吉林大学学报(理学版) ›› 2019, Vol. 57 ›› Issue (06): 1513-1518.

• 化学 • 上一篇    下一篇

MBS对PLA/GMS吹塑薄膜性能的影响

赵吉丽1,2,3, 张会良3,4, 高歌2   

  1. 1. 北华大学 理学院, 吉林 吉林 132013; 2. 吉林大学 化学学院, 长春 130012;3. 中国科学院长春应用化学研究所 生态环境高分子材料重点实验室, 长春 130022; 4. 浙江中科应用化学科技有限公司, 杭州 311300
  • 收稿日期:2019-01-02 出版日期:2019-11-26 发布日期:2019-11-21
  • 通讯作者: 张会良 E-mail:hlzhang@ciac.jl.cn

Effect of MBS on Properties of PLA/GMS/MBS Blown Films

ZHAO Jili1,2,3, ZHANG Huiliang3,4, GAO Ge2   

  1. 1. College of Science, Beihua University, Jilin 132013, Jilin Province, China;2. College of Chemistry, Jilin University, Changchun 130012, China; 3. Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;4. Zhejiang Zhongke Applied Chemistry Technology Co., Ltd, Hangzhou 311300, China
  • Received:2019-01-02 Online:2019-11-26 Published:2019-11-21
  • Contact: ZHANG Huiliang E-mail:hlzhang@ciac.jl.cn

摘要: 用熔融共混方法制备聚乳酸/甲基丙烯酸甲酯丁二烯苯乙烯三元共聚物/单硬脂酸甘油酯三元共混物及吹塑薄膜, 并研究聚乳酸/甲基丙烯酸甲酯丁二烯苯乙烯三元共聚物/单硬脂酸甘油酯三元薄膜的力学性能、 光学性能、 流变性能、 热性能和结晶
性能. 其中, 甲基丙烯酸甲酯丁二烯苯乙烯三元共聚物为增韧剂, 单硬脂酸甘油酯为增塑剂. 结果表明: 加入甲基丙烯酸甲酯丁二烯苯乙烯三元共聚物可改善聚乳酸/甲基丙烯酸甲酯丁二烯苯乙烯三元共聚物/单硬脂酸甘油酯薄膜的力学性能, 并提高聚乳酸的结晶性能.

关键词: 聚乳酸, 甲基丙烯酸甲酯丁二烯苯乙烯的三元共聚物, 单硬脂酸甘油酯, 增韧, 增塑, 吹塑薄膜

Abstract: The ternary blends of polylactic acid, poly (methyl methacrylatebutadienestyrene), and glycerol monostearate were prepared by meltblended method and blown films were prepared. Poly (methyl methacrylatebutadienestyrene) was used as toughener and glycerol monostearate as plasticizer. The crystallization morphology, mechanical properties, optical properties of the PLA/MBS/GMS films were studied. The results show that the addition of MBS can improve the mechanical properties of polylactic acid/poly(methyl methacrylatebutadienestyrene)/glycerol monostearate films and promote the crystallization properties of polylactic acid.

Key words: polylactic acid, poly(methyl methacrylatebutadienestyrene), glycerol monostearate, toughening, plasticizing, blown film

中图分类号: 

  • O631