关键词: 磺胺嘧啶, Co₃Mn-LDHs/rGO, 可见光/过硫酸盐耦合降解体系, 氧化还原反应

Abstract: Aiming at the problem of water pollution caused by the antibiotic sulfadiazine (SDZ), a three-dimensional layered Co₃Mn-LDHs/rGO dual-action catalyst with both photocatalysis and persulfate activation functions based on graphene (rGO) was prepared by a hydrothermal method,  and a visible light/persulfate coupled degradation system (Vis-PMS) was constructed to degrade SDZ in water. The experimental results show that Co₃Mn-LDHs are successfully loaded on rGO and the attachment of Co₃Mn-LDHs prevents the stacking of rGO sheets.  The optimal conditions for the degradation of SDZ in the visible-light-coupled non-homogeneous-phase-activated PMS system are Co₃Mn-LDHs/rGO mass concentration of 20 mg/L,  PMS mass concentration of 200 mg/L,  and an initial pH=7,  and the removal rate of SDZ reaches 87.58% after 60 min of reaction.   Co₃Mn-LDHs/rGO still has a high removal rate for SDZ with good reusability after 10 cycle tests.  The free radicals that play a major role  in this system are sulfate radicals (SO^-₄),  hydroxyl radicals (.OH),  and singlet-linear oxygen (¹O₂). 

Key words: sulfadiazine,  , Co₃Mn-LDHs/rGO,  , visible light/persulfate coupled degradation system,  , oxidation-reduction reaction