吉林大学学报(理学版) ›› 2026, Vol. 64 ›› Issue (2): 467-0474.

• • 上一篇    

稻壳生物炭g-C3N4复合光催化剂降解诺氟沙星

王丽丽, 赵瑾, 张恩硕, 杨晓东   

  1. 长春大学 材料科学与工程学院, 长春 130022
  • 收稿日期:2025-08-18 出版日期:2026-03-26 发布日期:2026-03-26
  • 通讯作者: 杨晓东 E-mail:xiaodongyangccu@163.com

Rice Husk Biochar g-C3N4 Composite Photocatalyst for Degradation of Norfloxacin

WANG Lili, ZHAO Jin, ZHANG Enshuo, YANG Xiaodong   

  1. School of Materials Science and Engineering, Changchun University, Changchun 130022, China
  • Received:2025-08-18 Online:2026-03-26 Published:2026-03-26

摘要: 为提高对残留在环境中诺氟沙星的降解率, 通过一步煅烧法制备一种稻壳生物炭类石墨相氮化碳(g-C3N4)复合光催化剂, 并采用多种方式对其结构进行表征, 通过C原子取代g-C3N4晶格中的桥接N原子, 有效构建离域π键系统, 显著增强其对诺氟沙星的光催化降解性能. 实验结果表明, 优化的生物炭g-C3N4复合光催化剂的光降解速率常数最高可达0.029 4 min-1, 对诺氟沙星的降解率在2 h内提升至85.45%,是纯g-C3N4材料的1.46倍.  本文为开发高效、稳定的水处理光催化剂提供了新的设计思路, 展示了生物炭g-C3N4复合材料在环境修复领域的应用潜力. 

关键词: 石墨碳g-C3N4, 生物炭, 抗生素, 降解, 诺氟沙星

Abstract: In order to improve the degradation rate of  norfloxacin residues in the environment, we prepared a rice husk biochar based graphite phase nitrogen doped carbon (g-C3N4) composite photocatalyst through a one-step calcination method. We characterized its structure by using various methods, substituting the bridging nitrogen atoms in the g-C3N4 lattice with carbon atoms to effectively construct a delocalized π-bond system, significantly enhancing its photocatalytic degradation performance of norfloxacin. Experimental results show  that the photocatalytic degradation rate constant of the optimized biochar g-C3N4 composite photocatalyst can reach up to  0.029 4 min-1, and the degradation rate of norfloxacin can be increased to 85.45% within 2 h, which is 1.46 times  that of pure g-C3N4 material. This article provides novel design concept for developing highly efficient and stable photocatalysts for water treatment, demonstrating the application potential of biochar g-C3N4 composite materials  in the field of environmental remediation.

Key words: graphitic carbon g-C3N4, biochar, antibiotic, degradation, norfloxacin

中图分类号: 

  • X132