吉林大学学报(理学版)

• 环境科学 • 上一篇    下一篇

去除水体中F-和SO2-4的吸附材料

董甜姿1,2, 张玉玲1,2, 高侃1, 赵伟国1, 秦晓强1   

  1. 1. 吉林大学 环境与资源学院, 长春 130021; 2. 吉林大学 水资源与环境研究所, 长春 130021
  • 收稿日期:2015-01-20 出版日期:2015-07-26 发布日期:2015-07-27
  • 通讯作者: 张玉玲 E-mail:lingling29@126.com

Materials of Adsorbing Fluoride and Sulfate in Water

DONG Tianzi1,2, ZHANG Yuling1,2, GAO Kan1, ZHAO Weiguo1, QIN Xiaoqiang1   

  1. 1. College of Environment and Resources, Jilin University, Changchun 130021, China; 2. Institute of Water Resources and Environment, Jilin University, Changchun 130021, China
  • Received:2015-01-20 Online:2015-07-26 Published:2015-07-27
  • Contact: ZHANG Yuling E-mail:lingling29@126.com

摘要:

选择火山渣、 骨炭、 粉煤灰和锰砂为吸附材料, 考察其去除水体中F-和SO2-4的性能, 并将火山渣和骨炭进行改性, 研究其改性后的动力学规律. 结果表明: 火山渣和骨炭对F-的吸附量分别为0.092,0.041 mg/g, 对SO2-4的吸附量分别为5.72,3.99 mg/g; 粉煤灰和锰砂对F-的吸附量均低于0.020 mg/g, 均未吸附SO2-4;Al2(SO4)3可作为改性剂; 经质量分数为10%的Al2(SO4)3联合热改性后火山渣对F-的最大吸附量为0.099 mg/g; 经质量分数为10%的Al2(SO4)3化学改性后火山渣对SO2-4的最大吸附量为5.93 mg/g; 二者动力学吸附规律均符合准二级方程.

关键词: 除氟, 除硫酸盐, 吸附材料, 改性材料

Abstract:

Four kinds of adsorption materialsscoria, bone char, ash and manganese sand were used to remove F- and SO2-4 in water. The research results show that adsorption capacities of scoria and bone char for F- were 0.092,0.041 mg/g; adsorption capacities of them for SO2-4were 5.72,3.99 mg/g. Adsorption capacities of ash and manganese sand for F- were both below 0.020 mg/g. AndSO2-4 was almost not adsorbed by them. Modification was applied in scoria and bone char because of their good adsorption effects. The research results show that Al2(SO4)3 could be used as modifier. Adsorption capacity of scoria which was soaked in 10% Al2(SO4)3 then calcinated at 300 ℃ was the maximum 0.099 mg/g. Adsorption capacity of scoria which was soaked in 10% Al2(SO4)3 was the maximum 5.93 mg/g. Adsorption kinetics of them both followed quasi-secondary dynamics equation.

Key words: fluoride removal, sulfate removal, adsorption materials, modified material

中图分类号: 

  • X523