关键词: 金属有机骨架材料, 光催化, 四环素

Abstract: Aiming at the problem that it was difficult to eliminate tetracycline in wastewater and achieve water quality purification through self-purification of the environment, we developed and designed a  new type of sewage treatment agents. A novel metal-organic framework (MOF) material [Mn₂(TCPQ)(H₂O)₈]·xsolvent.  was synthesized by 4，4′，4″，4′′′-(quinoxalin-2,3,6,7-tetrayl)tetrabenzoic acid as the organic ligand and Mn(Ⅱ) as the metal center ion. The structure and stability of the material were studied by using powder X-ray diffraction,  X\|ray single crystal diffraction, Fourier transform infrared spectroscopy and thermogravimetry,  and its photocatalytic performance was analyzed. The experimental results show that the degradation rate of tetracycline by the prepared MOFs material can reach 97.5% when exposed to visible light for 30 min. The compound can be used as an excellent  material for the degradation of tetracycline.

Key words: metal-organic framework material, photocatalysis, tetracycline