscopy[J]. J4, 2004, 42(03): 455-457.

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