吉林大学学报(理学版)

• 环境科学 • 上一篇    

松花江河漫滩沉积物柱样中PAHs分布的年代特征

刘小雪, 姜旭, 董德明, 梁大鹏, 郭志勇, 花修艺   

  1. 吉林大学 地下水资源与环境教育部重点实验室, 水资源与水环境吉林省重点实验室,环境与资源学院, 长春 130012
  • 收稿日期:2016-02-03 出版日期:2016-11-26 发布日期:2016-11-29
  • 通讯作者: 董德明 E-mail:dmdong@jlu.edu.cn

Temporal Distribution of PAHs in SedimentCores on Floodplain of Songhua River

LIU Xiaoxue, JIANG Xu, DONG Deming, LIANG Dapeng, GUO Zhiyong, HUA Xiuyi   

  1. College of Environment and Resources,  Key Lab of Water Resources and Aquatic Environment of Jilin Province,Key Lab of Groundwater Resources and Environment of Ministry of Education, Jilin University, Changchun 130012, China
  • Received:2016-02-03 Online:2016-11-26 Published:2016-11-29
  • Contact: DONG Deming E-mail:dmdong@jlu.edu.cn

摘要: 利用210Pb和137Cs定年技术结合松花江河漫滩沉积物柱样中多环芳烃(PAHs)的检测结果分析PAHs在近90年间的年代特征. 结果表明, 松花江河漫滩沉积物中PAHs质量比在1960年以后急剧增加, 20世纪90年代初期达到峰值后呈下降趋势, 与我国滇池和其他部分城市湖泊沉积记录基本一致, 但与发达国家同类研究结果明显不同. 与国内其他河流沉积物相比, 松花江PAHs污染处于中等水平.呈现以萘、 菲等低环化合物为主的污染特征. 根据PAHs环数的相对丰度、 w(蒽)/w(蒽+菲)、 w(荧蒽)/w(荧蒽+芘), 沉积物PAHs主要来源于石油类污染. PAHs质量比的阶段性变化与流域内近90年的人口、 GDP均显著相关, 即松花江PAHs污染与人类活动显著相关.

关键词: 河漫滩, 松花江, 多环芳烃, 沉积物柱样

Abstract: Using the  210Pb and 137Cs dating technique combined with test results of polycyclic aromatic hydrocarbons (PAHs) in sediment cores on floodplain of Songhua River, we analyzed time trend of PAHs mass ratio in the past 90 years. Results show that the mass ratio of PAHs in sediment increases sharply from the 1960s to a peak in the early 1990s and subsequently decrease. The time trend of sedimentary PAHs in Songhua River is basically similar to that in Dianchi and some other urban lakes in China, but clearly different from that in developed countries. The results also show that the PAHs concentrations reach a relatively moderate level in the surface sediments compared with other domestic river sediments. The pollution characteristics of low ring compounds such as naphthalene, phenanthrene and so on are presented. According to the relative abundance of PAHs ring number and ratios of w(Ant)/w(Ant+Phe), w(Flt)/w(Flt+Pyr), the PAHs of sediment mainly comes from petroleum pollution. The stage change of mass ratio of PAHs is significantly correlated with the population and GDP in the watershed during the last 90 years, i.e. PAHs pollution of Songhua River is related to human activities.

Key words: sediment core, polycyclic aromatic hydrocarbons (PAHs), floodplain, Songhua River

中图分类号: 

  • X132