高效氯化镁球形载体的制备及性质

J4 ›› 2009, Vol. 47 ›› Issue (6): 1309-1312.

高效氯化镁球形载体的制备及性质

宋赛楠, 许云波, 刘强, 王丹丹, 王霞, 贾军纪, 朱博超

中国石油兰州化工研究中心, 兰州 730060

收稿日期:2009-03-02 出版日期:2009-11-26 发布日期:2010-01-07
通讯作者: 贾军纪 E-mail:jiajunji@petrochina.com.cn.

Preparation and Properties of Efficient Spherical MgCl₂Support

SONG Sainan, XU Yunbo, LIU Qiang, WANG Dandan, WANG Xia, JIA Junji, ZHU Bochao

Lanzhou Petrochemical Research Center, Petro China, Lanzhou 730060, China

Received:2009-03-02 Online:2009-11-26 Published:2010-01-07
Contact: JIA Junji E-mail:jiajunji@petrochina.com.cn.

摘要/Abstract

摘要：

采用自行设计的磁力搅拌反应釜, 用低速搅拌法制备了球形氯化镁载体, 并研究了氯化镁球形载体的热重曲线, 测定了氯化镁乙醇配合物中乙醇和水的质量分数. 载体的扫描电镜照片表明: 载体呈球形, 粒度分布较均匀. 载体负载后, 催化丙烯聚合, 活性较高, 得到颗粒形态较好的球形聚丙烯.

关键词: Ziegler-Natta催化剂；球形载体；氯化镁

Abstract:

Spherical MgCl₂ support was prepared at a low stirring dispersion speed in a selfdesigned magnetic stirring reactor. SEM measurement showed spherical support had nice morphology. The particle size distribution of the support was even. The ethanol and water mass fraction of the support were determined through the thermogravimetry. Spherical supported ZieglerNatta catalysts for propylene polymerization showed a high activity, obtaining spherical polypropylene particles.

Key words: Ziegler-Natta catalyst, spherical support, magnesium chloride

中图分类号:

O614.2

宋赛楠, 许云波, 刘强, 王丹丹, 王霞, 贾军纪, 朱博超. 高效氯化镁球形载体的制备及性质[J]. J4, 2009, 47(6): 1309-1312.

SONG Sainan, XU Yunbo, LIU Qiang, WANG Dandan, WANG Xia, JIA Junji, ZHU Boc. Preparation and Properties of Efficient Spherical MgCl₂Support[J]. J4, 2009, 47(6): 1309-1312.