吉林大学学报(理学版)

• 环境科学 • 上一篇    

第二松花江流域水体表层沉积物多环芳烃的污染特征与暴露风险评价

刘宝林1,2, 董德明1, 花修艺1, 李明1   

  1. 1. 吉林大学 环境与资源学院, 长春 130012; 2. 长春师范大学 化学学院, 长春 130032
  • 收稿日期:2013-03-03 出版日期:2014-01-26 发布日期:2014-03-05
  • 通讯作者: 董德明 E-mail:dmdong@jlu.edu.cn

Pollution Characteristics and Exposure Risk Assessment of Polycyclic Aromatic Hydrocarbons (PAHs) in the SurfaceSediments of Second Songhua River Basin

LIU Baolin1,2, DONG Deming1, HUA Xiuyi1, LI Ming1   

  1. 1. College of Environment and Resources, Jilin University, Changchun 130012, China;2. College of Chemistry, Changchun Normal University, Changchun 130032, China
  • Received:2013-03-03 Online:2014-01-26 Published:2014-03-05
  • Contact: DONG Deming E-mail:dmdong@jlu.edu.cn

摘要:

考察第二松花江表层沉积物中16种多环芳烃类化合物(PAHs)的质量比. 结果表明: 16种PAHs的总质量比为350.0~3 877.4 ng/g, 平均质量比为1 322.6 ng/g, 4~6环相对丰度为58.5%, 2~3环相对丰度为41.5%; PAHs在上游水区的质量比最高, 与长江河口相近; 除河源区外, 大部分水域沉积物中PAHs人为来源为化石燃料的燃
烧, 少部分为石油源; 除表层沉积物中芴和苊烯可能具有一定的暴露风险外, 其他PAHs存在的暴露风险较小, 即第二松花江沉积物PAHs总量远低于风险评估低值(ERL), 存在的暴露风险较小.

关键词: 第二松花江, 表层沉积物, 多环芳烃, 暴露风险评价

Abstract:

The mass contents of 16 polycyclic aromatic hydrocarbons (PAHs) in the surface sediments of the second Songhua River were investigated. The total PAHs mass rate varied from 350.0 to 3 877.4 ng/g, with the mean value being 1 322.6 ng/g. The 4—6 rings PAHs made up 58.5%, whereas 2—3 rings PAHs made up 41.5%. The study shows that the mass content of PAHs was the highest in the surface sediments of the upstream of the second Songhua River. The total mass content of PAHs was close to that of the Yangtze River estuary. In addition to that from the source regions, the PAHs in the sedimen
ts were mainly from anthropogenic emission. Anthropogenically produced PAHs in the sediments in most of waters was from the burning of fossil fuels and a small part was from the petroleum derived. Exposure risk assessment results show that in addition to the fluorene and acenaphthylene, there was not obvious risk of exposure of other polycyclic aromatic hydrocarbons. The total mass content of PAHs in the sediments of the second Songhua River was much lower than the effects range\|low (ERL), and there was not obvious risk of exposure basically.

Key words: second Songhua River, surface sediment, polycyclic aromatic hydrocarbons, exposure risk assessment

中图分类号: 

  • X171