基于Baeyer-Villiger反应与Wittig反应合成几种新型苯并螺环酮类化合物

吉林大学学报(理学版) ›› 2019, Vol. 57 ›› Issue (5): 1261-1266.

基于Baeyer-Villiger反应与Wittig反应合成几种新型苯并螺环酮类化合物

吴运凯, 裴维兵, 王宇超, 刘宇

长春工业大学化学与生命科学院, 材料科学高等研究院, 长春 130012

收稿日期:2018-11-30 出版日期:2019-09-26 发布日期:2019-09-20
通讯作者: 刘宇 E-mail:yuliu@ccut.edu.cn

Synthesis of Several New Benzospirone Compounds Based on BaeyerVilliger Reaction and Wittig Reaction

WU Yunkai, PEI Weibing, WANG Yuchao, LIU Yu

Advanced Insitute of Materials Science, College of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, China

Received:2018-11-30 Online:2019-09-26 Published:2019-09-20
Contact: LIU Yu E-mail:yuliu@ccut.edu.cn

摘要/Abstract

摘要： 对Pd₂(dba)₃参与邻溴苯基环丁酮类化合物开环反应得到的苯并螺环二酮类化合物进行衍生化研究, 并通过Baeyer-Villiger反应和Wittig反应考察一系列含有不同官能团的反应底物. 结果表明, 该方法可高选择性地制备不同类型的苯并螺环化合物.

关键词: 苯并螺环化合物, BaeyerVilliger氧化, Wittig反应

Abstract: The derivatization of benzosriprodiones obtained from Pd₂(dba)₃ participated ringopening reaction of Obromophen
ylcyclobutanone derivatives was studied, a series of substrates containing different functional groups were investigated by BaeyerVilliger reaction and Wittig reaction. The results show that different types of benzospirocyclic compounds can be prepared by the proposed method with high selectivity.

Key words: benzospirocyclic compound, BaeyerVilliger oxidation, Wittig reaction

中图分类号:

O624.42

吴运凯, 裴维兵, 王宇超, 刘宇. 基于Baeyer-Villiger反应与Wittig反应合成几种新型苯并螺环酮类化合物[J]. 吉林大学学报(理学版), 2019, 57(5): 1261-1266.

WU Yunkai, PEI Weibing, WANG Yuchao, LIU Yu. Synthesis of Several New Benzospirone Compounds Based on BaeyerVilliger Reaction and Wittig Reaction[J]. Journal of Jilin University Science Edition, 2019, 57(5): 1261-1266.