3种乌头原碱的NMR

J4 ›› 2010, Vol. 48 ›› Issue (1): 127-132.

3种乌头原碱的NMR

魏巍, 李绪文, 周洪玉, 杨瑞杰, 时晓磊, 单晶, 孟磊, 金永日

吉林大学化学学院, 长春 130012

收稿日期:2009-05-13 出版日期:2010-01-26 发布日期:2010-01-27
通讯作者: 金永日 E-mail:jinyr@jlu.edu.cn.

Stuctural Elucidation of Three Aconines by NMR Spectroscopy

WEI Wei, LI Xuwen, ZHOU Hongyu, YANG Ruijie, SHI Xiaolei,SHAN Jing, MENG Lei, JIN Yongri

College of Chemistry, Jilin University, Changchun 130012, China

Received:2009-05-13 Online:2010-01-26 Published:2010-01-27
Contact: JIN Yongri E-mail:jinyr@jlu.edu.cn.

摘要/Abstract

摘要：

利用3种双酯型乌头碱（乌头碱、新乌头碱、次乌头碱）经水解得到3种乌头碱型生物原碱, 即乌头原碱、新乌头原碱、次乌头原碱. 应用一维和二维核磁共振（NMR，包括¹H-¹H COSY,HMQC和HMBC)对这3种化合物的结构进行了分析, 并对其¹H和¹³C化学位移进行了全归属.

关键词: 核磁共振（NMR）, 化学位移归属, 二维NMR, 乌头原碱

Abstract:

Three aconines: aconine, mesaconine, hypaconine were separated from the hydrolyzates of three diesterditerpenoid aconines aconitine, mesaconitine and hypaconitine. ¹H and ¹³C NMR spectra(including ¹H-¹H COSY, HMQC and HMBC) of the compounds were acquired and assigned. The structures of the compounds were elucidated. The chemical shift assignm
ents of ¹H and ¹³C were made.

Key words: nuclear magnetic resonance (NMR), chemical shift assignment, 2D NMR, aconine

中图分类号:

O657.61

魏巍, 李绪文, 周洪玉, 杨瑞杰, 时晓磊, 单晶, 孟磊, 金永日. 3种乌头原碱的NMR[J]. J4, 2010, 48(1): 127-132.

WEI Wei, LI Xu-Wen, ZHOU Hong-Yu, YANG Rui-Jie, SHI Xiao-Lei, CHAN Jing, MENG Lei, JIN Yong-Ri. Stuctural Elucidation of Three Aconines by NMR Spectroscopy[J]. J4, 2010, 48(1): 127-132.