超分子配合物{［Cd(phen)3］·NDC·8(H2O)}的合成、 晶体结构和性质

Abstract

Abstract: A supramolecular complex {［Cd(phen)₃］·NDC·8(H₂O)}（1） (phen： 1,10-phenanthroline， NDC： 2,6-naphthalenedicarboxylate) was synthesized under hydrothermal condition and characterized with elementalanalysis and singlecrystal X-ray diffraction. Complex 1 crystallized in the triclinic system with space group P1, a=1.201　0(2)　nm , b=1.286　4(3) nm, c=1.709　7(3) nm, α=74.21(3)°, β=69.92(3)°, γ=71.40(3)°, V=2.311　7(8) nm³, Z=2， R₁=0.066　0, wR₂=0.204 3.This complex shows photoluminescence property,indicating that it may be appliedin the development of luminescent materials.

Key words: crystal structure, hydrogen bonding, π…πinteraction, photoluminescence

CLC Number:

O614

YU Lianxiang, YIN Weirong, YE Junwei, XU Jianing, ZHANG Ping. Synthesis, Crystal Structure and Properties of Supramolecular Complex Based on PHEN and Naphthalene-2,6-dicarboxylic Acid Ligands[J].J4, 2007, 45(03): 493-496.

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Synthesis, Crystal Structure and Properties of Supramolecular Complex Based on PHEN and Naphthalene-2,6-dicarboxylic Acid Ligands

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