J4 ›› 2010, Vol. 48 ›› Issue (05): 840-842.

• 物理 • 上一篇    下一篇

ZnO晶须的变温Raman光谱

郭星原, 丁战辉, 薛燕峰, 徐辑廉, 衣艳磊, 李亮, 周静, 许大鹏   

  1. 吉林大学 物理学院, 长春 130012
  • 收稿日期:2010-03-11 出版日期:2010-09-26 发布日期:2010-09-21
  • 通讯作者: 郭星原 E-mail:guoxy@jlu.edu.cn

Raman Spectra of ZnO Whisker at Various Temperatures

GUO Xing yuan, DING Zhan hui, XUE Yan |feng, XU Ji lian, YI Yan lei, |LI Liang, ZHOU Jing, XU Da peng   

  1. College of Physics, |Jilin University, Changchun |130012, China
  • Received:2010-03-11 Online:2010-09-26 Published:2010-09-21
  • Contact: GUO Xing yuan E-mail:guoxy@jlu.edu.cn

摘要:

采用浮区法制备微米量级的ZnO晶须, X射线衍射(XRD)和偏光显微镜分析表明, 生长的ZnO单晶晶须为六方纤锌矿结构, 沿(100)晶面择优生长取向. 微区变温Raman光谱表明: 当温度为93~706 K时, 声子频率随温度升高呈倒指数下降(红移); 当温度超过500 K时, Ehigh2谱线随温度上升而加宽,  ZnO分子较活跃, Raman模频率呈明显的硬化现象.

关键词: 氧化锌, 晶须, X射线衍射, Raman光谱, 偏光显微镜

Abstract:

ZnO (wurtzite) whiskers were grown via a floating zone method. The as-grown samples were characterized by X-ray diffraction and polarizing microscopy. Their characteristic peaks verify that the as-grown ZnO whiskers have excellent hexagonal wurtzite phase and (100) orientation. Raman scattering results show that  when  temperature was 93~706 K, the  frequency was red shift with the temperature increasing. When temperature was up to 500 K, the line width of Ehigh2 mode broadened with the temperature increasing, ZnO elements turned into activity  status, Raman mode frequency was significant hardening.

Key words: zinc oxide, whisker, X-ray diffraction, Raman spectrum, polarizing microscope

中图分类号: 

  • O433.3