吉林大学学报(理学版) ›› 2018, Vol. 56 ›› Issue (5): 1261-1266.

• 化学 • 上一篇    下一篇

用蔗渣遗态转化法制备分级多孔结构氧化锌及其对丙酮气体的检测性能#br#

安泰吉, 董招君, 张宇鹏, 王延嘉, 冯威, 蒋惠忠   

  1. 吉林大学 环境与资源学院, 长春 130021
  • 收稿日期:2018-01-03 出版日期:2018-09-26 发布日期:2018-11-22
  • 通讯作者: 蒋惠忠 E-mail:461112170@qq.com

Preparation of Hierarchical Porous ZnO by BagasseMorphGenetic Transformation Method and Its Detection Performance for Acetone Gas#br#

AN Taiji, DONG Zhaojun, ZHANG Yupeng, WANG Yanjia, FENG Wei, JIANG Huizhong#br#   

  1. College of Environment and Resources, Jilin University, Changchun 130021, China
  • Received:2018-01-03 Online:2018-09-26 Published:2018-11-22

摘要: 以蔗渣为生物模板, 用遗态转化法制备分级多孔结构ZnO. 用X射线衍射(XRD)、 扫描电镜(SEM)及比表面积测试法对ZnO样品进行物相分析, 并进行气敏实验. 结果表明: 煅烧后得到的样品为纯相纤锌矿系六方晶结构ZnO, 模板已被完全去除; ZnO样品表面呈蔗渣模板的类蜂窝状结构, 由多孔道相互联结而成; 分级多孔结构ZnO对100 cm3/m3丙酮的响应值在340 ℃时达到最大值24.5, 比常规无模板ZnO约高2.23倍; 响应时间和恢复时间分别为6 s和1 s, 比常规无模板ZnO的时间均缩短, 并有很好的气体选择性.

关键词: 蔗渣, 遗态转化, 氧化锌, 气敏

Abstract: Using bagasse as biological template, the hierarchical porous structure ZnO was prepared by morphgenetic transformation method. The ZnO samples were phaseanalyzed by Xray diffraction (XRD), scanning electron microscopy (SEM) and specific surface area test method, and the gassensing experiment was carried out. The results show that the samples obtained after calcination is pure wurtzite hexagonal ZnO with bagasse template completely removed. The surface of ZnO samples show honeycomblike structure, which is formed by the interconnection of porous channels. The response of hierarchical porous ZnO reaches a maximum of 24.5 at 340 ℃ for 100 cm3/m3 acetone, about 2.23 times higher than that of
 conventional templatefree ZnO. Response time and recovery time are 6 s and 1 s, respectively, shorter  than that of the conventional templatefree ZnO, and it has good gas selectivity.

Key words: bagasse, morphgenetic transformation, zinc oxide, gas sensitivity

中图分类号: 

  • O614