ATRP法合成梳形结构的HPEG/PMA和HPEG/PAA

吉林大学学报(理学版)

ATRP法合成梳形结构的HPEG/PMA和HPEG/PAA

赵莉¹, 任殿福¹, 田卫星², 王宏², 陈仲², 韩兆让¹

1. 吉林大学化学学院, 长春 130012； 2. 吉林省计算中心, 长春 130012

收稿日期:2013-12-05 出版日期:2014-09-26 发布日期:2014-09-26
通讯作者: 韩兆让 E-mail:hanzr@jlu.edu.cn

Synthesis of Comb HPEG/PMA and HPEG/PAA via ATRP

ZHAO Li¹, REN Dianfu¹, TIAN Weixing², WANG Hong², CHEN Zhong², HAN Zhaorang¹

1. College of Chemistry, Jilin University, Changchun 130012, China;2. Computation Center of Jilin Province, Changchun 130012, China

Received:2013-12-05 Online:2014-09-26 Published:2014-09-26
Contact: HAN Zhaorang E-mail:hanzr@jlu.edu.cn

摘要/Abstract

摘要：

采用原子转移自由基聚合(ATRP)法聚合甲基烯丙基聚氧乙烯醚(HPEG)和丙烯酸甲酯(PMA), 生成低分子量梳形结构的低聚物HPEG/PMA. 经Fourier红外光谱
(FT-IR)和核磁共振氢谱(¹H NMR)对其结构特征基团进行分析, 确认合成了目标产物. 对HPEG/PMA进行凝胶渗透色谱(GPC)测试, 结果表明, ATRP法制备的梳形HPEG/PMA分子量为7.7×10³, 分布系数为1.11, 具有优异的可控性. 梳形HPEG/PMA经V(乙醇)∶V(水)=1的NaOH溶液水解，得到梳形结构甲基烯丙基聚氧乙烯醚和丙烯酸(HPEG/PAA)低聚物.

关键词: 原子转移自由基聚合, 梳形结构, 甲基烯丙基聚氧乙烯醚

Abstract:

Comb methyl allyl polyethenoxy etherpolymethyl acrylate (HPEG/PMA) was synthesized with atom transfer radical polymerization (ATRP). FT-IR and ¹H NMR were used to identify the structure of HPEG/PMA. The results show that we successfully synthesized comblike HPEG/PMA. Gel permeation
chromatography (GPC) was used to characterize the molecular weight and molecular weight distribution. The molecular weight was 7.7×10³ and molecular weight distribution was 1.11. It indicates that the synthesis of HPEG/PAA with ATRP has good controllability. The HPEG/PMA was hydrolyzed with NaOH 
V(ethanol)∶V(H₂O)=1 solution to get HPEG/PAA.

Key words: atom transfer radical polymerization (ATRP), comb structure, methy allyl polyethenoxy ether (HPEG)

中图分类号:

O631.5

赵莉, 任殿福, 田卫星, 王宏, 陈仲, 韩兆让. ATRP法合成梳形结构的HPEG/PMA和HPEG/PAA[J]. 吉林大学学报(理学版), 2014, 52(05): 1091-1094.

ZHAO Li, REN Dianfu, TIAN Weixing, WANG Hong, CHEN Zhong, HAN Zhaorang. Synthesis of Comb HPEG/PMA and HPEG/PAA via ATRP[J]. Journal of Jilin University Science Edition, 2014, 52(05): 1091-1094.