β-D-糖基苯胺基硫脲的合成与表征

Synthesis and Characterization of β-D-Glucopyranosyl Thiourea

SUN Wei-dong^1，2, WANG Xiao-ming², ZHANG Suo-qin², LI Yao-xian², ZHENG Ji-fu², YUAN Hong³, GUO Qing-huan³

1. Department of Chemistry, Chifeng College, Chifeng 024001, Inner Mongolia Autonomous Region,China; 2. College of Chemistry, Jilin University, Changchun 130021, China; 3. Jilin Chemical Combine Company, Jilin 132021, Jilin Province, China

Received:2005-06-06 Revised:1900-01-01 Online:2006-01-26 Published:2006-01-26
Contact: ZHANG Suo-qin

Abstract

Abstract: 2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl thiourea compounds were synthesised from the reaction of aniline and 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl isothiocyanate in acetonitrile under reflux. The 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl isothiocyanate was synthesised from 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl bromine. The structures of the title compounds were confirmed by elemental analyses, IR, MS and ¹H NMR spectra.

Key words: glycosyl isothiocyanate, synthesis, glucosyl thiourea

CLC Number:

O626

SUN Wei-dong, WANG Xiao-ming, ZHANG Suo-qin, LI Yao-xian, ZHENG Ji-fu, YUAN Hong, GUO Qing-huan. Synthesis and Characterization of β-D-Glucopyranosyl Thiourea[J].J4, 2006, 44(01): 109-112.

[1]	LI Erqiang, CHEN Kaijian, ZHOU Yang. Controllable Multi-texture Extended Synthesis and Transfer [J]. Journal of Jilin University Science Edition, 2021, 59(3): 577-586.
[2]	ZHANG Tingyu, CUI Xu, WANG Ying, LI Xuemei, ZHANG Jiayan, ZHUANG Changfu. Synthesis of Ferrocene Porphyrin and Its Substituent Effect [J]. Journal of Jilin University Science Edition, 2021, 59(2): 408-414.
[3]	LIN Hongyan, LI Jiahui, ZENG Ling, WANG Qinglin. Synthesis and Property of AndersonType PolyoxometalateBasedCopper Complex Hybridized by a Tetrazole [J]. Journal of Jilin University Science Edition, 2020, 58(4): 997-1002.
[4]	HUANG Xidai. Fuzzy Region Judgment Algorithm in Network Intrusion [J]. Journal of Jilin University Science Edition, 2020, 58(2): 321-328.
[5]	LIU Rong, WANG Tao, YAO Xin. Selfpropagating Combustion Synthesis and PhotoluminescentProperties of Pure Phase CaAl₄O₇∶Tb³⁺(Sm³⁺)#br# [J]. Journal of Jilin University Science Edition, 2019, 57(1): 166-170.
[6]	LIN Hongyan, ZHAO Jing, LIU Yu, ZENG Ling, WANG Qinglin. Synthesis, Structure and Dye Adsorption Property of OneDimensional[JP]Flexible Bispyridyltetrazolebased Copper Complex [J]. Journal of Jilin University Science Edition, 2018, 56(4): 1012-1016.
[7]	LI Zheng, YU Miao. Synthesis and Fluorescence Properties of Mesotetra(N-alkyl)-carbazolylporphyrins and Their Lanthanide Acetylacetone Complexes [J]. Journal of Jilin University Science Edition, 2016, 54(06): 1445-1450.
[8]	LIU Hong, ZHANG Shugong. Facial Expression Synthesis Based on Curve Representation [J]. Journal of Jilin University Science Edition, 2015, 53(01): 80-88.
[9]	WANG Wei, XIU Zhiming, WANG Deli, XU Tianshu,GUO Youming, WANG Liping. Synthesis and Characterization of Triisopropanolamine Borate [J]. Journal of Jilin University Science Edition, 2014, 52(04): 831-834.
[10]	KONG Weiping, WANG Cong, XU Dandan, ZHAO Li, ZOU Yongcun. High Temperature Hydrothermal Synthesis of PtFunctionalized Mesoporous Al₂O₃ andIts Catalytic Activity for Benzene Combustion [J]. Journal of Jilin University Science Edition, 2014, 52(03): 601-604.
[11]	LIU Hua, WANG Cong, ZOU Xu, LIU Fujian. oft Template Route for Synthesis of Supermicroporous Carbonswith Excellent Adsorption Property for Organic Dye [J]. Journal of Jilin University Science Edition, 2013, 51(06): 1173-1176.
[12]	WANG Yan, REN Dianfu, TIAN Weixing, WANG Hong,CHEN Zhong, HAN Zhaorang. Synthesis and Properties of PolyetherBased Superplasticizer [J]. Journal of Jilin University Science Edition, 2013, 51(05): 949-954.
[13]	PENG Chang-Fu, WANG Ying, ZHANG Jia-Xing, TUN Chun-Hua, TIAN Hang, QIN Yong-Jian, SHI Tong-Shun. Synthesis and Electrochemical Property of an UnsymmetricalPorphyrin and Its Zn Compound [J]. J4, 2012, 50(03): 571-.
[14]	WANG Ban-Ban, SONG Yan-Qiu, Sun-Er-Jun. Synthesis and Organic Photovoltaic Device of Starburst Europium (Ⅲ) β-Diketonate Complex [J]. J4, 2012, 50(02): 351-356.
[15]	YANG Jun, MA Gong-Chao, FU Ying-Huan, SONG Yu, WANG Yong-Wei, XU Chun-Ling, Dong-Xiao-Li. AlkaliActivated Synthesis of Zeolite P from Rice Husk [J]. J4, 2011, 49(04): 767-771.

Synthesis and Characterization of β-D-Glucopyranosyl Thiourea

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 10