基于羟基苯基卟啉骨架的二聚卟啉合成及性能

吉林大学学报(理学版) ›› 2020, Vol. 58 ›› Issue (4): 1010-1014.

基于羟基苯基卟啉骨架的二聚卟啉合成及性能

石莹岩¹, 张畅², 许风辉², 李迪³

1. 吉林建筑大学基础科学部, 长春 130118； 2. 吉林建筑大学材料科学与工程学院, 长春 130118；3. 西安建筑科技大学冶金工程学院, 西安 710055

收稿日期:2019-10-30 出版日期:2020-07-26 发布日期:2020-07-16
通讯作者: 石莹岩 E-mail:shiyingyan73@163.com

Synthesis and Properties of Dimeric PorphyrinsBased on Hydroxyphenyl Porphyrin Skeleton

SHI Yingyan¹, ZHANG Chang², XU Fenghui², LI Di³

1. Department of Basic Science, Jilin Jianzhu University, Changchun 130118, China;
2. College of Materials Science and Engineering, Jilin Jianzhu University, Changchun 130118, China;
3. School of Metallurgical Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, China

Received:2019-10-30 Online:2020-07-26 Published:2020-07-16
Contact: SHI Yingyan E-mail:shiyingyan73@163.com

摘要/Abstract

摘要： 以1,4-二氯-2,5-二硝基甲苯为桥联剂, 通过一步合成法制备H-2MHTPP卟啉二聚体, 用MALDI-TOF质谱表征卟啉二聚体的结构, 并研究卟啉二聚体的电化学和光化学性质以及表面光电压光谱（SPS）. 结果表明, H-2MHTPP卟啉二聚体是一种p型半导体.

关键词: 卟啉二聚体, 电化学和光化学性质, 表面光电压谱, p型半导体

Abstract: Using 1,4-dichloro-2,5-dinitrotoluene as bridging agent, H-2MHTPP porphyrin dimer was prepared by one-step synthesis. The structure of porphyrin dimer was characterized by MALDI-TOF mass spectrometry. The electrochemical and photochemical properties of the porphyrin dimer and the surface photovoltage spectrum (SPS) of the porphyrin dimer were studied. The results show that the H2MHTPP porphyrin dimer is a p-type semiconductor.

Key words: dimeric porphyrin, electrochemical and photochemical properties, surface photovoltage spectrum, ptype semiconductor

中图分类号:

O614

石莹岩, 张畅, 许风辉, 李迪. 基于羟基苯基卟啉骨架的二聚卟啉合成及性能[J]. 吉林大学学报(理学版), 2020, 58(4): 1010-1014.

SHI Yingyan, ZHANG Chang, XU Fenghui, LI Di. Synthesis and Properties of Dimeric PorphyrinsBased on Hydroxyphenyl Porphyrin Skeleton[J]. Journal of Jilin University Science Edition, 2020, 58(4): 1010-1014.